Distribution of melamine in polyester–melamine surface coatings cured under nonisothermal conditions

The influence of experimental cure parameters on the diffusion of reactive species in polyester–melamine thermoset coatings during curing has been investigated with X‐ray photoelectron spectroscopy and attenuated total reflectance Fourier transform infrared. The diffusion of melamine plays a vital role in the curing process and, therefore, in the ultimate properties of coatings. At a low (<20%) hexamethoxymethylmelamine (HMMM) crosslinker concentration, the matrix composition is uniform, but at high HMMM concentrations, excess HMMM rapidly segregates to the air–coating interface. The rate of migration is governed by the difference in the surface free energies of polyester and HMMM and the concentration gradient of HMMM between the bulk and the surface. An increased rate of energy absorption also increases the rate of migration of HMMM to the surface. A physical model has been proposed to explain this surface segregation phenomenon in terms of cocondensation and self‐condensation reactions. It suggests that an appropriate amount of melamine can be segregated on the surface and allowed to self‐condense to form a desired thickness of a melamine topcoat through the control of the binder composition and cure conditions. This technique can be implemented to apply a melamine topcoat during cure. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 83–91, 2004     

Parametric linear programming techniques for the indefnite quadratic programming problem

In this paper, we discuss a multiparametric technique for findinga global minimum for an indefinite quadratic programming problembased on the spectral decomposition of the matrix of the quadraticform. Special attention is given to the case where this matrixhas only rank 1, where the multiparametric linear program turnsout to be a single-parameter linear program. An extension ofthe traditional linear parametric procedure is introduced whichin general solves this problem efficiently. However, an exampleis presented showing that this technique may take an exponentialnumber of steps.     

Optimal repair-cost limit for a consumer following expiry of a warranty

This paper develops a methodology for obtaining the optimalrepair-cost limit for the repair-replace decision that a consumerfaces on the expiry of a product warranty, where the producthas been minimally repaired on failure during the warranty.Three cases are considered; (i) an exponentially distributedtime to failure with an arbitrary repair-cost distribution,(ii) an exponentially distributed time to failure with a uniformrepair-cost distribution, and (iii) a Weibull-distributed timeto failure with a beta-distributed repair cost. Numerical optimizationsare performed for the third case, and conclusions drawn as tothe sensitivity of the optimal repair-cost limit on the parametervalues of the distributions involved.     

Periodic solutions of second-order quasilinear hyperbolic equations

We study a periodic boundary-value problem for a quasilinear equation with the d'Alembert operator on the left-hand side and a nonlinear operator on the right-hand side and establish conditions under which the solution of the indicated problem is unique.Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 47, No. 10, pp. 1370–1375, October, 1995.     

High-frequency asymptotic behavior of the electromagnetic field on the surface of a stratified medium

Translated from Metody Matematicheskogo Modelirovaniya i Vychislitel'noi Diagnostiki, pp. 174–180, Izd. Moskovskogo Universiteta, Moscow, 1990.     

Construction of conformal,mappings of biconnected regions

The author's method for conformal mapping of simply connected circular regions of a special form is extended to biconnected regions. Examples are given to show that the solution of the problem for some common biconnected regions may be reduced to examining the corresponding simply connected regions with boundaries along straight lines and circles. The solutions given in this paper are convenient for generating numerical results.Translated from Vychislitel'naya i Prikladnaya Matematika, No. 58, pp. 71–75, 1986.     

On the analytical solutions of unstable surface layer similarity equations

Summary An approximate relationship between the gradient, Ri, and the bulk Richardson number, Ri_b, for unstable atmospheric conditions, is suggested. The proposed relation shows much better agreement with the estimation provided by a numerical iterative method than the usual approximations suggested by Louis and Byun.