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41.
Intermolecular Interactions of 3,5-Di-tert-butyl-4-hydroxybenzyl Acetate in Crystal and in Solutions
Bukharov S. V. Pod”yachev S. N. Syakaev V. V. Litvinov I. A. Gubaidullin A. T. 《Russian Journal of General Chemistry》2001,71(10):1570-1573
The molecular and crystal structure of 3,5-di-tert-butyl-4-hydroxybenzyl acetate was studied by single-crystal X-ray diffraction. The molecules form infinite chains in the crystals via hydrogen bonds between the hydroxy and carbonyl groups. The interchain bonding is provided by CH- interactions. In carbon tetrachloride, the molecules of the title compound form weak associates via hydrogen bonds between the hydroxy and carbonyl groups. 相似文献
42.
43.
S. N. Podyachev T. A. Barsukova S. V. Bukharov V. V. Syakaev S. N. Sudakova G. N. Nugumanova A. I. Konovalov 《Russian Journal of Organic Chemistry》2012,48(10):1360-1365
1,3-Alternate and cone stereoisomers of tetrathiacalix[4]arene and 4-tert-butyltetrathiacalix[4]arene functionalized by carbohydrazide groups reacted with 3,5-di-tert-butyl-4-hydroxybenzaldehyde to give the corresponding hydrazones having sterically hindered phenol fragments. 相似文献
44.
E. M. Gibadullina T. R. Shaekhov V. V. Syakaev A. R. Burilov M. A. Pudovik 《Russian Chemical Bulletin》2012,61(7):1502-1504
A reaction of 1,3-dimethoxybenzene with dimethyl (3,5-di-tert-butyl-4-oxocyclohexa-2,5-dienylidenemethyl)phosphonate gave rise to 1,3-bis[(3,5-di-tert-butyl-4-hydroxyphenyl)-(dimethoxyphosphoryl)methyl]-4,6-dimethoxybenzene, which was oxidized to 1,3-bis[(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dienylidene)(dimethoxyphosphoryl)methyl]-4,6-dimethoxy-benzene. 相似文献
45.
Sergey N. Podyachev Svetlana N. Sudakova Bulat M. Gabidullin Victor V. Syakaev Aidar T. Gubaidullin Wim Dehaen Alexander I. Konovalov 《Tetrahedron letters》2012,53(25):3135-3139
A new strategy for the synthesis of bifunctional compounds, based on 1,3-alternate tetrathiacalix[4]arene precursors functionalized by pairs of carboxylic acid and ester groups located on opposite sides of the macrocycle platform is described. These building blocks were prepared by the Cs2CO3 induced selective hydrolysis of tetrathiacalix[4]arene tetraester derivatives. A mechanism for the selective hydrolysis is suggested. The structures of the compounds are elucidated by NMR spectroscopic analysis and X-ray single crystal diffraction. 相似文献
46.
B. I. Buzykin E. V. Mironova V. N. Nabiullin N. M. Azancheev L. V. Avvakumova I. Kh. Rizvanov A. T. Gubaidullin I. A. Litvinov V. V. Syakaev 《Russian Journal of General Chemistry》2008,78(3):461-479
New complexing agents, potentially tautomeric 3-(2-hydroxyethylsulfanyl)-1H-1,2,4-triazole, its 5-methyl-and 5-phenyl-substituted analogs, and some their salts, were synthesized, and their structure was discussed on the basis of the 1H and 13C NMR, IR, and mass spectra, X-ray diffraction data, and published data. In keeping with the rule formulated previously for N-unsubstituted 1,2,4-triazoles having dissimilar substituents, the synthesized compounds were found to exist as 3-(2-hydroxyethylsulfanyl)-5-R-1H-1,2,4-triazole tautomers (3-RA-5-RD-1H-1,2,4-triazoly). They are protonated at the nitrogen atom in position 4 of the triazole ring. The 1H and 13C NMR spectra of these compounds in trifluoroacetic acid suggest the presence of two forms due to equilibrium between the neutral and protonated species. Analysis of the crystallographic data for the triazolium salts and published data showed preference of the 1H,4H-1,2,4-triazolium tautomer. 相似文献
47.
Sergey N. Podyachev Viktor V. Syakaev Svetlana N. Sudakova Roald R. Shagidullin Darya V. Osyanina Ludmila V. Avvakumova Boris I. Buzykin Shamil K. Latypov Ingmar Bauer Wolf D. Habicher Alexander I. Konovalov 《Journal of inclusion phenomena and macrocyclic chemistry》2007,58(1-2):55-61
A series of new calix[4]phenols, calix[4]resorcinols and calix[4]pyrogallols with acetylhydrazide substitutes has been␣synthesized
with high yields by hydrazinolysis of ester group containing calix[4]arenes. The synthesized calix[4]phenols adopt the cone
conformation while the calix[4]resorcinol and calix[4]pyrogallol derivatives prefer the boat conformation. The amide fragment
of the hydrazide groups predominantly exists in the trans-conformation. The binding ability of synthesized calix[4]arenes toward transition and alkali metals by solvent extraction
has been investigated. 相似文献
48.
A. R. Mustafina Yu. G. Elistratova V. V. Syakaev R. R. Amirov A. I. Konovalova 《Russian Chemical Bulletin》2006,55(8):1419-1424
Concentration range of solubilization of calix[4]resorcinarene (H8L) in sodium dodecyl sulfate (SDS) micelles was found. The interaction of the deprotonated form of H8L (tetraanions [H4L]4−) with tetramethylammonium (TMA) and choline cations in micellar solutions of SDS was studied by pH-metry and NMR spectroscopy.
The concentration dependences of the change in the cloud point in a multicomponent system TMA (choline)-[H4L]4-SDS-tetrabutylammonium bromide were determined. A correlation of these dependences with host-guest binding processes was
found. The sharp change in the cloud points of the corresponding micellar solutions in concentration regions of TMA (0-5·10−4 mol L−1) and choline (0–1.1· 10−3 mol L−1) is caused by the formation of inclusion complexes TMA (choline)-[H4L]4− at the interface of the aqueous and micellar pseudophases.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1366–1371, August, 2006. 相似文献
49.
Liliya I. Vagapova Julia K. Voronina Victor V. Syakaev Alexander R. Burilov Airat R. Garifzyanov Mikhail A. Pudovik 《Mendeleev Communications》2018,28(4):398-400
2-Aryl-substituted pyrrolidines containing phosphine oxide group have been obtained by the reaction of P-(4,4-diethoxybutylaminomethyl)- P,P-di-p-tolylphosphine oxide with polyatomic phenols. 相似文献
50.
T. R. Shaekhov E. M. Gibadullina Yu. K. Voronina V. V. Syakaev D. R. Sharafutdinova A. R. Burilov M. A. Pudovik 《Russian Chemical Bulletin》2011,60(10):1999-2002
Diphenyl (3,5-di-tert-butyl-4-hydroxybenzyl)phosphonate was oxidized to the corresponding methylidenequinonoid derivative. The addition of phenols to the exocyclic double bond of this compound gave phosphonates with two phenol moieties. 相似文献