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991.
992.
Standardless multicomponent qNMR analysis of compounds with overlapped resonances based on the combination of ICA and PULCON 下载免费PDF全文
Yulia B. Monakhova Dirk W. Lachenmeier Thomas Kuballa Svetlana P. Mushtakova 《Magnetic resonance in chemistry : MRC》2015,53(10):821-828
A fast and reliable nuclear magnetic resonance (NMR) method for quantitative analysis of targeted compounds with overlapped signals in complex mixtures has been established. The method is based on the combination of chemometric treatment for spectra deconvolution and the PULCON principle (pulse length based concentration determination) for quantification. Independent component analysis (ICA) (mutual information least dependent component analysis (MILCA) algorithm) was applied for spectra deconvolution in up to six component mixtures with known composition. The resolved matrices (independent components, ICs and ICA scores) were used for identification of analytes, calculating their relative concentrations and absolute integral intensity of selected resonances. The absolute analyte concentrations in multicomponent mixtures and authentic samples were then calculated using the PULCON principle. Instead of conventional application of absolute integral intensity in case of undisturbed signals, the multiplication of resolved IC absolute integral and its relative concentration in the mixture for each component was used. Correction factors that are required for quantification and are unique for each analyte were also estimated. The proposed method was applied for analysis of up to five components in lemon and orange juice samples with recoveries between 90% and 111%. The total duration of analysis is approximately 45 min including measurements, spectra decomposition and quantification. The results demonstrated that the proposed method is a promising tool for rapid simultaneous quantification of up to six components in case of spectral overlap and the absence of reference materials. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
993.
E. S. Bobkova D. S. Krasnov A. V. Sungurova A. I. Shishkina T. G. Shikova 《High Energy Chemistry》2013,47(2):53-56
The degradation kinetics of phenol and the formation kinetics of its decomposition products in the liquid cathode (distilled water) of direct-current atmospheric-pressure discharge in air have been experimentally measured. The processes occurring in the liquid phase have been simulated on the basis of the previously proposed reaction kinetics scheme complemented by phenol decomposition reactions and the formation/decay reactions of its degradation products. 相似文献
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Dr. Céline Cepeda Dr. Laurent Raibaut Dr. Guillaume Fremy Dr. Svetlana V. Eliseeva Dr. Anthony Romieu Dr. Jacques Pécaut Dr. Didier Boturyn Prof. Dr. Stéphane Petoud Dr. Olivier Sénèque 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(59):13476-13483
The interest in ratiometric luminescent probes that detect and quantify a specific analyte is growing. Owing to their special luminescence properties, lanthanide(III) cations offer attractive opportunities for the design of dual-color ratiometric probes. Here, the design principle of hetero-bis-lanthanide peptide conjugates by using native chemical ligation is described for perfect control of the localization of each lanthanide cation within the molecule. Two zinc-responsive probes, r-LZF1Tb|Cs124|Eu and r-LZF1Eu|Cs124|Tb are described on the basis of a zinc finger peptide and two DOTA (DOTA=1,4,7,10-tetraaza-cyclododecane-1,4,7,10-tetraacetic acid) complexes of terbium and europium. Both display dual-color ratiometric emission in response to the presence of Zn2+. By using a screening approach, anthracene was identified for the sensitization of the luminescence of two near-infrared-emitting lanthanides, Yb3+ and Nd3+. Thus, two novel zinc-responsive hetero-bis-lanthanide probes, r-LZF3Yb|Anthra|Nd and r-LZF3Nd|Anthra|Yb were assembled, the former offering a neat ratiometric response to Zn2+ with emission in the near-infrared around 1000 nm, which is unprecedented. 相似文献
996.
Svetlana V. Kurmaz Natalia V. Fadeeva Vladislav M. Ignatev Vladimir A. Kurmaz Sergei A. Kurochkin Nina S. Emelyanova 《Molecules (Basel, Switzerland)》2020,25(24)
Hydrated copolymers of N-vinylpyrrolidone (VP) with triethylene glycol dimethacrylate as a promising platform for biologically active compounds (BAC) were investigated by different physical chemical methods (dynamic light scattering, infrared spectroscopy, thermal gravimetric analysis, and differential scanning calorimetry) and the quantum chemical modeling of water coordination by the copolymers in a solution. According to the quantum chemical simulation, one to two water molecules can coordinate on one O-atom of the lactam ring of VP units in the copolymer. Besides the usual terminal coordination, the water molecule can form bridges to bind two adjacent C=O groups of the lactam rings of VP units. In addition to the first hydration shell, the formation of a second one is also possible due to the chain addition of water molecules, and its structure depends on a mutual orientation of C=O groups. We showed that N,N-dimethylbiguanidine hydrochloride (metformin) as a frontline drug for the treatment of type 2 diabetes mellitus can be associated in aqueous solutions with free and hydrated C=O groups of the lactam rings of VP units in studied copolymers. Based on the characteristics of the H-bonds, we believe that the level of the copolymer hydration does not affect the behavior and biological activity of this drug, but the binding of metformin with the amphiphilic copolymer will delight in the penetration of a hydrophilic drug across a cell membrane to increase its bioavailability. 相似文献
997.
Polymerization of alkenes with a post‐metallocene catalyst containing a titanium complex with an oxyquinolinyl ligand 下载免费PDF全文
Laura А. Rishina Yury V. Kissin Svetlana S. Lalayan Svetlana Ch. Gagieva Vladislav А. Тuskaev Vadim G. Krasheninnikov 《Journal of polymer science. Part A, Polymer chemistry》2017,55(11):1844-1854
Polymerization reactions of ethylene, propylene, higher 1‐alkenes (1‐hexene, 1‐octene, 1‐decene, vinyl cyclohexane, 3‐methyl‐1‐butene), and copolymerization reactions of ethylene with 1‐octene with a post‐metallocene catalyst containing an oxyquinolinyl complex of Ti and a combination of Al(C2H5)2Cl and Mg(C4H9)2 as a cocatalyst were studied. The catalyst is highly active and, judging by the broad molecular weight distribution of the polymers, contains several active center populations. The active centers differ not only in their kinetic parameters but also in stereospecificity. Most of the active centers produce essentially atactic polypropylene but a small fraction of the centers produces polypropylene of moderate isotacticity degree. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 1844–1854 相似文献
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