Sources and toxicity of fluoride in the environment

Fluoride, a naturally occurring element, exists in combination with other elements as a fluoride compound, and is found naturally in water, foods, soil, and several minerals such as fluorite and fluorapatite. Fluoride normally enters the environment and human body through water, food, industrial exposure, drugs, cosmetics, etc. However, fluoride (F^?) contamination in groundwater has been recognized as a serious problem worldwide. The World Health Organization’s specified tolerance limit of fluoride in drinking water is 1.5 mg/L. Human disease caused by fluoride manifests itself in three forms: dental, skeletal, and non-skeletal fluorosis. Apart from teeth and bones, the interaction and involvement of soft tissues, organs, and other systems of the body with fluoride leads to non-skeletal fluorosis. It leads to many bone diseases, mottling of teeth, and lesions of the endocrine glands, thyroid, liver, kidney, and other organs. Fluoride ion concentration in drinking water can be easily estimated by UV-Vis spectrophotometer. Various defluoridation techniques have been developed to reduce the fluoride content to the desired level including principally membrane and adsorption processes. Biosorption is still one of the most extensively used methods for defluoridation of drinking water due to it being cost-free or low cost and because of its viability.     

Solution NMR studies of supramolecular complexes of [60]- and [70]fullerenes with mono O-substituted calix[6]arene

Supramolecular complexation of [60]- and [70]fullerenes with 37-allyl-38,39,40,41,42-pentahydroxy-5,11,17,23,29,35-hexa(4-tert butyl)calix[6]arene (I) has been studied in CCl(4) medium by NMR spectrometric method. All of the complexes are found to be stable with 1:1 stoichiometry. Formation constants (K) of the above supramolecular complexes have been determined from systematic variation of NMR chemical shifts of specific protons of I in the presence of [60]- and [70]fullerenes. Trends in the K value suggest that [70]fullerene binds more strongly with I relative to [60]fullerene. Both PM3 and ab initio calculations reveal that the intermolecular interaction in the [70]fullerene/I complex proceeds through quite deep energy minima.     

Hydrocarbon Soluble Alkali-Metal-Aluminium Hydride Surrog[ATES]

A series of group 1 hydrocarbon-soluble donor free aluminates [AM(^tBuDHP)(TMP)Al(ⁱBu)₂] (AM=Li, Na, K, Rb) have been synthesised by combining an alkali metal dihydropyridyl unit [(2-^tBuC₅H₅N)AM)] containing a surrogate hydride (sp³ C−H) with [(ⁱBu)₂Al(TMP)]. These aluminates have been characterised by X-ray crystallography and NMR spectroscopy. While the lithium aluminate forms a monomer, the heavier alkali metal aluminates exist as polymeric chains propagated by non-covalent interactions between the alkali metal cations and the alkyldihydropyridyl units. Solvates [(THF)Li(^tBuDHP)(TMP)Al(ⁱBu)₂] and [(TMEDA)Na(^tBuDHP)(TMP)Al(ⁱBu)₂] have also been crystallographically characterised. Theoretical calculations show how the dispersion forces tend to increase on moving from Li to Rb, as opposed to the electrostatic forces of stabilization, which are orders of magnitude more significant. Having unique structural features, these bimetallic compounds can be considered as starting points for exploring unique reactivity trends as alkali-metal-aluminium hydride surrog[ATES].     

Interaction between coherent structures and surface temperature and its effect on ground heat flux in an unstably stratified boundary layer

Surface layer plumes, thermals, downdrafts and roll vortices are the most prominent coherent structures in an unstably stratified boundary layer. They contribute most of the temperature and vertical velocity variance, and their time scales increase with height. The effects of these multi-scale structures (surface layer plumes scale with surface layer depth, thermals scale with boundary layer height and the resulting roll vortices scale with convective time scale) on the surface temperature and ground heat flux were studied using turbulence measurements throughout the atmospheric boundary layer and the surface temperature measurements from an infrared camera. Plumes and thermals imprint on the surface temperature as warm structures and downdrafts imprint as cold structures. The air temperature trace shows a ramp-like pattern, with small ramps overlaid on a large ramp very close to the surface; on the other hand, surface temperature gradually increases and decreases. Turbulent heat flux and ground heat flux show similar patterns, with the former lagging the latter. The maximum values of turbulent heat flux and ground heat flux are 4 and 1.2 times the respective mean values during the ejection event. Surface temperature fluctuations follow a similar power-law exponent relationship with stability as suggested by surface layer similarity theory.     

A novel method of developing all-optical frequency encoded memory unit exploiting nonlinear switching character of semiconductor optical amplifier

The very fast running optical memory and optical logic gates are the basic building blocks for any optical computing data processing system. Realization of a very fast memory-cell in the optical domain is very challenging. In the last two decades many methods of implementing all-optical flip-flops have been proposed. Most of these suffer from speed limitation because of low switching response of the active devices. In our present communication the authors propose a method of developing a frequency encoded memory unit based on the switching action of semiconductor optical amplifier (SOA). Nonlinear polarization rotation characters of SOA and ‘SOA based Mach-Zehnder Interferometer’ switch, i.e. ‘SOA-MZI’ switch, are exploited for the purpose of some switching action with least switching power (<−3 dB_m) and high switching contrast ratio (20 dB). Here two logic states (‘0’ state and ‘1’ state) of the memory is encoded by two different frequencies, which will remain unchanged throughout the data communication irrespective of loss of light energy due to reflection, refraction, attenuation, etc. Though the SOA based switch runs with the operational speed 100 Gb/s, still due to the presence of the other optical components in the memory unit, the overall speed of the proposed system will come down to 10 Gb/s.     

Method of implementing frequency encoded multiplexer and demultiplexer systems using nonlinear semiconductor optical amplifiers

Multiplexing and demultiplexing are the essential parts of any communication network. In case of optical multiplexing and demultiplexing the coding of the data as well as the coding of control signals are most important issues. Many encoding/decoding mechanisms have already been developed in optical communication technology. Recently frequency encoding technique has drawn some special interest to the scientific communities. The advantage of frequency encoding technique over any other techniques is that as the frequency is fundamental character of any signal so it remains unaltered in reflection, refraction, absorption, etc. during transmission of the signal and therefore the system will execute the operation with reliability. On the other hand, the switching speed of semiconductor optical amplifiers (SOA) is sufficiently high with property of best on/off contrast ratio. In our present communication we propose a method of implementing a ‘4-to-1’ multiplexer (MUX) and a ‘1-to-4’ demultiplexer (DEMUX) exploiting the switching character of nonlinear SOA with the use of frequency encoded control signals. To implement the ‘4-to-1’ MUX and ‘1-to-4’ DEMUX system, the frequency selection by multiquantum well (MQW)-grating filter-based SOA has been used for frequency routing purpose. At the same time, the polarization rotation character of SOA has also been exploited to get the desired purpose. Here the fast switching action of SOA with reliable frequency encoded control input signals, it is possible to achieve a faithful MUX/DEMUX service at tera-Hz operational speed.     

Sharp signature of a dx2-y2 quantum critical point in the Hall coefficient of cuprate superconductors

We study the behavior of the Hall coefficient, R(H), in a system exhibiting dx(2)(-y(2)) density-wave order in a regime in which the carrier concentration, x, is tuned to approach a quantum critical point at which the order is destroyed. At the mean-field level, we find that n(Hall)=1/R(H) evinces a sharp signature of the transition. There is a kink in n(Hall) at the critical value of the carrier concentration, x(c); as the critical point is approached from the ordered side, the slope of n(Hall) diverges. Hall transport experiments in the cuprates, at high magnetic fields sufficient to destroy superconductivity, should reveal this effect.     

UV–Vis and NMR spectroscopic investigations on effective and selective non-covalent interactions between fullerenes and calix[6]arene

Ground state non-covalent interactions between a macro cyclic calixarene receptor, namely, 4-tert-butylcalix[6]arene (1), and fullerenes (C₆₀ and C₇₀) were studied in toluene medium by absorption spectrophotometric method. Absorption band due to the charge transfer (CT) transition have been observed in the visible region between fullerenes and 1. Utilizing the CT absorption bands, various important physicochemical parameters like oscillator strength, resonance energy, transition dipole strength of the fullerene-1 complexes and ionization potential of 1 is determined in present investigations. From Jobs method of continuous variation, it is observed that both C₆₀ and C₇₀ form stable 1:1 complexes with 1. The most fascinating feature of the present study is that 1 binds selectively C₇₀ compared to C₆₀ as obtained from binding constant (K) data of C₆₀–1 (K_C60–1) and C₇₀–1 (K_C70–1) complexes, i.e., K_C60–1 = 32,400 dm³·mol^? 1 and K_C70–1 = 110,000 dm³.mol^? 1 and selectivity (K_C70–1/K_C60–1) = 3.4. ¹H NMR analysis provides very good support in favor of strong binding between C₇₀ and 1.     

Quantum Pairing Time Orders

The concept of the time-independent correlators for the even- and odd-frequency pairing states that can be defined for both bosonic and fermionic quasiparticles is proposed. These correlators explicitly capture the existence of two distinct classes of pairing states and provide a direct probe of the hidden Berezinskii order. This concept is illustrated in the cases of pairings for Majorana fermions and quasiparticles in Dirac semimetals. It is shown that the time-independent correlator is able to effectively capture the energy scale relevant for pairing.     

Standardised acoustic characterisation of sonic crystals noise barriers: Sound insulation and reflection properties

This work presents sound insulation and sound reflection measurements conducted over sonic crystal noise barriers according to the European standards EN 1793-2, EN 1793-5 and EN 1793-6. In most of the reference literature, sound insulation and reflection properties of sonic crystals are measured or a diffuse sound field or in a direct sound field including the top and side edge diffraction effects together with the transmitted (or reflected) components. The aim of this work is to perform free-field measurements over a real-sized sample in order to window out all diffraction components and to verify the points of strength and weakness of the application of standardised measurements to sonic crystals. Diffuse field measurements in laboratory are also done for comparison purposes. Since the target frequency range for traffic noise spectrum is centred at around 1000 Hz, a finite element based parametric investigation is performed to design unit cells capable of generating band gaps in the one-third octave bands ranging from 800 Hz to 1250 Hz. Then, 3 × 3 m sonic crystal noise barriers are installed in the Laboratory of the University of Bologna and sound insulation and sound reflection measurements are performed according to the mentioned active standards for normal incidence. Sound insulation is measured for diffuse incidence too. The two methods give different results. The method more directly comparable to calculations is the free-field one. However, if on the one hand the application of a time window allows to compute the transmitted or reflected component only, on the other hand the time window itself limits the maximum width of the sample for which all reflections of the n-th order having a significant spectral content are included, and thus results critical in the analysis of this kind of noise barriers. Nevertheless, the standardised measurements allow a direct comparison between the performance of sonic crystals and common noise barriers.