全文获取类型
收费全文 | 675篇 |
免费 | 24篇 |
国内免费 | 4篇 |
专业分类
化学 | 529篇 |
晶体学 | 29篇 |
力学 | 11篇 |
数学 | 26篇 |
物理学 | 108篇 |
出版年
2024年 | 2篇 |
2023年 | 7篇 |
2022年 | 11篇 |
2021年 | 22篇 |
2020年 | 13篇 |
2019年 | 23篇 |
2018年 | 22篇 |
2017年 | 19篇 |
2016年 | 27篇 |
2015年 | 19篇 |
2014年 | 25篇 |
2013年 | 67篇 |
2012年 | 46篇 |
2011年 | 54篇 |
2010年 | 29篇 |
2009年 | 34篇 |
2008年 | 36篇 |
2007年 | 41篇 |
2006年 | 42篇 |
2005年 | 30篇 |
2004年 | 25篇 |
2003年 | 21篇 |
2002年 | 12篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 6篇 |
1996年 | 6篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1989年 | 1篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1973年 | 3篇 |
1969年 | 1篇 |
1967年 | 2篇 |
1959年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有703条查询结果,搜索用时 0 毫秒
31.
Libby Yoerg M. Ellen Matthews Lakshmi Kaza Naullage Indika Perera David W. Ball John Moran Alan T. Riga 《Journal of Thermal Analysis and Calorimetry》2012,108(1):19-24
Three aldohexose monosaccharides, d-glucose, d-mannose, and d-galactose, were examined by scanning temperature dielectric analysis (DEA) from ambient temperatures through their melts.
Phase transitions, including glass transition (T
g) and melting temperature (T
m), were evaluated by differential scanning calorimetry (DSC). The monosaccharides were found to exhibit thermally-induced
dielectric loss spectra in their amorphous-solid phase before melting. Activation energies for electrical charging of each
of the monosaccharides were calculated from an Arrhenius plot of the tan delta (e″/e′, dielectric loss factor/relative permittivity) peak frequency versus reciprocal temperature in Kelvin. The DEA profiles
were also correlated with the DSC phase diagrams, showing the changes in electrical behavior associated with solid–solid and
solid–liquid transitions. 相似文献
32.
Langan TJ Nyakubaya VT Casto LD Dolan TD Archer-Hartmann SA Yedlapalli SL Sooter LJ Holland LA 《Electrophoresis》2012,33(5):866-869
The binding affinity of 17β-estradiol with an immobilized DNA aptamer was measured using capillary electrophoresis. Estradiol captured by the immobilized DNA was injected into the separation capillary using pH-mediated sample stacking. Stacked 17β-estradiol was then separated using micellar electrokinetic capillary chromatography and detected with UV-visible absorbance. Standard addition was used to quantify the concentration of estradiol bound to the aptamer. Following incubation with immobilized DNA, analysis of free and bound estradiol yielded a dissociation constant of 70 ± 10 μM. The method was also used to screen binding affinity of the aptamer for estrone and testosterone. This study demonstrates the effectiveness of capillary electrophoresis to assess the binding affinity of DNA aptamers. 相似文献
33.
Bag P Dutta S Biswas P Maji SK Flörke U Nag K 《Dalton transactions (Cambridge, England : 2003)》2012,41(12):3414-3423
A series of mononuclear lanthanide(III) complexes [Ln(LH(2))(H(2)O)(3)Cl](ClO(4))(2) (Ln = La, Nd, Sm, Eu, Gd, Tb, Lu) of the tetraiminodiphenolate macrocyclic ligand (LH(2)) in 95 : 5 (v/v) methanol-water solution fix atmospheric carbon dioxide to produce the carbonato-bridged trinuclear complexes [{Ln(LH(2))(H(2)O)Cl}(3)(μ(3)-CO(3))](ClO(4))(4)·nH(2)O. Under similar conditions, the mononuclear Y(III) complex forms the dimeric compound [{Y(LH(2))(H(2)O)Cl}(μ(2)-CO(3)){Y(LH(2))(H(2)O)(2)}](ClO(4))(3)·4H(2)O. These complexes have been characterized by their IR and NMR ((1)H, (13)C) spectra. The X-ray crystal structures have been determined for the trinuclear carbonato-bridged compounds of Nd(III), Gd(III) and Tb(III) and the dinuclear compound of Y(III). In all cases, each of the metal centers are 8-coordinate involving two imine nitrogens and two phenolate oxygens of the macrocyclic ligand (LH(2)) whose two other imines are protonated and intramolecularly hydrogen-bonded with the phenolate oxygens. The oxygen atoms of the carbonate anion in the trinuclear complexes are bonded to the metal ions in tris-bidentate μ(3)-η(2):η(2):η(2) fashion, while they are in bis-bidentate μ(2)-η(2):η(2) mode in the Y(III) complex. The magnetic properties of the Gd(III) complex have been studied over the temperature range 2 to 300 K and the magnetic susceptibility data indicate a very weak antiferromagnetic exchange interaction (J = -0.042 cm(-1)) between the Gd(III) centers (S = 7/2) in the metal triangle through the carbonate bridge. The luminescence spectral behaviors of the complexes of Sm(III), Eu(III), and Tb(III) have been studied. The ligand LH(2) acts as a sensitizer for the metal ions in an acetonitrile-toluene glassy matrix (at 77 K) and luminescence intensities of the complexes decrease in the order Eu(3+) > Sm(3+) > Tb(3+). 相似文献
34.
Molybdenyl(VI) acetylacetonate is an effective catalyst for the protective tetrahydropyranylation of alcohols and phenols. 相似文献
35.
Molybdenyl(VI) acetylacetonate is an effective catalyst for the deprotection of acetals into the corresponding aldehydes and ketones, in good yields. 相似文献
36.
Increasing the stability of perovskite solar cells is one of the most important tasks in the photovoltaic industry. Thus, the structural, energetic, and electronic properties of pure CH3NH3PbI3 and fully doped compounds (CH3NH3PbBr3 and CH3NH3PbCl3) in cubic and tetragonal phases were investigated using density functional theory calculations. We also considered the effects of mixed halide perovskites CH3NH3PbI2X (where X = Br and Cl) and compared their properties with CH3NH3PbI3. The DFT results indicate that the phase transformation from tetragonal to cubic phase decreases the band gap. The calculated results show that the X‐site ion plays a vital role in the geometrical stability and electronic levels. An increase in the band gap and a reduction in the lattice constants are more apparent in CH3NH3PbI2X compounds (I > Br > Cl). 相似文献
37.
Selvaraj Vishnuprasad Morri Bindusai Nair Lakshmi M. Krishnan Haribabu 《Journal of Thermal Analysis and Calorimetry》2019,137(5):1527-1536
Journal of Thermal Analysis and Calorimetry - Low thermal conductivity is a primary issue in the development of efficient heat transfer fluids and materials required for the thermal management of... 相似文献
38.
Stacey M. Frumm Zi Peng Fan Kenneth N. Ross Jeremy R. Duvall Supriya Gupta Lynn VerPlank Byung-Chul Suh Edward Holson Florence F. Wagner William B. Smith Ronald M. Paranal Christopher F. Bassil Jun Qi Giovanni Roti Andrew L. Kung James E. Bradner Nicola Tolliday Kimberly Stegmaier 《Chemistry & biology》2013,20(5):713-725
39.
40.
Rabindra N. Roy Lakshmi N. Roy Jason G. Grant Mason P. Cummins Bennett J. Tabor III Sarah J. Richards Curtis A. Himes Bret R. Lively Penny L. Blackwell Ashley N. Simon 《Journal of solution chemistry》2002,31(11):861-872
The values of the second dissociation constant, pK
2, for the dissociation of the NH+ charge center of the zwitterionic buffer compounds 4-(N-morpholino)butanesulfonic acid (MOBS), and N-(2-hydroxyethyl)piperazine-N-4-butanesulfonic acid (HEPBS) have been determined from 5 to 55°C, including, 37°C at intervals of 5°C. The electromotive-force (emf) measurements have been made utilizing hydrogen electrodes and silver–silver chloride electrodes. The value of pK
2 for MOBS was found to be 7.702 ± 0.0005, and 8.284 ± 0.0004 for HEPBS, at 25°C, respectively. The related thermodynamic quantities, G
o, H
o, S
o, and C
p
o for the dissociation processes of MOBS and HEPBS have been derived from the temperature coefficients of pK
2. Both the MOBS and HEPBS buffer materials are useful as primary pH standards for the control of pH 7.3 to 8.6 in the region close to that of physiological fluids. 相似文献