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341.
Snehasish Mondal Achintya Jana Ranajit Bera Neeladri Das 《Journal of polymer science. Part A, Polymer chemistry》2017,55(22):3725-3735
Fluorescent materials have emerged as one of the promising candidates for chemical sensing due to their high sensitivity towards analytes that are relatively electron deficient such as nitroaromatics (NACs). Herein, four new 1,2,3‐triazole functionalized dibromo monomers ( 2‐5 ) have been synthesized. These dibromo monomers ( 2‐5 ) have been subsequently polymerized with 2,6‐diethynyltriptycene ( DET ) to yield four new ethynyl linked polymers ( P2‐P5 ) with 1,2,3‐triazole pendent. These polymers are organosoluble, amorphous in nature and have high thermal stability [Td > 289 °C and high char yield (>73%) at 800 °C]. Interestingly these new polymers ( P2‐P5 ) are highly fluorescent in solution (Φ = 0.37–0.43 in DCM) relative to the polymer ( P1 ) that does not have the 1,2,3‐triazole motif as a pendent. The host–guest interaction between these polymers ( P1‐P5 ) and electron deficient molecules (PA and C60) has been investigated. The Stern–Volmer quenching constant (KSV) data suggest that the interaction of picric acid and polymers increases significantly in presence of 1,2,3‐triazole linked pendent group whereas in case of C60, the KSV value decrease considerably in presence of 1,2,3‐triazole linked pendent. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 3725–3735 相似文献
342.
Dr. Mandeep Kaur Dr. Noor U Din Reshi Kamaless Patra Arindom Bhattacherya Dr. Sooraj Kunnikuruvan Prof. Jitendra K. Bera 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(41):10737-10748
A Cp*Ir(III) complex ( 1 ) of a newly designed ligand L1 featuring a proton-responsive pyridyl(benzamide) appended on N - heterocyclic carbene (NHC) has been synthesized. The molecular structure of 1 reveals a dearomatized form of the ligand. The protonation of 1 with HBF4 in tetrahydrofuran gives the corresponding aromatized complex [Cp*Ir(L1H)Cl]BF4 ( 2 ). Both compounds are characterized spectroscopically and by X-ray crystallography. The protonation of 1 with acid is examined by 1H NMR and UV-vis spectra. The proton-responsive character of 1 is exploited for catalyzing α-alkylation of ketones and β-alkylation of secondary alcohols using primary alcohols as alkylating agents through hydrogen-borrowing methodology. Compound 1 is an effective catalyst for these reactions and exhibits a superior activity in comparison to a structurally similar iridium complex [Cp*Ir(L2)Cl]PF6 ( 3 ) lacking a proton-responsive pendant amide moiety. The catalytic alkylation is characterized by a wide substrate scope, low catalyst and base loadings, and a short reaction time. The catalytic efficacy of 1 is also demonstrated for the syntheses of quinoline and lactone derivatives via acceptorless dehydrogenation, and selective alkylation of two steroids, pregnenolone and testosterone. Detailed mechanistic investigations and DFT calculations substantiate the role of the proton-responsive ligand in the hydrogen-borrowing process. 相似文献
343.
Soniya Rani Soumya Ranjan Dash Asish Bera Md Nirshad Alam Kumar Vanka Pradip Maity 《Chemical science》2021,12(26):8996
A phosphite mediated stereoretentive C–H alkylation of N-alkylpyridinium salts derived from chiral primary amines was achieved. The reaction proceeds through the activation of the N-alkylpyridinium salt substrate with a nucleophilic phosphite catalyst, followed by a base mediated [1,2] aza-Wittig rearrangement and subsequent catalyst dissociation for an overall N to C-2 alkyl migration. The scope and degree of stereoretention were studied, and both experimental and theoretical investigations were performed to support an unprecedented aza-Wittig rearrangement–rearomatization sequence. A catalytic enantioselective version starting with racemic starting material and chiral phosphite catalyst was also established following our understanding of the stereoretentive process. This method provides efficient access to tertiary and quaternary stereogenic centers in pyridine systems, which are prevalent in drugs, bioactive natural products, chiral ligands, and catalysts. N-Alkylpyridinium salt of chiral amines undergoes phosphite mediated stereoretentive migrations to generate chiral alkylpyridines. The role of phosphite on reactivity and stereoselectivity were examined to achieve a catalytic asymmetric version. 相似文献
344.
Aleksandar Radivojac Oskar Bera Zoran Zekovi Nemanja Tesli
ivan Mrkonji Danijela Bursa Kova
evi Predrag Putnik Branimir Pavli 《Molecules (Basel, Switzerland)》2021,26(10)
Consumers are becoming more mindful of their well-being. Increasing awareness of the many beneficial properties of peppermint essential oil (EO) has significantly increased product sales in recent years. Hydrodistillation (HD), a proven conventional method, and a possible alternative in the form of microwave-assisted hydrodistillation (MWHD) have been used to isolate peppermint EO. Standard Soxhlet and alternatively supercritical fluid (SFE), microwave-assisted, and ultrasound-assisted extraction separated the lipid extracts. The distillations employed various power settings, and the EO yield varied from 0.15 to 0.80%. The estimated environmental impact in terms of electricity consumption and CO2 emissions suggested that MWHD is an energy efficient way to reduce CO2 emissions. Different extraction methods and solvent properties affected the lipid extract yield, which ranged from 2.55 to 5.36%. According to the corresponding values of statistical parameters, empiric mathematical models were successfully applied to model the kinetics of MWHD and SFE processes. 相似文献
345.
A quantum pumping protocol through which the quasiparticles of Weyl/multi-Weyl and nodal-line semimetals are subjected to a time-periodic rectangular potential well is considered. The presence of an oscillating potential of frequency ω creates equispaced Floquet side-bands with spacing . As a result, a Fano resonance is observed when the difference in the Fermi energy (i.e., the energy of the incident quasiparticle), and the energy of one of the (quasi)bound state levels of the well, coincides with the energy of an integer number of photons (each carrying energy quantum ). Using the Floquet theory and the scattering matrix approach in the zero-temperature non-adiabatic pumping limit, characteristic Fano resonance patterns are found in the transmission coefficients. The inflection points in the pumped shot noise spectra also serve as a proxy for the corresponding Fano resonances. Therefore, the pumped shot noise is also numerically evaluated. Finally, the existence of the Fano resonance points is correlated to the (quasi)bound states of the well, by explicitly calculating the bound states of the static well (which are a subset of the bound states of the driven system). Since semimetals with anisotropic dispersions are considered, all the features observed depend on the orientation of the potential well. 相似文献