全文获取类型
收费全文 | 24270篇 |
免费 | 3998篇 |
国内免费 | 3380篇 |
专业分类
化学 | 18665篇 |
晶体学 | 514篇 |
力学 | 1247篇 |
综合类 | 297篇 |
数学 | 2504篇 |
物理学 | 8421篇 |
出版年
2024年 | 35篇 |
2023年 | 322篇 |
2022年 | 474篇 |
2021年 | 660篇 |
2020年 | 799篇 |
2019年 | 911篇 |
2018年 | 689篇 |
2017年 | 724篇 |
2016年 | 1059篇 |
2015年 | 1120篇 |
2014年 | 1285篇 |
2013年 | 1753篇 |
2012年 | 2258篇 |
2011年 | 2266篇 |
2010年 | 1783篇 |
2009年 | 1711篇 |
2008年 | 1983篇 |
2007年 | 1658篇 |
2006年 | 1666篇 |
2005年 | 1522篇 |
2004年 | 1231篇 |
2003年 | 962篇 |
2002年 | 1006篇 |
2001年 | 753篇 |
2000年 | 598篇 |
1999年 | 464篇 |
1998年 | 300篇 |
1997年 | 224篇 |
1996年 | 220篇 |
1995年 | 182篇 |
1994年 | 187篇 |
1993年 | 147篇 |
1992年 | 95篇 |
1991年 | 110篇 |
1990年 | 75篇 |
1989年 | 52篇 |
1988年 | 53篇 |
1987年 | 29篇 |
1986年 | 32篇 |
1985年 | 46篇 |
1984年 | 23篇 |
1983年 | 23篇 |
1982年 | 20篇 |
1981年 | 27篇 |
1980年 | 17篇 |
1979年 | 17篇 |
1978年 | 11篇 |
1977年 | 15篇 |
1974年 | 8篇 |
1972年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
For the synthesis of 2-substituted 4H-4-chromenones, 2-methylsulfonyl-4H-4-chromenones as common intermediate were reacted with nucleophiles such as amines and thiophenol to afford the corresponding 2-substituted adducts in very high yields. 相似文献
992.
A nucleophilic substitution reaction of an α‐ferrocenyl alcohol with various amines, indoles and thiols was successfully developed by using a catalytic amount of Bi(NO3)3.5H2O at room temperature without the aid of phase transfer catalyst. The reactions proceeded in aqueous media, leading to the formation of new C=C, C=N and C=S bonds bearing ferrocenyl substituent with high efficiency. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
993.
Based on the governing equations of 2D plane-strain Biot’s consolidation, the relationship between generalized displacements and stresses of a single soil layer with anisotropic permeability and incompressible fluid and solid constituents is described by an analytical layer-element, which is deduced in the Laplace–Fourier transform domain by using the eigenvalue approach. Taking the boundary conditions and the continuity of the soil layers into consideration, a global stiffness matrix is subsequently assembled and solved. As to the 3D case, the same derivation is employed after the application of a decoupling transformation. The actual solutions in the physical domain can further be acquired by inverting the Laplace–Fourier transform. Finally, numerical examples are carried out to verify the presented theory and discuss the influence of the anisotropic permeability on the consolidation behavior. 相似文献
994.
As stimulated Brillouin scattering (SBS) materials, solids have many advantages such as compactness, innoxiousness, and ease of handling. The SBS threshold and reflectivity of K8 glass, a solid material, are investigated. A SBS phase control experiment using K8 glass to achieve coherent beam combination is performed with a self-phase-control technique below the optical damage threshold. The experimental results show that the short-term phase has been stabilized well with λ/33.8 fluctuation during 256 shots (25.6 s), and that the long-term phase change with non-convective K8 glass is much slower than that with convective HT-70 liquid. 相似文献
995.
Rong Wang Hua Xie Yue‐bing Xu Zheng‐ping Jia Xian‐dong Meng Juan‐hong Zhang Jun Ma Juan Wang Xian‐hua Wang 《Biomedical chromatography : BMC》2012,26(3):393-399
The DNA fragment detection focusing technique has further enhanced the sensitivity and information of DNA targets. The DNA fragment detection method was established by capillary electrophoresis with laser‐induced fluorescence detection and restriction endonuclease chromatographic fingerprinting (CE‐LIF‐REF) in our experiment. The silica capillary column was coated with short linear polyarclarylamide (SLPA) using nongel sieving technology. The excision product of various restricted enzymes of DNA fragments was obtained by REF with the molecular biology software Primer Premier 5. The PBR322/BsuRI DNA marker was used to establish the optimization method. The markers were focused electrophoretically and detected by CE‐LIF. The results demonstrate that the CE‐LIF‐REF with SLPA can improve separation, sensitivity and speed of analysis. This technique may be applied to analysis of the excision product of various restricted enzymes of prokaryotic plasmid (pIRES2), eukaryote plasmid (pcDNA3.1) and the PCR product of codon 248 region of gastric cancer tissue. The results suggest that this method could very sensitively separate the excision products of various restricted enzymes at a much better resolution than the traditional agarose electrophoresis. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
996.
997.
Homoallylic alcohols have been prepared in good yields by allylation of ketones with allyl bromide in the presence of stannous chloride dihydrate, zinc iodide, and ammonium chloride in water. 相似文献
998.
Jun‐Sheng Duan Randolph Rach Shi‐Ming Lin 《Mathematical Methods in the Applied Sciences》2013,36(13):1790-1804
We present a new approach to calculate analytic approximations of blow‐up solutions and their critical blow‐up times. Our approach applies the Adomian decomposition–Padé method to quickly and easily compute the critical blow‐up times, which comprises the Adomian decomposition method combined with the Padé approximants technique. We validate our new approach with a variety of numerical examples, including nonlinear ODEs, systems of nonlinear ODEs, and nonlinear PDEs. Furthermore, our new method is shown to be more convenient than prior art that relies on compound discretized algorithms. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
999.
Nanosized Ni particles with an average diameter of about 8 nm were prepared by reducing of NiCl 2 with sodium borohydride (NaBH 4 ) in aqueous solution. By moderate annealing in protective atmosphere, the composite grew up to be 15-20 nm particles. Both of the as-prepared and annealed Ni particles were coated by a layer of manganese oxide via decomposition reaction in aqueous KMnO4 solution. Hysteresis loops of as-prepared samples show a large increase in the magnetization with decreasing temperature and an unsaturated component at high magnetic field. In contrast, the ferromagnetic characteristics of annealed one are much stronger with large magnetization and coercivity. The thermomagnetic curves verified the coexistence of ferromagnetic Ni and antiferromangetic Mn oxide phases. But there exists no exchange bias behavior in the samples, even though the interface structure between the ferromagnetic Ni core and the antiferromagnetic manganese oxides has been distinctly formed. The absence of exchange bias probably originates from the weak ferromagnetic characteristic of Ni cores. 相似文献
1000.
Carbon supports modified with well dispersed anatase TiO2 (C–Ti-X; X (0.25, 0.5, 0.75, and 1.0) represents mass ratio of Ti precursor to carbon) were synthesized with various Ti loadings and used to support Pd catalysts for oxygen reduction. The anatase nanoparticles increased in size with increasing Ti loading. Pd dispersion improved with increasing Ti loading up to the C–Ti-0.75, which resulted in the best catalytic activity. Although the Pd dispersion was lowest on the C–Ti-1.0, it showed better catalytic performance than the catalysts supported on C–Ti-0.25 and C–Ti-0.5. At 0.8 V (vs. RHE), the best catalytic activity achieved was respectively 2.7 and 2.7 times the mass and specific activities of Pd supported on un-modified carbon. The interaction between Pd and highly dispersed TiO2 is believed to improve the catalytic activity of Pd supported on TiO2-modified carbons. 相似文献