全文获取类型
收费全文 | 1076篇 |
免费 | 50篇 |
国内免费 | 3篇 |
专业分类
化学 | 778篇 |
晶体学 | 7篇 |
力学 | 33篇 |
数学 | 174篇 |
物理学 | 137篇 |
出版年
2024年 | 1篇 |
2023年 | 12篇 |
2022年 | 16篇 |
2021年 | 20篇 |
2020年 | 17篇 |
2019年 | 20篇 |
2018年 | 16篇 |
2017年 | 14篇 |
2016年 | 31篇 |
2015年 | 26篇 |
2014年 | 36篇 |
2013年 | 49篇 |
2012年 | 90篇 |
2011年 | 117篇 |
2010年 | 75篇 |
2009年 | 53篇 |
2008年 | 83篇 |
2007年 | 57篇 |
2006年 | 69篇 |
2005年 | 52篇 |
2004年 | 53篇 |
2003年 | 50篇 |
2002年 | 44篇 |
2001年 | 12篇 |
2000年 | 11篇 |
1999年 | 10篇 |
1998年 | 9篇 |
1997年 | 7篇 |
1996年 | 16篇 |
1995年 | 4篇 |
1994年 | 8篇 |
1993年 | 4篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1976年 | 5篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有1129条查询结果,搜索用时 765 毫秒
111.
Hussein El-Kashef Pascal Rathelot Patrice Vanelle Sylvain Rault 《Monatshefte für Chemie / Chemical Monthly》2007,138(5):469-476
Summary. 2-Amino-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carbonitrile was converted into the corresponding 2-(pyrrol-1-yl) derivative, followed by reduction of the latter
compound into the corresponding amine. This amine and its acyl, aroyl, and arylidene derivatives were used as synthons in
the synthesis of several title compounds. 相似文献
112.
Mariya V. Edeleva Igor A. Kirilyuk Dmitry P. Zubenko Irina F. Zhurko Sylvain R. A. Marque Didier Gigmes Yohann Guillaneuf Elena G. Bagryanskaya 《Journal of polymer science. Part A, Polymer chemistry》2009,47(23):6579-6595
The H‐atom transfer reaction was studied for a series of imidazoline, imidazolidine, and pyrrolidine‐based alkoxyamines containing either isobutyrate‐2‐yl or 1‐phenylethyl alkyl fragments. The C O bond homolysis rate constants and activation energies were determined by 1H NMR product analysis as a function of temperature. Inter‐ and intramolecular H‐atom transfer reactions were distinguished by examination of alkoxyamine thermolysis products in the absence and in the presence of a radical scavenger (thiophenol or deuterated styrene). A correlation between the structure of the nitroxyl fragment of alkoxyamine and the H‐transfer reaction was found. The high steric demands of the substituents on the nitroxyl part of the isobutyrate‐2‐yl alkoxyamine decrease both types of reaction. For alkoxyamines containing the 1‐phenylethoxyamines, neither inter‐ nor intramolecular H‐atom transfer was observed. Controlled polymerization of methylmethacrylate initiated with imidazoline‐based alkoxyamine was observed, although the polymer obtained was not living. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6579–6595, 2009 相似文献
113.
We prove a C1-connecting lemma for pseudo-orbits of diffeomorphisms on compact manifolds. We explore some consequences for C1-generic diffeomorphisms. For instance, C1-generic conservative diffeomorphisms are transitive. To cite this article: C. Bonatti, S. Crovisier, C. R. Acad. Sci. Paris, Ser. I 336 (2003). 相似文献
114.
Triangulations in CGAL 总被引:7,自引:0,他引:7
Jean-Daniel Boissonnat Olivier Devillers Sylvain Pion Monique Teillaud Mariette Yvinec 《Computational Geometry》2002,22(1-3):5-19
This paper presents the main algorithmic and design choices that have been made to implement triangulations in the computational geometry algorithms library
. 相似文献
115.
Sur les immeubles triangulaires et leurs automorphismes 总被引:1,自引:0,他引:1
Résumé Les travaux de J. Tits ont conduit à la classification complète des immeubles euclidiens de dimension supérieure ou égale
à 3. L’ensemble de ces immeubles à isomorphisme près est dénombrable et paramétré par les corps locaux qui leur correspondent.
Dans cet article nous nous intéressons aux immeubles triangulaires, qui sont euclidiens de dimension 2 et pour lesquelles
une paramétrisation analogue est impossible. Nous construisons une lamination Λ sur un espace topologique localement compact
séparé, dont l’espace des feuilles est l’ensemble des immeubles triangulaires à isomorphisme près. On considère ainsi les
immeubles triangulaires comme points d’un espace dont Λ est une désingularisation naturelle. Nous établissons des résultats
de chirurgie sur les immeubles triangulaires à données locales fixées. Ils entra?nent par exemple que Λ est topologiquement
transitive. Nous montrons qu’un immeuble triangulaire générique au sens de Baire a un groupe d’automorphismes trivial et qu’il
contient toutes les géométries locales possibles. L’espace des immeubles triangulaires à isomorphisme près est un nouvel exemple
d’espace non commutatif.
Le second auteur a été en partie financé par JSPS. 相似文献
116.
In this Note, we present direct numerical simulation results of a spatial mixing layer generated behind an upstream plate separating two boundary layers. The effect of the shape of the trailing edge of the plate is considered through comparisons between flows obtained from a bevelled or a blunt plate. In the former case, a spatial mixing layer consistent with previous experimental and numerical observations is obtained. In the latter case, the self-excited state that establishes in the near wake region dominates primary and secondary instability mechanisms while understating the importance of inflow perturbations. This behaviour is interpreted in terms of convective or absolute instability. The effects on turbulent statistics are also discussed. To cite this article: S. Laizet, E. Lamballais, C. R. Mecanique 334 (2006). 相似文献
117.
In this paper we give four definitions of Maslov index and show that they all satisfy the same system of axioms and hence are equivalent to each other. Moreover, relationships of several symplectic and differential geometric, analytic, and topological invariants (including triple Maslov indices, eta invariants, spectral flow and signatures of quadratic forms) to the Maslov index are developed and formulae relating them are given. The broad presentation is designed with a view to applications both in geometry and in analysis. © 1994 John Wiley & Sons, Inc. 相似文献
118.
Recently, it has been shown that alkoxyamines can be used as radical initiators in tin-free radical chemistry. Thus, it prompted us to develop the preparation of highly valuable alkoxyamines via ionic chemistry and the radical cyclization was triggered by thermal initiation. Following that procedure, bicyclic, spiro and eight-membered lactones were easily prepared in good yields with very high stereoselectivity. 相似文献
119.
This work is aimed towards determining the macroscopic strength criterion of a heterogeneous material with a random microstructure. We use the self-consistent concept by considering a reference material, which is of same nature as the constituents of the heterogeneous material. We deduce that the estimates of the macroscopic strength domain are the solutions to self-consistent equations and we give their derivation procedure. To cite this article: S. Turgeman, B. Guessab, C. R. Mecanique 330 (2002) 623–626. 相似文献
120.
Computational Studies on Intramolecular Cycloadditions of Azidoenynes and Azidobutenenitriles to Give 6H‐Pyrrolo[1,2‐c][1,2,3]triazoles and 5H‐Pyrrolo[1,2‐d]tetrazoles 下载免费PDF全文
Gérard Audran Paul Brémond Douniazad El Abed Sylvain R. A. Marque Didier Siri Maurice Santelli 《Helvetica chimica acta》2015,98(7):1018-1027
Energetics of intramolecular cycloadditions of azidoenynes and azidobutenenitriles to give 6H‐pyrrolo[1,2‐c][1,2,3]triazoles and 5H‐pyrrolo[1,2‐d]tetrazoles have been calculated at the B3LYP/6.311++G(3df,3pd) level of theory in ideal gas and in H2O as solvent. Stabilities of the corresponding anions, tautomers, and isomers are discussed. Transition states of the cyclization of parent compounds are determined at the same level of theory. 相似文献