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11.
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A heterobimetallic supramolecular polymer (polyRuFe) with alternately complexed Ru(II) and Fe(II) is prepared following a stepwise synthetic route through harnessing first the strongly binding metal ion Ru(II) and then the weakly binding metal ion Fe(II). A high yield of product is achieved in each step. The heterometal ions are incorporated into the polymer chain in identical coordination environments formed by two 2,2′:6′,2″-terpyridine moieties. Characterization is accomplished by NMR spectroscopy, MALDI–TOF mass spectrometry, UV–Vis spectroscopy, and cyclic voltammetry. PolyRuFe shows a wide optical window (λ = 311–577 nm) and a broad distinct reversible redox nature of two types, originated from the coupling of the two heterometallic segments into the polymer chain. Such characteristics of polyRuFe suggest its potential for various electrochemical and electro-optical applications. 相似文献
13.
Samit Bera Bhaskar Das Arnab De Atish Barua Susmita Das Bratati De 《Natural product research》2020,34(4):599-603
AbstractThe methanolic extract of Cycas revoluta cone (MECR) was analyzed by GC-MS and UHPLC for metabolite profiling and was evaluated for anti-colon cancer property by using in vitro assays like Cell Viability Assay, Colony Formation Assay, ROS Determination, Flowcytometry, DAPI staining assay, Tunel assay. GC-MS and HPLC analysis confirmed the presence of different phytochemicals in the extract of Cycas revoluta cone. In-vitro studies showed MECR extract showed significant anti-colon cancer activity by reducing proliferation and inducing apoptosis in colon cancer cell (HCT-8) line, but no such activity was seen in normal colon cell (CCD-18Co) line. The investigation confirms that MECR may be a promising candidate in colon cancer protection. 相似文献
14.
Sudip Kumar Bera Sudipta Mondal Arijit Singha Hazari Jos Luis Priego Reyes Jimnez‐Aparicio Wolfgang Kaim Goutam Kumar Lahiri 《化学:亚洲杂志》2020,15(16):2532-2543
The dianion derived from (2Z,6Z)‐3,7‐diphenyl‐N2,N6‐di(pyridin‐2‐yl)pyrrolo[2,3‐f]indole‐2,6(1H,5H)‐diimine (H2BL), a modified BODIPY ligand precursor, is shown to be capable of bridging two metal complex fragments RuL2, L=2,4‐pentanedionato (acac?), 2,2’‐bipyridine (bpy) or 2‐phenylazopyridine (pap) in [Ru(acac)2Ru(μ‐BL)Ru(acac)2] ( 1 / 2 ), [Ru(bpy)2Ru(μ‐BL)Ru(bpy)2](ClO4)2 ([ 3 ](ClO4)2) and [Ru(pap)2Ru(μ‐BL)Ru(pap)2](ClO4)2 ([ 4 ](ClO4)2). The compounds, including a diastereoisomeric pair 1 (meso) and 2 (rac) were spectroscopically and structurally characterized. Reversible electron transfers as revealed by cyclic and differential pulse voltammetry allowed for an EPR and UV‐vis‐NIR spectroelectrochemical investigation of several neighboring charge states. Together with susceptibility measurements and TD‐DFT calculations the assignment of oxidation states reveals that 1 , 2 are diruthenium(III) species which can be oxidized or reduced by one electron whereas 3 2+ and 4 2+ contain ruthenium(II) and get reduced or oxidized mainly at the dianionic bridge ( 3 2+) or are reduced at the ancillary ligands pap ( 4 2+). 相似文献
15.
Subhasis Mallick Subala Mondal Arup Mandal Biplab K. Bera Parnajyoti Karmakar Alak K. Ghosh 《国际化学动力学杂志》2011,43(9):498-506
The kinetics of the interaction of three glycine‐containing dipeptides, namely, glycine‐L‐leucine (Gly‐Leu), glycine‐L‐isoleucine (Gly‐Ile), and glycine‐valine (Gly‐Val) with [Pt(en)(H2O)2](ClO4)2 has been studied spectrophotometrically as a function of [substrate complex], [dipeptides] and temperature at a particular pH(4.0), where the substrate complex exists predominantly as the diaqua species and the dipeptides as a zwitterion. The substitution reaction shows two consecutive steps; the first is the ligand‐assisted anation and the second is the chelation step. The activation parameters for both the steps were evaluated using Eyring's equation. The low ΔH1≠ and large negative value of ΔS1≠ as well as ΔH2≠ and ΔS2≠ indicate an associative mode of activation for both the aqua ligand substitution processes. © 2011 Wiley Periodicals, Inc. Int J Chem Kinet 43: 498–506, 2011 相似文献
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[reaction: see text] The first enantioselective syntheses of slagenins B and C, marine metabolites from Agelas nakamurai, starting from L-arabinose have been described. 相似文献
18.
An investigation is made of Rainich's ‘already unified field theory’ from the standpoint of continuous groups of motions, and a solution is obtained for the case where the electromagnetic field is non-static and the space-time admits a three-parameter continuous group of motions whose minimum invariant varieties are three-dimensional spaces. There exists a divergence-free electromagnetic field for values of t at which the metric is not singular. 相似文献
19.
Studies on CdS nanoparticles dispersed in silica matrix prepared by sol-gel technique 总被引:2,自引:0,他引:2
B. Bhattacharjee S.K. Bera D. Ganguli S. Chaudhuri A.K. Pal 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,31(1):3-9
SiO2/CdS-nanoparticle composite films (SiO2:CdS=85:15, 80:20, 75:25 and 70:30) were prepared by the sol-gel route. The films were characterized by studying microstructural
(XRD and TEM) and optical (transmittance and photoluminescence) properties. Band gaps of these films annealed at different
temperatures (373-473 K) for different times (10-120 min) indicated that the signature of nanocrystallinity is retained throughout
the range of our experimental conditions. A thermal diffusion process controlled growth in the crystallite size with increasing
annealing time and temperature. The average radii of the nanoparticles varied as the cube root of the annealing time but showed
exponential dependence on the inverse of annealing temperature. Photoluminescence (PL) studies of the composite films indicated
excitonic transitions. Theoretical analysis of the line shapes of the PL peaks recorded at 300 K and 80 K could be accounted
for by the combined effects of size distribution and phonon broadening. It was observed that the deformation potential (E
d) effectively controlled the line shapes of the PL measurements.
Received 24 May 2002 Published online 27 January 2003
RID="a"
ID="a"e-mail: msakp@mahendra.iacs.res.in 相似文献
20.
Rizet N Brissaud M Gonnard P Bera JC Sunyach M 《The Journal of the Acoustical Society of America》2000,107(4):2061-2067
An active control system was developed to control the flexural vibrations of a beam with a modal filtering with only one secondary actuator. Segmented piezoelectric actuators and sensors were used for driving and sensing the bending beam vibrations. The primary actuator was fed by a broadband random disturbance signal in order to excite the first five modes of the structure. However, only the second to fifth modes were controlled. The control algorithm was implemented on a DSP board and the input and output signals were filtered using high order low pass filters. These filters, implemented on the DSP board avoid the degrading effect on the control performances of the higher order modes and which are not controlled. The modal filtering was achieved by computing. To this end, it is based on a previous identification procedure. This latter models, in one step, the dynamics of the structure and also the transfer function of the electronic circuits of the controller. The identified filtered modes were then used to compute the gain matrix using a LQR technique (linear quadratic regulator). Simulations of the active control were carried out and practical implementation of the control algorithms was performed. Experimental and simulation results were then compared and discussed. 相似文献