Covalent assembly of metal nanoparticles on cellulose fabric and its antimicrobial activity

We develop an antimicrobial active robust metal-cellulose nanohybrid by covalent assembly of metal nanoparticles on cellulose fabric using a simple impregnation of thiol-modified cellulose fabric in colloidal silver (Ag) or palladium (Pd) nanoparticle solutions. The combined results of high resolution transmission electron microscopy (HR-TEM), field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDXS) and inductively coupled plasma atomic emission spectrometry (ICP-AES) reveal that the nanoparticles are highly loaded and dispersed in the thiol-modified cellulose fabric, and X-ray photoelectron spectroscopy (XPS) analysis reveals that the nanoparticles are immobilized in the fabric by a strong and stable covalent bond with thiol functional group. This robust covalent linkage between the nanoparticles and the fabric leads to a remarkable suppression of the release of metal nanoparticles from the fabric. In addition, the metal-cellulose nanohybrids show high antimicrobial activity in excess of 99.9 % growth inhibition of the microorganism. Thus, we anticipate that our metal-cellulose nanohybrid may not only protect cell damage caused by penetration and fixation of metal nanoparticles into the human body but also act as a sustainable biomedical textile.     

Grain rotations and distortions in the asymptotic variance of vacancy of the Boolean model

We consider the asymptotic variance of vacancy (AVV) in the high intensity small-grain Boolean model. Subjecting the grains to rotations or, more generally, linear distortions gives rise to a function which maps distortion distributions to the AVV of the corresponding Boolean model. We mainly study continuity properties of this function, where we use the L¹ Wasserstein metric on distortion distributions. An important role in the formulation and derivation of our results is played by notions of symmetry commonly used in multivariate analysis and stochastic simulation, such as conjugation-invariance and group models.     

A gas jet superposition model for CFD modeling of group-hole nozzle sprays

In the present study, a jet superposition modeling approach is explored to model group-hole nozzle sprays, in which multiple spray jets interact with each other. An equation to estimate the merged jet velocity from each of the individual jets was derived based on momentum conservation for equivalent gas jets. Diverging and converging group-hole nozzles were also considered. The model was implemented as a sub-grid-scale submodel in a Lagrangian Drop–Eulerian Gas CFD model for spray predictions. Spray tip penetration predicted using the present superposition model was validated against experimental results for parallel, diverging and converging group-hole nozzles as a function of the angle between the two holes at various injection and ambient pressures. The results show that spray tip penetration decreases as the group hole diverging or converging angle increases. However, the spray penetration of the converging group-hole nozzle arrangement is more sensitive to the angle between the two holes compared to diverging nozzle because the radial momentum component is converted to axial momentum during the jet–jet impingement process in the converging group-hole nozzle case. The modeling results also indicate that for converging group-hole nozzles the merged sprays become ellipsoidal in cross-section far downstream of the nozzle exit with larger converging angles, indicating increased air entrainment.     

Synthesis of Silicate Zeolite Analogues Using Organic Sulfonium Compounds as Structure‐Directing Agents

A microporous crystalline silica zeolite of the MEL structure type and three other zeolite analogues composed of germanosilicate frameworks were synthesized using tributylsulfonium, triphenylsulfonium, or tri(para‐tolyl)sulfonium as the structure‐directing agent. The germanosilicates thus obtained had ISV, ITT, or a new zeolite structure depending on the synthesis conditions. The structure of the new germanosilicate was solved using X‐ray powder diffraction data with the aid of a charge‐flipping method. The solution indicated a crystal structure belonging to the P63/mmc space group with cell parameters of a=16.2003 Å and c=21.8579 Å. After calcination, the new germanosilicate material exhibited two types of accessible micropores with diameters of 0.61 and 0.78 nm.     

Synthesis and properties of an ionic polyacetylene with aromatic heterocycles

A new ionic polyacetylene with two aromatic heterocycles (pyridyl and thienyl) was prepared by the activation polymerization of 2‐ethynylpyridine by using 3‐(6‐bromohexyloxy)methylthiophene without any additional initiator or catalyst. The activated acetylenic triple bond of N‐substituted‐2‐ethynylpyridinium bromide, formed at first quaternarization process, was susceptible to linear polymerization. The instrumental analysis data on the polymer structure revealed that the polymer have the conjugated polyene backbone structure with the designed two aromatic heterocycles. The photoluminescence peak is located at 510 nm corresponding to a photon energy of 2.43eV. The electrochemical properties of this ionic polyacetylene were also measured and discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5679–5685, 2007     

Growth and characteristics of hydrogenated In-doped ZnO thin films by pulsed DC magnetron sputtering

We investigated the role of hydrogen impurities in highly oriented In-doped ZnO (IZO:H) films. The conductivity of ZnO:H films exhibit small variation despite the increase of hydrogen ratio. The small variation of the carrier concentration in IZO:H films can be explained by the reduction of the oxygen deficiency for the charge neutrality and the increase of Vzn-H bonding for partially charge compensation in the films. The additional mode at 573 cm⁻¹ is interpreted as vacancy clusters. The discrepancy between the increase of vacancy clusters (573 cm⁻¹) and small variation of carrier concentration is attributed to the different physical characteristics of the IZO:H films due to the hydrogen existence between bulk and surface. The measured FT-IR peak at 3500 cm⁻¹ exhibits typical characteristic of O-H bonding.     

Aluminum phthalocyanine: an active and simple catalyst for cyanosilylation of aldehydes

Aluminum phthalocyanine (AlPc) in the presence of Ph₃PO acts as a highly effective catalyst for cyanosilylation of various aldehydes to the corresponding cyanohydrin trimethylsilyl ethers. The reaction proceeds smoothly with 5 mol% catalyst loading at room temperature, giving up to 96% yield. Copyright © 2007 John Wiley & Sons, Ltd.     

Reynolds stress modelling of rectangular open‐channel flow

A Reynolds stress model for the numerical simulation of uniform 3D turbulent open‐channel flows is described. The finite volume method is used for the numerical solution of the flow equations and transport equations of the Reynolds stress components. The overall solution strategy is the SIMPLER algorithm, and the power‐law scheme is used to discretize the convection and diffusion terms in the governing equations. The developed model is applied to a flow at a Reynolds number of 77000 in a rectangular channel with a width to depth ratio of 2. The simulated mean flow and turbulence structures are compared with measured and computed data from the literature. The computed flow vectors in the plane normal to the streamwise direction show a small vortex, called inner secondary currents, located at the juncture of the sidewall and the free surface as well as the free surface and bottom vortices. This small vortex causes a significant increase in the wall shear stress in the vicinity of the free surface. A budget analysis of the streamwise vorticity is carried out. It is found that both production terms by anisotropy of Reynolds normal stress and by Reynolds shear stress contribute to the generation of secondary currents. Copyright © 2006 John Wiley & Sons, Ltd.     

Polymeric photoacid generators for direct photochemical modification of surface

To achieve easy spin coating and enhanced efficiency in the photolithographic process for the direct photochemical modification of surface, we incorporated photoacid generator (PAG) into polymer backbone. Bis‐(4‐hydroxy‐phenyl)‐(4‐methoxy‐3,5‐dimethyl‐phenyl)‐sulfonium chloride was synthesized as a monomer, and was polymerized with sebacoyl chloride and terephthaloyl chloride. The resulting polymeric PAG in chloride salt form was converted to the p‐toluenesulfonate and 1‐naphthol‐5‐sulfonate forms with ion‐exchange reactions. By the photolithographic process with the polymeric PAG, the protecting groups of the linker molecules self‐assembled onto a glass plate were micropatterned to produce an amine pattern for the microarray of oligonucleotides. The acids generated from the polymeric PAG effectively deprotect the acid‐labile protecting groups of the linker molecules through a chemical amplification process in the exposed region. After the treatment of the patterned amino groups with a fluorescent dye, the pattern profiles were observed with a fluorescence scanner. The fluorescence image reveals a well‐defined pattern at a micro level, which clearly indicates that the polymeric PAGs have a great potential in photochemical surface modification for the microarray of oligonucleotides. Copyright © 2007 John Wiley & Sons, Ltd.