Synthesis and Characterization of Some Carbon Based Nanostructures

Carbon thin films were synthesized using the original Thermionic Vacuum Arc (TVA) method. Mechanical properties were investigated using Micro Materials NanoTest 500 instrument using a NT Berkovich indenter. XPS provides a quantitative analysis of the surface composition and X‐ray generated Auger electron spectroscopy (XAES) performed by Thermoelectron ESCALAB 250 revealed information about the sp³:sp² ratio of the carbon bondings. Structure and morphology was studied by Transmission Electron Microscope CM120ST, providing information on the grain size distribution of the crystalline diamond structures (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The nominal butyl ester ion in the mass spectra of long-chain n-alkyl esters: A postscript

n-Octadecyl benzoate, taken as a model for long-chain n-alkyl carboxylates generally, loses C₁₄H₂₈ under electron impact to yield a product with the same elemental composition as the butyl benzoate molecular ion. This product retains quantitatively one hydrogen from C-6, and seems to be formed as an oxygen-protonated 4-benzoyloxybutyl radical. It reacts further to lose H₂O, in which deuterium labeling demostrates that the second hydrogen atom comes predominantly from C-4. The intermediate reorganization, for which the driving force is presumably furnished by the instability associated with a primary radical, is pictured in terms of cyclization via bonding between the C-4 radical site and the benzoyl carbon concerted with hydrogen migration via a 4-membered quasicyclic transition state.     

Comparison of Gaussian particle center estimators and the achievable measurement density for particle tracking velocimetry

A series of numerical simulations were conducted to investigate the performance of two particle center estimation algorithms for Particle Tracking Velocimetry: a simple three-point Gaussian estimator and a least-square Gaussian. The smallest position error for images with reasonable noise levels was found to be approximately 0.03 pixels for both estimators using particles with diameters of 4 pixels. As both estimators performed equally well, use of the simple three-point Gaussian algorithm is recommended because it executes 100 times faster than the least-square algorithm. The maximum achievable measurement density and accuracy for the three-point Gaussian estimator were determined with a numerical simulation of an Oseen vortex. Uncertainty measures have been introduced to filter out unreliable displacement measurements. It was found that 4 to 5 velocity vectors could be obtained within a 32 × 32 pixel area with an average displacement error of 0.1 pixels. This doubles the spatial resolution of conventional cross-correlation based Particle Image Velocimetry at comparable accuracy. Received: 26 June 1998/Accepted: 12 October 1999     

A numerical study of fully developed laminar flows in pipes with two planar curvatures

The spectral element method is applied on unstructured tetrahedral elements to solve the Navier–Stokes equations for fully developed laminar flow in pipes with two planar curvatures. Specific implementations of the spectral element method to double curved pipes and parallelization are described. Previous studies on flows in pipes focused on constant curvature or torsion geometries, as well as pipes with varying curvature. This study focuses on the periodic variation of both the curvature as well as torsion by analysing a pipe having two planar curvatures. The effects of the three parameters defining the pipe are studied to isolate the curvature and torsion effect on the magnitude and angle of the secondary flow. Furthermore, the geometric effects on the wall shear stress are studied, as it is an important fluid flow property, especially in blood flows. Copyright © 2006 John Wiley & Sons, Ltd.     

Design and performance of an ultra‐high‐vacuum‐compatible artificial channel‐cut monochromator

The design and performance of a novel ultra‐high‐vacuum‐compatible artificial channel‐cut monochromator that has been commissioned at undulator beamline 8‐ID‐I at the Advanced Photon Source are presented. Details of the mechanical and optical design, control system implementation and performance of the new device are given. The monochromator was designed to meet the challenging stability and optical requirements of the X‐ray photon correlation spectroscopy program hosted at this beamline. In particular, the device incorporates a novel in‐vacuum sine‐bar drive mechanism for the combined pitch motion of the two crystals and a flexure‐based high‐stiffness weak‐link mechanism for fine‐tuning the pitch and roll of the second crystal relative to the first crystal. The monochromator delivers an exceptionally uniform and stable beam and thereby improved brilliance preservation.