A new iridoid glucoside,10-O-veratroyleranthemoside(1) was isolated from the roots of Wendlandia tinctoria.The structure was established by spectroscopic(including 2D NMR) and chemical methods. 相似文献
Two naphthalene- and one anthracene-end-capped 4,4′-π-conjugated-2,2′-bipyridine chromophores have been synthesized via the Horner-Wordsworth-Emmons reaction protocol and their electronic absorption and emission properties have been examined. DFT and TD-DFT computational studies have been carried out in order to comprehend the role of steric factor over the electronic factor. 相似文献
Apolar aprotic solvents are particularly advantageous for investigating the intrinsic ortho effect free from complications of specific solvent effects. A kinetic study for toluene-phase proton transfers between ortho F, Cl, Br, I, OMe, OEt, OPh, OAc, Me, NO(2), COMe, COPh, OH, NH(2), and H benzoic acids and crystal violet carbinol base has shown the forward rate constant (log k(+1)) is the most appropriate reactivity parameter in toluene. log k(+1) (toluene) as compared to other reported reactivity parameters in benzene, toluene, or chlorobenzene has been found more sensitive to the ortho substituent effect. The regression results of the correlation of log k(+1) (toluene) of the acids (except OH and NH(2) substituted ones) according to seven ortho effect models are all very significant, and the best result is given by Fujita-Nishioka's model. The overall analysis reveals that a substituent's ortho effect pattern is a 58:24:18 ratio of its ordinary electrical, proximity electrical, and steric effects and that the proximity electrical effect is the major component to account for the peculiarity of the substituent's ortho effect. The results further favor the transmission of this effect mainly through the molecular cavity. The effect may, however, be outweighed by the steric component for bulky enough substituents, e.g., Me. The enhanced strength exhibited by salicylic acid in toluene has been quantitatively described using Pytela-Lis?ka's σ(HB)(i) parameter. The abnormally high log k(+1) observed for anthranilic acid in toluene has been ascribed to a very extensive homoconjugation in its acid-acid anion complex induced by the acid's three hydrogen bond donors. 相似文献
Stereoscopic porous microspheres based gellan gum (GG–Ca) were successfully prepared by sol–gel method using ethyl acetate as porogen and glutaraldehyde as crosslinker. The obtained GG–Ca microspheres were mainly of mesoporous with the average pore diameter was about 4 nm. It displayed a higher ability for uranium removal. In addition, the uranium adsorption process was endothermic and spontaneous following a pseudo-second-order and the adsorption isotherm was the best fit with the Freundlich model with maximum uranium capacity of 202.26 mg g−1. The UO2+ adsorption mechanism is ion-exchange with Ca2+ based on SEM, EDX and XPS data analysis.
The present study attempts to quantitatively estimate total potassium content in soil samples collected from different areas of Indian Sundarbans by gamma-spectrometry, exploiting the radiogenic properties of potassium and by wavelength dispersive X-ray fluorescence technique. The elemental K concentration varied in between 2.08 ± 0.05 and 3.46 ± 0.06% in the soil samples. Besides estimation of total potassium, the activity of 40K was also estimated in the same soil samples and found to be in the range of 532 ± 8.9 to 1043 ± 13.2 Bq kg−1.
Oxidative coupling of benzylamines with indoles to bis‐(indolyl)methanes (BIMs) was achieved using an inexpensive water‐soluble cobalt complex, Co(bpb). The catalyst was found to be quite effective when air was used as the oxidant and water as solvent under mild reaction conditions. Aromatic amines were successfully converted to the corresponding BIMs with yields up to 85 %. We have successfully carried out a 1 gram scale reaction, and few pharmaceutically relevant compounds were also synthesised by this method in good yields. Control experiments have also been carried out to understand the possible reaction mechanism. 相似文献
Coordination complexes of an olefinic molecule (PIP) containing pyridine and imidazopyridine moieties with ZnII/NiII metal salts were shown to exhibit appreciable proton conductivity. These complexes form 3D‐hydrogen bonded frameworks containing rhomboidal channels that are occupied by uncoordinated 1,5‐naphthalenedisulfonate (NDS). The extensive hydrogen bonding between the frameworks and NDS resulted in thermally stable and water‐insoluble materials. Irrespective of the metal atom present, both complexes exhibited moderate to high proton conduction in the range of 10?5 to 0.5×10?3 S cm?1 depending on the temperature and humidity levels. 相似文献