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201.
Magnetic resonance imaging of soft tissue masses: an evaluation of fifty-three histologically proven tumors 总被引:3,自引:0,他引:3
Fifty-three histologically confirmed soft tissue masses in 48 patients were evaluated by magnetic resonance imaging (MR) and computerized tomography (CT). Twenty-three of these were malignant, twenty-three benign and seven of intermediate malignancy (all aggressive fibromatosis). The two procedures were compared for sensitivity and delineation of masses, their relationship to important neurovascular structures, their potential for histological diagnoses, their relative roles in influencing the surgical approach and the preferred modality in the follow-up for detection of tumor recurrence. Both modalities have their relative strengths and weaknesses. However, the superior contrast resolution of magnetic resonance imaging, its demonstration of lesions not clearly identified by CT, its pluridirectional capabilities and its ability to demonstrate large soft tissue tumors in a single coronal or sagittal plane makes it the preferred initial modality for evaluation of the soft tissue tumor of uncertain etiology and also in the follow-up of these patients. Despite MR's superiority in anatomically staging soft tissue tumors it, like CT, is of limited value in characterizing soft tissue sarcomas. 相似文献
202.
Given a set X of points in the plane, two distinguished points s,tX, and a set Φ of obstacles represented by line segments, we wish to compute a simple polygonal path from s to t that uses only points in X as vertices and avoids the obstacles in Φ. We present two results: (1) we show that finding such simple paths among arbitrary obstacles is NP-complete, and (2) we give a polynomial-time algorithm that computes simple paths when the obstacles form a simple polygon P and X is inside P. Our algorithm runs in time O(m2n2), where m is the number of vertices of P and n is the number of points in X. 相似文献
203.
Vaithilingam Sivakumar Gopal Sakthivel Thirumalai Srinivasan Senthil Kumar Manokar A. Muthu Sathyamurthy Ravishankar Esakkimuthu Ganapathy Sundaram Kumar Ravinder Sharifpur Mohsen 《Journal of Thermal Analysis and Calorimetry》2021,145(3):1103-1119
Journal of Thermal Analysis and Calorimetry - The shortage of freshwater is becoming a major threat to sustainable environmental development. Water desalination techniques provide solutions for... 相似文献
204.
Gas phase quantum chemical calculations of linear, hydrogen bonded oligomers of carbonic acid have been carried out to examine the feasibility for such species to be the building blocks of crystalline carbonic acid. Infrared and Raman vibrational spectra have been calculated and are compared against experimentally known spectra for two polymorphs of carbonic acid. The calculated anharmonic frequencies of the linear oligomer agree well with the experimental data for the centrosymmetric β-carbonic acid, rather than with that for the α polymorph. These calculations strongly suggest that β-carbonic acid should consist of one-dimensional hydrogen bonded carbonic acid molecules in the anti-anti conformation. 相似文献
205.
206.
Narayan K. Sundaram 《哲学杂志》2013,93(23):2883-2903
ABSTRACTThe indentation of a metal specimen by a narrow-angle wedge produces extreme plastic deformation, with an effect akin to cutting into the metal. Simulation of such processes is challenging, and complicated by the need to model material separation along the indentation symmetry axis. Here we use an Arbitrary Lagrangian Eulerian (ALE) framework to enforce the symmetry boundary conditions (bcs) in their original, `strong’ form, as well as conventional Lagrangian FE to impose the bcs in a complementary, `weak’ form. Taken together these two cases, representing perfectly strong and perfectly weak interfaces, produce accurate bounds on the mechanical response for indentation by wedges with semi-apical angles as small as 15 degrees, and encompass intermediate cases that would require complicated models of ductile failure. The method accurately predicts the transition from the cutting pattern to the non-cutting (radially compressive) pattern as the apical angle is increased. In combination with Lagrangian particle tracking, the simulations reveal the deformation pattern as well as strain, strain-rate, and velocity fields in narrow angle indentation at high resolution. Interestingly, the strong form predicts a thin (tens of microns), near-wall layer of intense plastic strain, which has been observed recently in indentation experiments. With the exception of this feature, the strong and weak bc solutions are quite similar. The present approach reveals insights about plastic flow past narrow obstacles in a range of related problems including cone penetration and machining, and suggests using narrow-angle indentation as a way to probe material failure. 相似文献
207.
The fluorescence quenching of 9-aminoacridine by certain biologically important catechols and rutin was investigated using absorption, steady state and time resolved fluorescence measurements. The in vitro-antioxidant activities of the above compounds were studied using deoxyribose degradation assay and nitric oxide scavenging assay. The experimental results showed that the fluorescence of 9-aminoacridine was quenched by quencher molecules via forming ground state complex. The bimolecular quenching rate constant k(q), binding constant (K) and number of binding sites (n) were calculated at different temperatures from relevant fluorescence data. Static quenching mechanism was supported by lifetime measurement. The free energy change (ΔG(et)) for electron transfer process was calculated by Rehm-Weller equation. The binding distance of 4-nitrocatechol with 9-aminoacridine was obtained according to Forster's non-radiative energy transfer theory. Nature of binding forces and their interactions was probed based on thermodynamic parameters. 相似文献
208.
R. Golovchak O. Shpotyuk A. Kozdras B. J. Riley S. K. Sundaram J. S. McCloy 《Journal of Thermal Analysis and Calorimetry》2011,103(1):213-218
Radiation-induced physical aging effects are studied in binary As
x
S100−x
and As
x
Se100−x
(30 ≤ x ≤ 42) glasses by conventional differential scanning calorimetry (DSC) method. It is shown that γ-irradiation (Co60 source, ~3 MGy dose) of glassy As
x
S100−x
caused a measurable increase in glass transition temperature and endothermic peak area in the vicinity of glass transition
region, which was associated with acceleration of structural relaxation processes in these materials. In contrast to sulfide
glasses, the samples of As–Se family did not exhibit any significant changes in DSC curves after γ-irradiation. The observed
difference in radiation-induced physical aging between sulfides and selenides was explained by more effective destruction-polymerization
transformations and possible metastable defects formation in S-based glassy network. 相似文献
209.
Arulmozhiraja S Coote ML Lu D Salem G Wild SB 《The journal of physical chemistry. A》2011,115(17):4530-4534
This paper presents a combined experimental and theoretical study of the electronic spectrum of the natural adamantane-type polyarsenical Arsenicin A. Experiments reveal that this molecule strongly absorbs UV light in the absence of an obvious chromophore. The observed absorbance is supported by the time-dependent density functional (TD-DFT) calculations with B3LYP, M06-L, and M06-2X functionals combined with the 6-311+G(3df,2pd) basis set, as well as by symmetry-adapted cluster/configuration interaction (SAC-CI) theory. The theoretical investigations reveal that the absorption is facilitated by through-space and through-bond interactions, between the lone pairs on the arsenic and oxygen atoms and the σ-bonding framework of the molecule, that destabilize occupied and stabilize unoccupied molecular orbitals. 相似文献
210.
Shalini Purwar Shanthy Sundaram Praveen Verma Shaili Srivastava Anil Kumar 《Applied biochemistry and biotechnology》2012,168(8):2344-2357
To identify novel components of basal resistance against the Tellitia indica of wheat, breeding for disease resistance was carried out on resistant and susceptible genotype of Karnal Bunt. The different members of wheat cystatin gene families were cloned, and their role in triggering differential resistance through co-expression was analyzed in our lab. The multidomain wheat cystatin (WCM) is a proteinase inhibitor characterized by cloning the gene from susceptible (WH542) and resistant genotype (HD 29). A WCM cDNA was isolated from both genotypes and sequenced. The WCM had a highly conserved N-terminal cystatin domain and a long C-terminal extension containing a second region, which exhibited similarity to the cystatin domain. The expression level was significantly (P?>?0.001) higher in resistant compared to susceptible genotype at all the physiological stages of wheat spikes. In order to characterize the biochemical properties of WCM, the coding sequence was expressed in Escherichia coli using pET expression vector. The recombinant WCM was purified from soluble fraction of the cell extract by using affinity chromatography. WCM, with 23 KDa molecular mass, showed cysteine proteinase inhibitory activity against papain (Ki 3.039?×?10?7?M) as determined by using BAPNA as substrate. Furthermore, it was able to arrest the fungal mycelial growth of T. indica. Hyphae growth was inhibited, and morphological changes such as swelling and fragmentation of the fungus were observed. Overall, these observations suggest an endogenous high expression of cystatin, possibly associated with the resistance of wheat against Karnal bunt. 相似文献