全文获取类型
收费全文 | 23447篇 |
免费 | 838篇 |
国内免费 | 65篇 |
专业分类
化学 | 15110篇 |
晶体学 | 381篇 |
力学 | 727篇 |
综合类 | 1篇 |
数学 | 1844篇 |
物理学 | 6287篇 |
出版年
2023年 | 239篇 |
2022年 | 589篇 |
2021年 | 540篇 |
2020年 | 603篇 |
2019年 | 728篇 |
2018年 | 655篇 |
2017年 | 637篇 |
2016年 | 931篇 |
2015年 | 651篇 |
2014年 | 1086篇 |
2013年 | 1943篇 |
2012年 | 1570篇 |
2011年 | 1731篇 |
2010年 | 1122篇 |
2009年 | 952篇 |
2008年 | 1130篇 |
2007年 | 1123篇 |
2006年 | 872篇 |
2005年 | 756篇 |
2004年 | 609篇 |
2003年 | 471篇 |
2002年 | 426篇 |
2001年 | 257篇 |
2000年 | 240篇 |
1999年 | 183篇 |
1998年 | 125篇 |
1997年 | 153篇 |
1996年 | 180篇 |
1995年 | 170篇 |
1994年 | 166篇 |
1993年 | 183篇 |
1992年 | 214篇 |
1991年 | 156篇 |
1990年 | 145篇 |
1989年 | 162篇 |
1988年 | 135篇 |
1987年 | 136篇 |
1986年 | 117篇 |
1985年 | 172篇 |
1984年 | 187篇 |
1983年 | 135篇 |
1982年 | 143篇 |
1981年 | 134篇 |
1980年 | 143篇 |
1979年 | 146篇 |
1978年 | 149篇 |
1977年 | 135篇 |
1976年 | 96篇 |
1975年 | 94篇 |
1974年 | 93篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
71.
Homopolymerization of methyl methacrylate (MMA) was carried out in the presence of triphenylstibonium 1,2,3,4-tetraphenyl-cyclopentadienylide
as an initiator in dioxane at 65°C±0·l°C. The system follows non-ideal radical kinetics (R
p
∝ [M]1·4 [I]0·44
@#@) due to primary radical termination as well as degradative chain-transfer reaction. The overall activation energy and average
value ofk
2
p
/k
t
were 64 kJmol−1 and 0.173 × 10−3 1 mol−1 s−1 respectively 相似文献
72.
M. Singh 《Journal of the Iranian Chemical Society》2006,3(4):334-339
Using upper consolute temperatures (UCT) and corresponding consolute compositions (CC) of water-phenol systems with each of 0.1 mol kg?1 salts and acids, 1.0% polyethylene glycol 200, 0.01 mol kg?1 surfactant and aromatic compounds, we obtained 0.01 mol kg?1 CaF2 and CrCl3 compositions. Focusing on UCT and CC, the role of valence electrons and shell number, basicity, hydrophilic, hydrophobic and π conjugated electrons of corresponding additives are reported. The surfactants and π conjugation electrons are noted to decrease the UCT in a constant ratio that depicts the state and inherent strength of ionic and molecular-water interactions. The data are useful in the investigation of cloud points of immiscible solutions based on the Hofmeister series. 相似文献
73.
A short and efficient enantioselective synthesis of sulfobacin A has been achieved using the Sharpless asymmetric dihydroxylation and the regiospecific nucleophilic opening of a cyclic sulfate as the key steps. 相似文献
74.
75.
A (p, q)-sigraph S is an ordered pair (G, s) where G = (V, E) is a (p, q)-graph and s is a function which assigns to each edge of G a positive or a negative sign. Let the sets E
+ and E
– consist of m positive and n negative edges of G, respectively, where m + n = q. Given positive integers k and d, S is said to be (k, d)-graceful if the vertices of G can be labeled with distinct integers from the set {0, 1, ..., k + (q – 1)d such that when each edge uv of G is assigned the product of its sign and the absolute difference of the integers assigned to u and v the edges in E
+ and E
– are labeled k, k + d, k + 2d, ..., k + (m – 1)d and –k, – (k + d), – (k + 2d), ..., – (k + (n – 1)d), respectively.In this paper, we report results of our preliminary investigation on the above new notion, which indeed generalises the well-known concept of (k, d)-graceful graphs due to B. D. Acharya and S. M. Hegde. 相似文献
76.
Raj Gandhi Kamales Kar S. Uma Sankar Abhijit Bandyopadhyay Rahul Basu Pijushpani Bhattacharjee Biswajoy Brahmachari Debrupa Chakraborti M. Chaudhury J. Chaudhury Sandhya Choubey E. J. Chun Atri Desmukhya Anindya Datta Gautam Dutta Sukanta Dutta Anjan Giri Sourendu Gupta Srubabati Goswami Namit Mahajan H. S. Mani A. Mukherjee Biswarup Mukhopadhyaya S. N. Nayak M. Randhawa Subhendu Rakshit Asim K. Ray Amitava Raychaudhuri D. P. Roy Probir Roy Suryadeep Roy Shiv Sethi G. Sigl Arunansu Sil N. Nimai Singh Mark Vagins Urjit Yagnik 《Pramana》2003,60(2):405-409
This is the report of neutrino and astroparticle physics working group at WHEPP-7. Discussions and work on CP violation in
long baseline neutrino experiments, ultra high energy neutrinos, supernova neutrinos and water Cerenkov detectors are discussed. 相似文献
77.
An age-dependent branching process where disasters occur as a renewal process leading to annihilation or survival ofall the cells, is considered. For such a process, the total mean sojourn time of all the cells in the system is analysed using the regeneration point technique. The mean number of cells which die in timet and its asymptotic behaviour are discussed. When the disasters arrival as a Poisson process and the lifetime of the cells follows exponential distribution, elegant inter-relationships are found among the means of (i) the total number of cells which die in timet (ii) the total sojourn time of all cells in the system upto timet and (iii) the number of living cells at timet. Some of the existing results are deduced as special cases for related processes. 相似文献
78.
The effect of solar features on geospheric conditions leading to geomagnetic storms (GMSs) with planetary index,A
P ≥ 20 and the range of horizontal component of the Earth’s magnetic fieldH such that 250γ <H < 400γ has been investigated using interplanetary magnetic field (IMF), solar wind plasma (SWP) and solar geophysical data
(SGD) during the period 1978–99. Statistically, it is observed that maximum number of GMSs have occurred during the maximum
solar activity years of 21st and 22nd solar cycles. A peculiar result has been observed during the years 1982, 1994 when sunspot
numbers (SSNs) decrease very rapidly while numbers of GMSs increase. No distinct association between yearly occurrence of
disturbed days and SSNs is observed. Maximum number of disturbed days have occurred during spring and rainy seasons showing
a seasonal variation of disturbed days. No significant correlation between magnitude (intensity) of GMSs and importance ofH
α
, X-ray solar flares has been observed. Maximum number of GMSs is associated with solar flares of lower importance, i.e.,
SF during the period 1978-93.H
α
, X-ray solar flares occurred within lower helio-latitudes, i.e., (0–30)°N to (0–30)°S are associated with GMSs. NoH
α
, X-ray solar flares have occurred beyond 40°N or 40°S in association with GMSs. In helio-latitude range (10–40)°N to (10–40)°S,
the 89.5% concentration of active prominences and disappearing filaments (APDFs) are associated with GMSs. Maximum number
of GMSs are associated with solar flares. Coronal mass ejections (CMEs) are related with eruptive prominences, solar flares,
type IV radio burst and they occur at low helio-latitude. It is observed that CMEs related GMS events are not always associated
with high speed solar wind streams (HSSWSs). In many individual events, the travel time between the explosion on the Sun and
maximum activity lies between 58 and 118 h causing GMSs at the Earth. 相似文献
79.
80.
This study presents a method of adaptive identification of parameters describing Sugeno fuzzy inference system in presence of bounded disturbances while maintaining the readability and interpretability of the fuzzy model during and after identification. This method do not require any a priori knowledge of a bound on the disturbance and noise and of a bound on the unknown parameters values. The method can be used for the robust and adaptive identification of slowly time varying nonlinear systems using fuzzy inference systems. The suggested method was used to build a fuzzy expert system that approximates the functional relationship between physical fitness and some of the measurable physiological parameters by their real measurements and opinion (human-experiences) of a medical expert. 相似文献