Adsorption characteristics of as(III) and as(V) with titanium dioxide loaded Amberlite XAD-7 resin.

The adsorption characteristics of As(V) and As(III) on titanium dioxide loaded Amberlite XAD-7 resin have been studied. The resin was prepared by impregnation of Ti(OC2H5)4 followed by hydrolysis with ammonium hydroxide. Batch adsorption experiments were carried out as a function of the pH, shaking time and the concentration of As(V) and As(III) ions. The resin showed a strong adsorption for As(V) from pH 1 to 5 and for As(III) from pH 5 to 10. The adsorption isotherm data for As(V) at pH 4 fitted well to a Langmuir equation with a binding constant of 59 dm3 mol(-1) and a capacity constant of 0.063 mmol g(-1). The data for As(III) at pH 7 also fitted well to a Langmuir equation with a binding constant of 5.4 dm3 mol(-1) and a capacity constant of 0.13 mmol g(-1). The effect of diverse ions on the adsorption of arsenic was also studied. Column adsorption experiments showed that the adsorption of As(III) is more favorable compared to As(V), due to both the faster adsorption and larger capacity for As(III) than As(V).     

Mechanism of cyclic acetal formation

The mechanism of formation of 1,3-dioxolanes is considered in the light of Baldwin's rule for ring-closure.     

Antibacterial wollastonite supported excellent proliferation and osteogenic differentiation of human bone marrow derived mesenchymal stromal cells

Journal of Sol-Gel Science and Technology - Biocompatibility and bacterial infections are the primary concerns associated with the current bone graft substitutes. The application of...     

An Extremely Simple and Effective Colony PCR Procedure for Bacteria, Yeasts, and Microalgae

An extremely simple and effective colony PCR procedure is established for both gram-negative and gram-positive bacteria, yeasts, and microalgae. Among the four lysis buffers examined, Y-PER is observed to be more effective than Tris/EDTA, 0.2 % SDS, and 10 mM EDTA in the extraction of PCR-quality genomic DNA from those microorganisms. Vortexing or pipetting agitation of the cells in Y-PER for 5–10 s was sufficient to release genomic DNA for all the test bacteria and yeasts, and most microalgae. Additional incubation at 98 °C for 5 min for further cell disruption was essential only for Chlorella vulgaris due to its notoriously rigid cell wall.     

Electrochemical behaviour of nickel-based electrodes for oxygen evolution reaction in alkaline water electrolysis

NiZnS electrode has been investigated for use in oxygen evolution reaction in alkaline media. Nickel mesh electrode was coated with the ternary composition of NiZnS by four methods, viz., direct current electrodeposition, pulse electrodeposition, sonoassisted direct current electrodeposition and sonoassisted pulse electrodeposition. The oxygen evolution studies carried out using these electrodes resulted in higher current density for the electrode prepared by sonoassisted pulse electrodeposition compared to those prepared by other methods. Effect of plating current density, pulse duty cycle and temperature on the electrochemical parameters of the alloy coating has been studied. Surface morphologies of the various coating were studied using scanning electron microscopy. Long-term stability of the electrodes prepared was studied in alkaline medium. Exchange current density (j _o) was found to increase with the increase in temperature and was the highest for sonoassisted pulse electrodeposited electrode.     

Combined Laminar Mixed Convection and Surface Radiation using Asymptotic Computational Fluid Dynamics (ACFD)

This paper reports the use of the technique of combining asymptotics with computational fluid dynamics (CFD), known as asymptotic computational fluid dynamics (ACFD), to handle the problem of combined laminar mixed convection and surface radiation from a two dimensional, differentially heated lid driven cavity. The fluid under consideration is air, which is radiatively transparent, and all the walls are assumed to be gray and diffuse and having the same hemispherical, total emissivity (ɛ). The computations have been performed on FLUENT 6.2. The full radiation problem (i.e. all the walls are radiatively black corresponding to ɛ = 1) is first taken up and the method of “perturbing and blending” is used wherein, first, limiting solutions of natural and forced convection are perturbed, to obtain correlations for the weighted average convective Nusselt numbers for the full radiation case. These correlations are then blended suitably in order to obtain a composite correlation for the weighted average convective Nusselt number that is valid for the entire mixed convection range, i.e., 0 ≤ Ri ≤ ∞. This correlation is then expanded in terms of ɛ to obtain an expression for the average convective Nusselt number that is valid for any ɛ in the range 0 ≤ ɛ ≤ 1. In so far as radiation heat transfer is concerned, using asymptotic arguments, a new weighted average radiation Nusselt number is defined such that this quantity can be expanded just in terms of ɛ. Hence, by the use of ACFD, the number of solutions required to obtain reasonably accurate correlations for both the convective and radiative heat transfer rates and hence the total heat transfer rate (Nu _total = Nu _C + Nu _R), is substantially reduced. More importantly, the correlations for convection and radiation are asymptotically correct at their ends. The effect of secondary variables like aspect ratio and the case of unequal wall emissivities can also be included without significant additional effort.     

Mixed convection heat transfer from a horizontal channel with protruding heat sources

A numerical investigation is carried out to study fluid flow and heat transfer characteristics of conjugate mixed convection from a two dimensional horizontal channel with four protruding heat sources mounted on one of the finite thick channel walls. The flow is assumed as laminar, hydrodynamically and thermally developing. Water and FC70 are the fluids under consideration. The geometric parameters such as spacing between the channel walls (S), size of protruding heat sources (L_h×t_h), thickness of substrate (t) and spacing between heat sources (b) are fixed. Results are presented to show the effect of parameters such as Re_S, Gr_S^*, Pr, k_p/k_f and k_s/k_f on fluid flow and heat transfer characteristics. Using the method of asymptotic expansions, correlations are also presented for the maximum temperature of heat source.     

Computation of conjugate heat transfer in the turbulent mixed convection regime in a vertical channel with multiple heat sources

This paper presents the results of a comprehensive numerical study to analyze conjugate, turbulent mixed convection heat transfer from a vertical channel with four heat sources, uniformly flush-mounted to one of the channel walls. The results are presented to study the effect of various parameters like thermal conductivity of wall material (k _s), thermal conductivity of flush-mounted discrete heat source (k _c), Reynolds number of fluid flow (Re _s), modified Richardson number (Ri ⁺) and aspect ratio (AR) of the channel. The standard k-ε turbulence model, modified by including buoyancy effects with physical boundary conditions, i.e. without wall functions, has been used for the analysis. Semi-staggered, non-uniform grids are used to discretise the two dimensional governing equations, using finite volume method. A correlation, encompassing a wide range of parameters, is developed for the non-dimensional maximum temperature (T ^*) using the asymptotic computational fluid dynamics (ACFD) technique.