The D′ → A′ transition in Br2

A vibrational and rotational analysis is presented for the D′ → A′ transition (2800–2950 Å) of Br₂. The analysis includes 11 rotationally analyzed bands for ⁷⁹Br₂ and 3 for ⁸¹Br₂, plus bandheads for 70 additional v′-v″ bands of ⁷⁹Br₂, ⁸¹Br₂, and ⁷⁹Br⁸¹Br. The latter include some violet-degraded and spikelike features at the long-wavelength end of the spectrum, which are interpreted and assigned with the aid of band profile simulations. The assigned features are fitted directly to 14 vibrational and rotational expansion parameters for the two electronic states, from which the following spectroscopic constants are obtained: ΔT_e = 35706 cm^?1, ω′_e = 150.86 cm^?1, ω″_e = 165.2 cm^?1, B′_e = 0.042515 cm^?1, B″_e = 0.05944 cm^?1, $\text{R′}{}_{\mathrm{e}}\text{= 3.170}\text{A}\text{?}$, $\text{R″}{}_{\mathrm{e}}\text{= 2.681}\text{A}\text{?}$. The spectroscopic parameters are used to calculate RKR potentials and Franck-Condon factors for the transition.     

Observation of different azimuthal emission patterns of K+ and of K- mesons in heavy-ion collisions at 1-2 A GeV

Azimuthal distributions of pi+, K+, and K- mesons have been measured in Au+Au reactions at 1.5A GeV and Ni+Ni reactions at 1.93 A GeV. In semicentral collisions at midrapidity, pi+ and K+ mesons are emitted preferentially perpendicular to the reaction plane in both collision systems. In contrast for K- mesons in Ni+Ni reactions, an in-plane elliptic flow was observed for the first time at these incident energies.     

Polymerization of N-acryloyl pyrrolidone and synthesis of graft copolymer by using the mechanism of initiation of anionic ring-opening polymerization

N-acryloyl pyrrolidone (NAP) was synthesized by reaction of pyrrolidone with acryloyl chloride. First, the polymerization of NAP and copolymerization of NAP with styrene (St) were carried out at 60°C, using 2,2′-azobisisobutyronitrile (AIBN) as an initiator. Kinetic studies showed that the rate of polymerization (R_p) could be expressed by R_p = K [AIBN]^0.5 [NAP]^1.0. The reactivity of NAP was found to be larger than that of N-methacryloyl pyrrolidone. The overall activation energy was calculated to be 24.3 kcal mole^?1. The following monomer reactivity ratio and Q and e values were obtained. NAP(M₁)—St(M₂): r₁ = 1.50, r₂ = 0.35, Q₁ = 0.42, and e₁ = 1.60. Second, graft copolymers were synthesized by reacting pyrrolidone, in the presence of a catalytic amount of its potassium salt, with poly(NAP-co-St).     

Study ofγ radiation from100Pd decay

This paper presents a study of the rays from the electron capture decay of 3.63d ¹⁰⁰Pd. Singles and coincidence measurements provided an accurate determination of-ray intensities and an improved knowledge of the¹⁰⁰Rh level scheme. Experimental evidence supports excitation of levels in¹⁰⁰Rh at 86-, 136- and 154 keV, not previously reported from the decay of¹⁰⁰Pd.On leave from Departamento de Fisica, Comision Nacional de Energia Atomica, Buenos Aires, Argentina     

Chemistry of Peri-condensed pyrroles. Synthesis of 4H-naphtho[1,4-def]carbazole. A new route to nitrotriphenylenes

Reaction of 1-nitrotriphenylene ( 7a ) with triethylphosphite (Cadogan reaction) produces 4H-naphtho[1,4-def]carbazole, a likely component of fossil fuels. Surprisingly 7a and its 2-isomer are obtained from treatment of triphenylene with sulfuric acid/trifluoroacetic anhydride in nitromethane. Correlation between ultraviolet spectra and substitution reactions in peri-condensed pyrroles and thiophenes is presented.     

Titrimetrische Bestimmung von Magnesium mit ÄDTA in äthanolhaltiger Lösung

Zusammenfassung Eine makro- und mikrotitrimetrische Methode zur Bestimmung von Magnesium mit ÄDTA in 60%iger äthanolischer Lösung gegen Methylthymolblau wurde ausgearbeitet. Durch Anwendung von Äthanol wird der Farbwechsel verschärft, die Indikatorblockierung durch Spuren von Kupfer(II) beseitigt und die Ergebnisse verbessert.

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Summary A macro- and micro-titrimetric method has been developed for the determination of magnesium with EDTA in 60% ethanolic solution using methylthymol blue as indicator. The use of ethanol sharpens the color change, the blocking of the indicator by traces of copper is eliminated, and the results improved.

     

Monte Carlo studies of percolation phenomena for a simple cubic lattice

The site-percolation problem on a simple cubic lattice is studied by the Monte Carlo method. By combining results for periodic lattices of different sizes through the use of finite-size scaling theory we obtain good estimates forp _c (0.3115±0.0005), (0.41±0.01), (1.6±0.1), and(0.8±0.1). These results are consistent with other studies. The shape of the clusters is also studied. The average surface area for clusters of sizek is found to be close to its maximal value for the low-concentration region as well as for the critical region. The percentage of particles in clusters of different sizesk is found to have an exponential tail for large values ofk forP <p _c. Forp >p _c there is too much scatter in the data to draw firm conclusions about the size distribution.Work supported in part by USAFOSR Grant #73-2430B and by ERDA #E(11-1)-3077.