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The pressure dependence of the direct and indirect bandgap of epitaxial In0.52Al0.48As on InP(001) substrate has been measured using photoluminescence up to 92 kbar hydrostatic pressure. The bandgap changes
from Γ toX at an applied pressure of ∼ 43 kbar. Hydrostatic deformation potentials for both the Γ andX bandgaps are deduced, after correcting for the elastic constant (bulk modulus) mismatch between the epilayer and the substrate.
For the epilayer we obtain
and+(2.81±0.15)eV for the Γ andX bandgaps respectively. From the pressure dependence of the normalized Γ-bandgap photoluminescence intensity a Γ-X lifetime ratio, (τΓ/τ
X
), of 4.1×10−3 is deduced. 相似文献
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Fukuji Higashi Chong Su Cho Hideo Kakinoki Osao Sumita 《Journal of polymer science. Part A, Polymer chemistry》1977,15(10):2303-2309
Semiconducting organic polymer was obtained by the modification of polyacrylamide (PAAm)–Cu++ chelate with iodine in acetone. Favorable conditions for preparing the chelate effective for the conduction were investigated. Surface resistivities were affected by the amounts of cupric salts and iodine, satisfactory results being given by about 25 wt % of the salts based on PAAm and more than 1 wt % of iodine on the chelate. The conductivity was also varied with the degree of neutralization of the chelate in solution, and optimal values were obtained by addition of about an equimolar amount of potassium hydroxide to cupric salts. Effective structures of the polymer chelate in solution were assumed on the basis of the visible and the NMR spectra and potentiometric titration. 相似文献
27.
S. Y. Cho O. D. Awh Y. J. Chung Y. S. Chung 《Journal of Radioanalytical and Nuclear Chemistry》1997,217(1):107-109
A nondestructive instrumental neutron activation technique was used to analyze human hair samples collected from people living in metropolitan and rural areas in Korea. Samples were also collected from factory workers and cancer patients. Hair from metropolitan area residents contain higher concentrations of Ca, Mg, Zn, Cu, Na, Br, Mn, I and S than rural area residents. Concentrations of I and S from cancer patients, Mg, Zn, Al, Na, Mn and As from glassware workers were relatively higher. The results show that the trace element concentrations of the hair are possibly related to the trace element concentrations in the body. 相似文献
28.
A nonenzymatic glucose sensor with good selectivity for the ascorbic acid oxidation is presented. After the gold polycrystalline electrode was subjected to amalgamation treatment, two advantageous effects were observed. One is the enhancement of the surface roughness and the other is an increase in the catalytic current in the glucose oxidation. Besides the known first effect, the latter provided another advantageous effect in a fabrication of nonenzymatic glucose sensor. Using a gold electrode subjected to amalgamation treatment for 60 s, two calibration curves for glucose oxidation at two different potentials of ?0.1 V and 0.25 V were obtained and compared. At the potential of ?0.1 V, at which no ascorbic acid was oxidized and no interference effect was observed, a current sensitivity of 16 μA cm?2 mM?1 from zero to 10 mM glucose concentration range was obtained. At the other potential of 0.25 V, at which ascorbic acid was easily oxidized, a satisfactory calibration curve with negligible ascorbic acid interference was also obtained together with a more enhanced current sensitivity of 32 μA cm?2 mM?1. 相似文献
29.
Filler-elastomer interactions: influence of silane coupling agent on crosslink density and thermal stability of silica/rubber composites 总被引:3,自引:0,他引:3
In this work, the crosslink density and thermal stability of the silica/rubber composites treated by silane coupling agents, i.e., gamma-aminopropyl triethoxysilane (APS), gamma-chloropropyl trimethoxysilane (CPS), and gamma-methacryloxypropyl trimethoxysilane (MPS), were investigated. The chemical structures of modified silicas were studied in term of solid-state 29Si NMR spectroscopy. The crosslink density of the composites was determined by swelling measurement. The development of organic functional groups on silica surfaces treated by coupling agents led to an increase in the crosslink density of the composites, resulting in increasing final thermal stability of the composites. The composites treated by MPS showed the superior crosslink density and thermal stability in these systems. The results could be explained by the fact that the organic functional groups of silica surfaces by silane surface treatments led to an increase of the adhesion at interfaces between silicas and the rubber matrix. 相似文献
30.
Jin Young Kim Kyung Hwa Cho Bo Young Jeong Chang Gyo Park Hoi Young Lee 《Experimental & molecular medicine》2020,52(7):1152
Rab coupling protein (RCP) is upregulated in head and neck squamous cell carcinoma (HNSCC) and is correlated with the progression and survival of patients. However, the role of RCP in one of the aggressive types of HNSCC, oral squamous cell carcinoma (OSCC), remains elusive. In the present study, we identified the important role of Zeb1 in RCP-induced OSCC epithelial-to-mesenchymal transition (EMT) and invasion. RCP induces Zeb1 expression, and silencing Zeb1 expression significantly inhibits RCP-induced OSCC invasion. In addition, Zeb1 upregulates MT1-MMP expression to promote OSCC EMT and invasion. Furthermore, we observed that the β1 integrin/EGFR/β-catenin signaling cascade mediates RCP-induced Zeb1 expression to promote OSCC invasion. Notably, we provide evidence that resveratrol (REV) strongly inhibits RCP-induced Zeb1 expression through blocking β1 integrin endosome recycling and EGFR activation, leading to suppression of RCP-induced OSCC invasion, demonstrating the important role of RCP in OSCC invasion and its reversion by REV. Collectively, the present study provides evidence for the first time that RCP aggravates OSCC invasion through increasing Zeb1 expression and subsequently upregulating MT1-MMP expression and that this process is reversed by REV, providing novel biomarkers and indicating the therapeutic potential of REV in OSCC.Subject terms: Oral cancer, Cell invasion 相似文献