Ion-selective electrodes for the determination of ionic liquids in water using direct potentiometry

Ion-selective electrodes (ISEs) with membranes based on ion exchangers plasticized with o-nitrophenyl octyl ether (NPOE), diethyl sebacate (DES), or dibutyl phthalate (DBP) are used for the determination of ionic liquids (ILs) in water. The membrane composition is optimized with respect to the ion-exchanger concentration and the plasticizer.     

Brownian motion in a solitary potential well in a bounded solid structure

The motion of a heavy Brownian particle in a low-dimensional bounded solid structure under the effect of a phonon’s excitation fluctuations is considered. Because of the finiteness of the system, the fluctuation spectrum has zero spectral density at zero frequency. The effect of this kind of noise, which is conditionally called “green” noise, is studied both analytically by using the averaging method and numerically on the basis of predictor-corrector algorithms. The effective potential is introduced, and its form is shown to govern the particle dynamics. Considering a Gaussian potential well (a trap) as an example, it is demonstrated that green noise leads to abrupt phase transitions in the system as a result of very small parameter variations (a catastrophe-type effect). The results are compared with the case of white noise in an unbounded structure. From numerical calculations, it follows that the boundedness of the structure, which changes the noise spectrum, favors a considerable increase in the lifetime of the particle in the trap.     

Cross-sections of large-angle hadron production in proton–and pion–nucleus interactions V: lead nuclei and beam momenta from ±3 GeV/c to ±15 GeV/c

We report on double-differential inclusive cross-sections of the production of secondary protons, charged pions, and deuterons, in the interactions with a 5% λ _int thick stationary lead target, of proton and pion beams with momentum from ±3 GeV/c to ±15 GeV/c. Results are given for secondary particles with production angles 20°<θ<125°. Cross-sections on lead nuclei are compared with cross-sections on beryllium, copper, and tantalum nuclei.     

Systems with Discontinuous Quasi-Zero Reconstructing Force

The paper deals with the problem of constructing systems with discontinuous quasizero reconstructing force on the basis of structures where an elastic element moves between two directrices of prescribed design shape perpendicularly to their axis of symmetry. A spring is considered as an elastic element. The cases where the elastic element works only in compression or only in tension are considered.     

Comparison of Geant4 hadron generation with data from the interactions with beryllium nuclei of +8.9 GeV/c protons and pions and −8.0 GeV/c pions

Hadron generation in the Geant4 simulation tool kit is compared with inclusive spectra of secondary protons and pions from the interactions with beryllium nuclei of +8.9 GeV/c protons and pions, and of −8.0 GeV/c pions. The data were taken in 2002 at the CERN Proton Synchrotron with the HARP spectrometer. We report on significant disagreements between data and Monte Carlo simulation especially in the polar-angle distributions of secondary protons and pions. On leave of absence at Ecole Polytechnique Fédérale, Lausanne, Switzerland.     

Recovery of electrical-resistivity and viscoelasticity relaxation in thermally aged bulk Pd<Subscript>40</Subscript>Cu<Subscript>30</Subscript>Ni<Subscript>10</Subscript>P<Subscript>20</Subscript> metallic glass

The structural relaxation of a bulk Pd₄₀Cu₃₀Ni₁₀P₂₀ metallic glass is studied by measuring the electrical resistivity and infralow-frequency (0.05 Hz) internal friction. It is demonstrated that the structural relaxation in thermally aged samples can be restored by quenching them from a supercooled liquid state. It is found that the degree of relaxation after quenching can exceed the initial one by several times.