Dissociative recombination of the deuterated acetaldehyde ion, CD3CDO(+): product branching fractions, absolute cross sections and thermal rate coefficient

Dissociative recombination of the deuterated acetaldehyde ion CD3CDO(+) has been studied at the heavy-ion storage ring CRYRING, located at the Manne Siegbahn Laboratory, Stockholm, Sweden. Product branching fractions together with absolute DR cross-sections were measured. The branching fractions were determined at a relative collision energy between the ions and the electrons of approximately 0 eV. With a probability of 34% the DR events resulted in no ruptures of bonds between heavy atoms (i.e. no breakage of the C-C bond or the C[double bond, length as m-dash]O bond). In the remaining 66% of the events one of the bonds between the heavy atoms was broken. The energy-dependent cross-section for the DR reaction was measured between approximately 0 and 1 eV relative kinetic energy. In the energy region between 1 meV and 0.2 eV the absolute cross section could be fitted by the expression sigma(E) = 6.8 x 10(-16)E(-1.28) cm(2), whereas in the energy interval between 0.2 and 1 eV the data were best fitted by sigma(E) = 4.1 x 10(-16)E(-1.60) cm(2). From these cross section data the thermal rate coefficient (as a function of the electron temperature), alpha(T) = 9.2 x 10(-7) (T/300)(-0.72) cm(3) s(-1) was obtained.     

Birefringence of high-pressure injection-molded high-density polyethylene at 70.5 μm wavelength

A newly constructed far-infrared laser interferometer was used to measure the birefringence of 1-mm-thick injection-molded high-density polyethylene test bars, manufactured at unusually high molding pressures. The long wavelength used, 70.5 μm, allowed nondestructive tests to be made, demonstrating the usefulness of far-infrared techniques for probing crystalline polymers. The birefringence was shown to increase with increasing molding pressure, supporting the belief that molecular orientation increases with increasing molding pressure. The tensile modulus was also measured and was found to increase linearly with molding pressure.     

Advanced Research Using New X-ray Sources

The Nordic summer school in synchrotron radiation science, Advanced Research Using New X-ray Sources, was held from June 13–21, 2011 in Sweden. The school was organized by MAX-lab with economic support from the Nordic Academy for Advanced Studies (NorFA) and the Swedish German Röntgen-Ångström consortium. The school was divided into two parts. The first lecture part was held at Odengården, a cosy conference facility in the countryside of Skåne, Sweden's most southern province, followed by practical exercises at the MAX-lab synchrotron radiation laboratory.     

Potentiometric Cholesterol Biosensor Based on ZnO Nanowalls and Stabilized Polymerized Lipid Film

A novel potentiometric cholesterol biosensor was fabricated by immobilization of cholesterol oxidase into stabilized lipid films using zinc oxide (ZnO) nanowalls as measuring electrode. Cholesterol oxidase was incorporated into the lipid film prior polymerization on the surface of ZnO nanowalls resulting in a sensitive, selective, stable and reproducible cholesterol biosensor. The potentiometric response was 57 mV/ decade concentration. The sensor response had no interferences by normal concentrations of ascorbic acid, glucose, and urea, proteins and lipids. The present biosensor could be implanted in the human body because of the biocompatibility of the lipid film.     

Timing jitter owing to intrachannel pulse interactions in dispersion-managed transmission systems

We study interaction-induced timing jitter in single-channel dispersion-managed return-to-zero ttransmission systems operating at high map strengths. An equation for the frequency and timing shifts of two interacting pulses is derived by a variational approach. The interaction can be of either an attractive or a repulsive character, and we show that the resultant timing jitter can be reduced by proper design of the dispersion map.     

On large transverse momentum production in high-energy proton-nucleus collisions

Experimental data from inclusive production of large p_T hadronsin high-energy proton-nucleus collisions are analysed with emphasis on the influence of the size of the target nucleus. It is found that data at p_T?3 GeV/c are consistent with the hypothesis that the incoming proton collides “simultaneously” with all the nucleons in its way, resulting in an effective collision energy larger than the one expected in a single proton-nucleon hit. At p_T > 3 GeV/c, data are in conflict with such a simple model, a result we think is a consequence of the dominance of hard parton collisions at very large p_T.     

Screening for biomarkers in plasma from patients with gangrenous and phlegmonous appendicitis using CE and CEC in combination with MS

Today a high degree of "false" appendicitis diagnoses are occurring. In this study, a screening experiment of biomarkers of two different kinds of appendicitis, gangrenous and phlegmonous, were conducted with CE and CEC coupled to MS. Plasma samples were obtained from patients pre- and post-surgery. A large amount of data was generated to be able to compare them, and chemometrics tools were utilized to visualize the differences. Indicative patterns were found for both pre- and post-surgery of the two types of inflammation as well as between them. The divergences were traced back to the MS peaks obtained in the CE- and CEC-MS setups as possible biomarkers for the two forms of appendicitis.     

单分子层修饰生物芯片基片的电化学研究

构建了一种亲和素单分子层修饰的电化学分析生物芯片基片，并且以二茂铁和亚铁氰化钾为指示剂对该基片的电化学性能进行了研究．循环伏安实验结果表明，单分子层的存在增强了二茂铁在基片上的响应电流，二茂铁可以作为该基片的高效电子媒介体，实验结果具有良好的重现性和一致性，基片产生的背景噪声可以忽略不计．文中对这些结果产生的原因进行了讨论．     

A Fourier-Coefficient Based Solution of an Optimal Control Problem in Quantum Chemistry

We consider an optimal control problem for the time-dependent Schrödinger equation modeling molecular dynamics. The dynamics can be steered by interactions with a tuned laser field. The problem of designing an optimal field can be posed as an optimal control problem. We reformulate the optimization problem by using a Fourier transform of the electric field, and narrow the frequency band. The resulting problem is less memory intense, and can be solved with a superlinearly convergent quasi-Newton method. We show computational results for a Raman-transition example and give numerical evidence that our method can outperform the standard monotonically convergent algorithm.