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71.
The 2D Ising model is well-formulated to address problems in adsorption thermodynamics. It is particularly well-suited to describing the adsorption isotherms predicting the surface enantiomeric excess, , observed during competitive co-adsorption of enantiomers onto achiral surfaces. Herein, we make the direct one-to-one correspondence between the 2D Ising model Hamiltonian and the Hamiltonian used to describe competitive enantiomer adsorption on achiral surfaces. We then demonstrate that adsorption from racemic mixtures of enantiomers and adsorption of prochiral molecules are directly analogous to the Ising model with no applied magnetic field, i.e., the enantiomeric excess on chiral surfaces can be predicted using Onsager’s solution to the 2D Ising model. The implication is that enantiomeric purity on the surface can be achieved during equilibrium exposure of prochiral compounds or racemic mixtures of enantiomers to achiral surfaces. 相似文献
72.
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74.
V.K. Sharma S. Mitra P. Maheshwari D. Dutta P.K. Pujari R. Mukhopadhyay 《The European physical journal. Special topics》2010,189(1):273-277
Dynamics of ethylene glycol (EG) adsorbed in H-ZSM5 zeolite as studied using quasielastic neutron scattering (QENS) technique
is reported here. Analysis of QENS data revealed that observed dynamics correspond to isotropic rotational motion of EG. Rotational
diffusion coefficient of EG adsorbed in H-ZSM5 zeolite is found to be slower compared to bulk and comparable to that of benzene
adsorbed in the same host. Positron Annihilation Spectroscopy (PAS) technique is used to understand the nature of guest-host
interaction and the results of both QENS and PAS are found to be consistent with each other. 相似文献
75.
This article illustrates the developments of effective preconcentration techniques and highly sensitive detection methods for accurate measurements of Tl species at extremely low concentration in aqueous solutions. The literature on this topic was taken from the Analytical Abstracts in the period 1990-2005. 相似文献
76.
Previously reported endovesicular reactions in the cleavage of -nitrophenyl diphenyl phosphate by hydroxide (or fluoride) ions in vesicles of dihexadecyldimethylammonium bromide appear to be artifacts. 相似文献
77.
The amount and extent of structural misaligments in natural graphite crystals have been determined, and the temperature variation of the basal plane electrical conductivity (σ⊥) of naturally occurring graphite has also been studied from 300 to 90 K. The conductivity (σ⊥) has been found to obey a law σ⊥α() down to a certain temperature θ (θ varying from sample to sample), below which the variation deviates from linearity towards lower values of σ⊥. This behaviour, which was earlier thought to be a characteristic of graphite and whose origin could not be traced, has been shown to be an effect of the structural misalignments usually present in natural samples of graphite. 相似文献
78.
By applying ultrasound at different frequencies and intensities through the bottom of a narrow tube containing liquids of varying physical properties, followed by critical analysis of the experimental data, a systematic study of the effect of these parameters on enhancement in rate of mass transfer has been made and a correlation has been proposed for prediction of such enhancement. 相似文献
79.
Parity-violating electron deuteron scattering and the proton's neutral weak axial vector form factor
Ito TM Averett T Barkhuff D Batigne G Beck DH Beise EJ Blake A Breuer H Carr R Clasie B Covrig S Danagoulian A Dodson G Dow K Dutta D Farkhondeh M Filippone BW Franklin W Furget C Gao H Gao J Gustafsson K Hannelius L Hasty R Hawthorne-Allen AM Herda MC Jones CE King P Korsch W Kowalski S Kox S Kramer K Lee P Liu J Martin JW McKeown RD Mueller B Pitt ML Plaster B Quéméner G Réal JS Ritter J Roche J Savu V Schiavilla R Seely J Spayde D Suleiman R Taylor S Tieulent R Tipton B Tsentalovich E 《Physical review letters》2004,92(10):102003
We report on a new measurement of the parity-violating asymmetry in quasielastic electron scattering from the deuteron at backward angles at Q2=0.038 (GeV/c)2. This quantity provides a determination of the neutral weak axial vector form factor of the nucleon, which can potentially receive large electroweak corrections. The measured asymmetry A=-3.51+/-0.57 (stat)+/-0.58 (syst) ppm is consistent with theoretical predictions. We also report on updated results of the previous experiment at Q2=0.091 (GeV/c)2, which are also consistent with theoretical predictions. 相似文献
80.
Sengupta T Dutta Choudhury S Basu S 《Journal of the American Chemical Society》2004,126(34):10589-10593
The interaction between 2'-deoxyadenosine and the model antitumor drug menadione has been studied in organic solvent and in micellar medium. The aim of the work is to elucidate the mechanism of this drug-nucleoside interaction and to determine the environmental effects. Laser flash photolysis and magnetic field effect are used to detect the transients and their spin states. The results indicate that H atom transfer and electron transfer are the operative mechanisms depending upon the medium. 相似文献