全文获取类型
收费全文 | 298篇 |
免费 | 4篇 |
国内免费 | 1篇 |
专业分类
化学 | 226篇 |
晶体学 | 2篇 |
力学 | 11篇 |
综合类 | 3篇 |
数学 | 17篇 |
物理学 | 44篇 |
出版年
2024年 | 2篇 |
2023年 | 2篇 |
2022年 | 25篇 |
2021年 | 20篇 |
2020年 | 11篇 |
2019年 | 18篇 |
2018年 | 16篇 |
2017年 | 4篇 |
2016年 | 9篇 |
2015年 | 5篇 |
2014年 | 10篇 |
2013年 | 20篇 |
2012年 | 16篇 |
2011年 | 28篇 |
2010年 | 11篇 |
2009年 | 7篇 |
2008年 | 8篇 |
2007年 | 8篇 |
2006年 | 7篇 |
2005年 | 5篇 |
2004年 | 6篇 |
2003年 | 5篇 |
2002年 | 4篇 |
2001年 | 1篇 |
2000年 | 3篇 |
1999年 | 4篇 |
1998年 | 6篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1956年 | 2篇 |
排序方式: 共有303条查询结果,搜索用时 93 毫秒
31.
S M Sultan 《The Analyst》1986,111(1):97-99
32.
Nurettin Sahiner Sultan Butun Sengel Mustafa Yildiz 《Journal of Coordination Chemistry》2017,70(21):3619-3632
Tannic acid (TA) complexes with various metal ions are prepared in buffer solutions by readily adjusting the pH, but there is no normalizing method to produce ferric tannate complexes. In this study, TA-Fe(III) complex was prepared in reverse microemulsion medium by reaction of TA as ligand with Fe(III) in 1:3 ligand:metal ion molar ratio. The complex was characterized by SEM, AFM, FT-IR, elemental analysis, AAS measurement, and Brunauer-Emmett-Teller (BET) method. Furthermore, magnetic susceptibility was tested with the Gouy method, and electronic spectral studies of TA-Fe(III) complex were completed with solid UV–vis measurements. The thermal stability was also studied by TGA analysis. These studies show that the ligand molecules have octahedral arrangement around Fe(III) and the complex is paramagnetic. The bandgap energy of the complex was calculated as 3.42 eV with solid UV–vis analysis. To determine antioxidant activity of the complex, Total Phenol Content (TPC) and Trolox Equivalent Antioxidant Concentration (TEAC) methods were used. The complex has great antioxidant properties with TPC = 45 ± 1 mg L?1 GAE and TEAC = 296 ± 2 mM trolox g?1 for dry sample. 相似文献
33.
Ibrahim A. Darwish Maha A. Sultan Hessa A. Al-Arfaj 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2010,75(1):334-339
A selective and simple kinetic spectrophotometric has been developed, for the first time, for the determination of gatifloxacin (GAT) in its dosage forms. The method was based on the formation of a colored N-vinyl chlorobenzoquinone derivative of GAT by its reaction with 2,3,5,6-tetrachloro-1,4-benzoquinone in presence of acetaldehyde. The formation of the colored product was monitored spectrophotometrically by measuring the absorbances at 655 nm. The factors affecting the reaction were studied and optimized. The stoichiometry of the reaction was determined, and the reaction pathway was postulated. Under the optimized conditions, the initial rate and fixed time (at 5 min) methods were utilized for constructing the calibration graphs. The graphs were linear in the concentration ranges of 2–100 and 10–140 μg ml?1 with limits of detection of 0.84 and 3.5 μg ml?1 for the initial rate and fixed time methods, respectively. The analytical performance of both methods was fully validated, and the results were satisfactory. The proposed methods were successfully applied to the determination of GAT in its commercial dosage forms. The label claim percentages were 99.7–100.5 and 98.2–99.5% for the initial rate and fixed time methods, respectively. Statistical comparison of the results with those of the reference method showed excellent agreement and proved that there was no significant difference in the accuracy and precision between the reference and the proposed methods. The proposed methods are superior to all the previously reported spectrophotometric methods in terms of the procedure simplicity and assay selectivity. 相似文献
34.
From the black coral Antipathies dichotoma, a sphingolipid (2S*,3S*,4E,8E)-2N-[tetradecanoyl]-4(E),8(E)-icosadiene-1,3-diol (1) and a steroid (22E)-methylcholesta-5,22-diene-1α,3β,7α-triol (2) were isolated. Other known compounds, 3β,7α-dihydroxy-cholest-5-ene (3), (22E,24S),5α,8α-epidioxy-24-methylcholesta-6,22-dien-3β-ol (4) and (22E,24S),5α,8α-epidioxy-24-methylcholesta-6,9(11),22-trien-3β-ol (5). The structures were established on the basis of NMR spectroscopic analysis and comparison with literature. The antibacterial activity of five compounds was evaluated. 相似文献
35.
Wietstruk M Melnikov A Stamm C Kachel T Pontius N Sultan M Gahl C Weinelt M Dürr HA Bovensiepen U 《Physical review letters》2011,106(12):127401
Femtosecond x-ray magnetic circular dichroism was used to study the time-dependent magnetic moment of 4f electrons in the ferromagnets Gd and Tb, which are known for their different spin-lattice coupling. We observe a two-step demagnetization with an ultrafast demagnetization time of 750 fs identical for both systems and slower times which differ sizeably with 40 ps for Gd and 8 ps for Tb. We conclude that spin-lattice coupling in the electronically excited state is enhanced up to 50 times compared to equilibrium. 相似文献
36.
Thin films of SnO2 were deposited by RF-magnetron sputtering on quartz substrates at room temperature in an environment of Ar and O2. The XRD pattern shows amorphous nature of the as-deposited films. The optical properties were studied using the reflectance and transmittance spectra. The estimated optical band gap (Eg) values increase from 4.15 to 4.3 eV as the Ar gas content decreases in the process gas environment. The refractive index exhibits an oscillatory behavior that is strongly dependent on the sputtering gas environment. The Urbach energy is found to decrease with increase in band gap. The band gap is found to decrease on annealing the film. The role of oxygen defects is explored in explaining the variation of optical parameters. 相似文献
37.
Ahmed Abdel-Lateff Walied M. Alarif Seif-Eldin N. Ayyad Sultan S. Al-Lihaibi Salim A. Basaif 《Natural product research》2015,29(1):24-30
Chemical investigation of the soft coral Sarcophyton glaucum collected from the Red Sea led to isolation of 11 isoprenoidal metabolites (1–11). A new sesquiterpenoid, 6-oxo-germacra-4(15),8,11-triene (1), a new natural cembranoid, sarcophinediol, along with two known sesquiterpenoids (2 and 3) and seven known cembranoids (5–11) was obtained. The structures of the compounds were established based on their NMR, MS, IR and UV spectral data. All compounds were evaluated for their cytotoxicity employing three cancer cell lines (HepG2, MCF-7 and HCT116). Compounds 4 and 6 showed significant cytotoxicity towards HepG2 with IC50 values of 18.8 ± 0.07 and 19.9 ± 0.02 μM; respectively. Compounds 5–7 exhibited potent cytotoxicity against MCF-7 cells with IC50 values of 9.9 ± 0.03, 2.4 ± 0.04 and 3.2 ± 0.02 μM, respectively. Compounds 1, 4 and 5 showed significant activities towards HCT116 cells with IC50 values of 29.4 ± 0.03, 19.4 ± 0.02 and 25.8 ± 0.03 μM, respectively. 相似文献
38.
JPC – Journal of Planar Chromatography – Modern TLC - A simple and robust thin-layer chromatography (TLC) method has been developed and validated for the simultaneous quantitative... 相似文献
39.
40.
Ahmed M. M. Soliman Mahmoud. Abd El‐Aleem. Ali. Ali. El‐Remaily Adel. A. Sultan Hossam. Abdel‐Ghany 《Journal of heterocyclic chemistry》2014,51(5):1476-1481
5‐Amino‐3‐anilino‐1H‐pyrazole‐4‐carbonitrile 1 was alkylated with various halo reagents under phase transfer conditions to give the corresponding imidazopyrazole derivatives 2a , 2b , 2c , 3 , 4 , 5 , 6 . Pyrazolo[1,5‐a] pyrimidine derivatives 11 , 12 , 13 , 14 were prepared by treating compound 1 with different dicarbonyl reagents, namely, diethymalonate, ethyl 3‐oxo‐3‐phenylpropanoate, pentane‐2,4‐dione or ethyl 3‐oxobutanoate. 相似文献