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91.
通过构造新的正对角因子元素,本文给出了几个判定非奇异H-矩阵新的充分条件,改进和推广了"一类非奇异H-矩阵判定的新条件"一文的主要结果,并用数值例子说明了文中结果判定范围的更加广泛性. 相似文献
93.
在多电子态模型下,利用二阶劈裂传播子算法计算了H2^+在强激光场中的离散行为。结果发现在高频场时分子的多光子离散碎片是近对称的,而对于低频场,在所考虑的激光强度下H2^+是被隧道离散的,因而其离散碎片H^+分布是反对称的,另外,文中还探讨了三脉冲形状对分子离解几率、离解碎片动力学行为的影响。 相似文献
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Jérémy Stemper Wei Tuo Eva Mazarío Ahmed S. Helal Alexandre Djurovic Claude Lion Jean-Michel El Hage Chahine François Maurel Miryana Hémadi Thierry Le Gall 《Tetrahedron》2018,74(21):2641-2649
Uranium pollution involves high toxicity and radioactivity and, therefore, constitutes a grave threat to human health and the environment. Chelation is an effective method for sequestering uranium. It is well known that chelators based on oxime groups are able to complex uranyl cations efficiently. To this end, various bis(amidoxime)s were synthesized by reaction of hydroxylamine with the corresponding dinitriles. In these compounds the amidoximes are separated by chains of various lengths, some including a heterocycle (pyridine or 1,3,5-triazine). The abilities of these bis(amidoxime)s to complex uranyl cation in water were evaluated by determining their affinity constants and thermodynamic parameters by means of Isothermal Titration Calorimetry (ITC). DFT calculations were also performed, to determine the optimum structures of the complexes formed between uranyl cations and the oximate groups. A tetrakis(amidoxime), also synthesized in this work, shows good affinity for uranium, and a single molecule is able chelate several uranyl cations. These results are of importance for the remediation of uranium-polluted wastewaters, and open up several perspectives for the design and synthesis of new amidoxime compounds. 相似文献
96.
Triethylene glycol-substituted 4-(N-methyl-N-Boc-amino)styrylpyridine which can serve as key precursor for many monodentate and multidentate imaging agents for Aβ plaques in human brain has been readily synthesized with cost-effective starting materials. The important non-radioactive monodentate positron emission tomography agent [F]florbetapir ([F]AV-45) has also been prepared by our new method. 相似文献
97.
The cover picture shows an efficient one‐pot condensation of maleimide derivatives in the presence of acetic acid and water to afford a series of benzene triimides (BTIs). The structure, physicochemical properties and electrochemistry behavior of BTIs were systematically investigated. Owing to the planar structure and unique electron‐deficient nature, BTIs can self‐assemble into different motifs. More details are discussed by Wang et al. on page 684–688.
98.
Tenghui Yuan Tuo Wang Gong Zhang Wanyu Deng Dongfang Cheng Hui Gao Jing Zhao Jia Yu Peng Zhang Jinlong Gong 《Chemical science》2022,13(27):8117
In the electrochemical CO2 reduction reaction (CO2RR), halide ions could impose a significant effect on multi-carbon (C2+) product production for Cu-based catalysts by a combined contribution from various mechanisms. However, the nature of specific adsorption of halide ions remains elusive due to the difficulty in decoupling different effects. This paper describes a facile method to actively immobilize the morphology of Cu-based catalysts during the CO2RR, which makes it possible to reveal the fundamental mechanism of specific adsorption of halide ions. A stable morphology is obtained by pre-reduction in aqueous KX (X = Cl, Br, I) electrolytes followed by conducting the CO2RR using non-buffered and non-specifically adsorbed K2SO4 as the supporting electrolyte, by which the change of local pH and cation concentration is also maintained during the CO2RR. In situ spectroscopy revealed that the specific adsorption of halide ions enhances the adsorption of *CO intermediates, which enables a high selectivity of 84.5% for C2+ products in 1.0 M KI.Reconstruction of catalyst morphology induced by halide ions over of Cu-based catalysts during CO2 electroreduction is suppressed using K2SO4 as supporting electrolyte. Adsorption of halide ions is an enabling factor to enhance CO2 electroreduction. 相似文献
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Recyclable and reusable NiCl2(PPh3)2/CuI/PEG‐400/H2O system for the sonogashira coupling reaction of aryl iodides with alkynes 下载免费PDF全文
A stable and highly efficient NiCl2(PPh3)2/CuI/PEG‐400/H2O catalytic system for the Sonogashira reaction has been developed. In the presence of NiCl2(PPh3)2 and CuI, the coupling reaction of aryl iodides with terminal alkynes was carried out smoothly in a mixture of poly(ethylene glycol) (PEG‐400) and water at 100°C with K2CO3 as base to afford a variety of arylacetylenes in good to excellent yields. The isolation of the products was readily performed by extraction with petroleum ether, and the NiCl2(PPh3)2/CuI/PEG‐400/H2O system could be easily recycled and reused six times without significant loss of catalytic activity. Our system not only avoids the use of easily volatile organic solvents but also solves the basic problem of catalyst reuse. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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