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401.
Insulin monoiodinated in Tyr A14, A19, B16 and B26 can be separated from insulin and diiodoinsulins using reversed-phase high-performance liquid chromatography on LiChrosorb RP-18 columns. Monoiodoinsulins with high and low specific activities were isolated from a number of buffer systems without any reduction in binding affinity and biological activity in isolated rat fat cells. The reason for the previously observed reduction in the binding affinity was probably column bleeding, i.e., chemical degradation of the column support. 相似文献
402.
403.
The temperature dependence of the lifetime of the excited 2T2 state of the Cu2+ ion in a LiTaO3 crystalline host has been measured with picosecond optical pulses. Its value ranges from 450 psec at 22°K to 10 psec at 423°K. Consistent with this result is the observation of weak fluorescence at 1.75 μm having a low temperature quantum efficiency of ~ 10?6. The experimental results are in reasonably good agreement with recent theoretical models based on strong coupling of the Cu2+ impurities to the host lattice. 相似文献
404.
405.
Linde H Velarde MG Waldhelm W Wierschem A 《Journal of colloid and interface science》2001,236(2):214-224
Collisions and reflections of solitary waves and (periodic) wave trains driven by surface tension gradients (Marangoni stresses) exhibit a wealth of astonishing features. Depending on the angle between the incoming wave crests, the outgoing waves show in their trajectories after collision negative phase shift for small enough angles, no phase shift at about pi/2 and hence no appreciable change in their trajectories, or positive phase shift, accompanied by the appearance of a phase-locked third wave or Mach-Russell stem at wider crossing angles. Synchronous wave collisions exhibit regular but complex dynamic network patterns whose formation and dependence on the size and the shape of the container are discussed. Although wave reflections share some of these features, corresponding apparently to the outcome of the virtual collision of a wave with its mirror image, there are significant differences that are described here. Copyright 2001 Academic Press. 相似文献
406.
T. Åkesson R. Aleksan B. Allanach S. Bertolucci A. Blondel J. Butterworth M. Cavalli-Sforza A. Cervera M. de Naurois K. Desch U. Egede R. Heuer A. Hoecker P. Huber K. Jungmann F. Linde A. Lombardi M. Mangano M. Mezzetto G. Onderwater N. Palanque-Delabrouille K. Peach A. Polosa E. Rondio B. Webber G. Weiglein J. Womersley 《The European Physical Journal C - Particles and Fields》2007,51(2):421-500
This document was prepared as part of the briefing material for the Workshop of the CERN Council Strategy Group, held in DESY
Zeuthen from 2nd to 6th May 2006. It gives an overview of the physics issues and of the technological challenges that will
shape the future of the field, and incorporates material presented and discussed during the Symposium on the European Strategy
for Particle Physics, held in Orsay from 30th January to 2nd February 2006, reflecting the various opinions of the European
community as recorded in written submissions to the Strategy Group and in the discussions at the Symposium. 相似文献
407.
To improve the classical Wigner (CW) model, we recently proposed the classical Wigner model with an effective quantum force (CWEQF). The results of the CWEQF model are more accurate than those of the CW model. Still the simplicity of the CW model is retained. The quantum force was obtained by defining a characteristic distance η(0) between two Feynman paths that enter the expression for the flux-flux correlation function. η(0) was considered independent of the position along the reaction path. The CWEQF leads to a lowering of the effective potential barrier. Here we develop the method to use position dependent η(0) values. The method is also generalized to two dimensions. Applications are carried out on one-dimensional model problems and the two-dimensional H + H(2) collinear reaction. 相似文献
408.
Dipl.‐Chem. Nicolas Dietl Dr. Xinhao Zhang Dipl.‐Chem. Christian van der Linde Prof. Dr. Martin K. Beyer Dr. Maria Schlangen Prof. Dr. Helmut Schwarz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(9):3017-3028
The reactivities of the adamantane‐like heteronuclear vanadium‐phosphorus oxygen cluster ions [VxP4?xO10].+ (x=0, 2–4) towards hydrocarbons strongly depend on the V/P ratio of the clusters. Possible mechanisms for the gas‐phase reactions of these heteronuclear cations with ethene and ethane have been elucidated by means of DFT‐based calculations; homolytic C? H bond activation constitutes the initial step, and for all systems the P? O. unit of the clusters serves as the reactive site. More complex oxidation processes, such as oxygen‐atom transfer to, or oxidative dehydrogenation of the hydrocarbons require the presence of a vanadium atom to provide the electronic prerequisites which are necessary to bring about the 2e? reduction of the cationic clusters. 相似文献
409.
Brask J Damstrup ML Nielsen PM Holm HC Maes J De Greyt W 《Applied biochemistry and biotechnology》2011,163(7):918-927
An integrated biodiesel process that combines enzymatic esterification and alkaline transesterification is suggested. With
focus on the enzymatic step, the paper provides proof of concept and suggestions for further process development. Hence, palm
fatty acid distillate (PFAD) has been enzymatically converted to fatty acid methyl esters in a two-step process using the
immobilized lipase Novozym 435 in packed-bed columns. With only a small excess of methanol, the first reaction stage could
reduce the free fatty acid (FFA) content from 85% to 5%. After removal of water by simple phase separation, it was possible
to lower the FFA content to 2.5% in a second reaction stage. Both reaction stages are relatively fast with suggested reaction
times of 15 min in column 1 (productivity 10 kg/kg/h) and 30 min in column 2 (productivity 5 kg/kg/h), resulting in 15% FFA
after column 1 and 5% FFA after column 2. A lifetime study indicated that approximately 3,500 kg PFAD/kg Novozym 435 can be
treated in the first reaction stage before the enzyme has become fully inactivated. With further optimization, the enzymatic
process could be a real alternative to today’s sulfuric acid catalyzed process. 相似文献
410.
Hollow-core photonic-crystal fibers are shown to enable dynamically phase-matched high-order harmonic generation by a gigawatt soliton pump field. With a careful design of the waveguide structure and an appropriate choice of input-pulse and gas parameters, a remarkably broadband phase matching can be achieved for a soliton pump field and a large group of optical harmonics in the soft-x-ray-extreme-ultraviolet spectral range. 相似文献