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121.
Oh Kuen Kwon Jun Ha Lee Jungchul Park Ki-Sub Kim Jeong Won Kang 《Current Applied Physics》2013,13(2):360-365
A tunable graphene-nanoribbon (GNR)-resonator was investigated via classical molecular dynamics simulations. Resonance frequencies increased with increasing externally applied gate-force and axial-strain, and could be tuned above several hundred GHz. Tunable resonance frequencies achieved from the gate force were higher than those achieved from the axial-strain. The operating frequencies of GNR-resonators without axial-strain or with small axial-strains were most widely tuned by the gate, and almost linearly increased with increasing mean deflection. As the axial strain increased, the tunable ranges of the GNR-resonators were exponentially decreased, although the operating frequencies increased. GNR-resonators without axial-strain could be applied to wide-range-tuners, whereas GNR-resonators with high axial-strain could be applied to high-frequency-fine-tuners. 相似文献
122.
Relationships between structure,ionization profile and sensitivity of exogenous anabolic steroids under electrospray ionization and analysis in human urine using liquid chromatography–tandem mass spectrometry
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Eunju Cha Sohee Kim Hee Won Kim Kang Mi Lee Ho Jun Kim Oh‐Seung Kwon Jaeick Lee 《Biomedical chromatography : BMC》2016,30(4):555-565
The relationships between the ionization profile, sensitivity, and structures of 64 exogenous anabolic steroids (groups I–IV) was investigated under electrospray ionization (ESI) conditions. The target analytes were ionized as [M + H]+ or [M + H–nH2O]+ in the positive mode, and these ions were used as precursor ions for selected reaction monitoring analysis. The collision energy and Q3 ions were optimized based on the sensitivity and selectivity. The limits of detection (LODs) were 0.05–20 ng/mL for the 64 steroids. The LODs for 38 compounds, 14 compounds and 12 compounds were in the range of 0.05–1, 2–5 and 10–20 ng/mL, respectively. Steroids including the conjugated keto‐functional group at C3 showed good proton affinity and stability, and generated the [M + H]+ ion as the most abundant precursor ion. In addition, the LODs of steroids using the [M + H]+ ion as the precursor ion were mostly distributed at low concentrations. In contrast, steroids containing conjugated/unconjugated hydroxyl functional groups at C3 generated [M + H ? H2O]+ or [M + H ? 2H2O]+ ions, and these steroids showed relatively high LODs owing to poor stability and multiple ion formation. An LC‐MS/MS method based on the present ionization profile was developed and validated for the determination of 78 steroids (groups I–V) in human urine. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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Simple scaling laws for the design parameters of plasma wakefield accelerators were obtained using a theoretical model, which were confirmed via particle simulation studies. It was found that the acceleration length was given by Δx=0.804λp/(1−βg), where λp is the plasma wavelength and βgc the propagation velocity of the ion cavity. The acceleration energy can also be given by ΔE=(γm−1)mc2=2.645mc2/(1−βg), where m is the electron rest mass. As expected, the acceleration length and energy increase drastically as βg approached unity. These simple scaling laws can be very instrumental in the design of better-performing plasma wakefield accelerators. 相似文献
126.
Hiu Yung Lam Rannveig Ingebrigtsen Gaarden Xuechen Li 《Chemical record (New York, N.Y.)》2014,14(6):1086-1099
Daptomycin, the first antibiotic of its class, provides a new structural motif for the development of new antibiotics. Recently, we have completed the total synthesis of daptomycin. The development of the successful synthetic strategy is described here, including the application of serine/threonine ligation mediated peptide cyclization to the daptomycin macrocyclization. 相似文献
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Mathematische Zeitschrift - We introduce new partial orders on the sequence positive roots and study the statistics of the poset by using Auslander–Reiten quivers for finite type ADE. Then we... 相似文献
128.
Gakhyun Kim Dr. Ranjan Dutta Dr. Won-Young Cha Dr. Seong-Jin Hong Dr. Juwon Oh Dr. Dikhi Firmansyah Hongil Jo Prof. Dr. Kang Min Ok Prof. Dr. Chang-Hee Lee Prof. Dr. Dongho Kim 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(69):16434-16440
π–π Stacking is omnipresent not only in nature but in a wide variety of practical fields applied to our lives. Because of its importance in a performance of natural and artificial systems, such as light harvesting system and working layer in device, many researchers have put intensive effort into identifying its underlying nature. However, for the case of π–π stacked systems composed of antiaromatic units, the understanding of the fundamental mechanisms is still unclear. Herein, we synthesized a new type of planar β,β’-phenylene-bridged hexaphyrin (1.0.1.0.1.0), referred as naphthorosarin which possesses the 24π-electron conjugated pathway. Especially, the corresponding antiaromatic porphyrinoid shows the unique property to form dimeric species adopting the face-to-face geometry which is unprecedented in cases of known annulated naphthorosarins. In order to elucidate the intriguing properties derived from the stacked dimer, the current study focuses on the experimental support to rationalize the observed π–π interactions between the two subunits. 相似文献
129.
Yongho Shin Tae Yeon Kong Jae Cheol Cheong Jin Young Kim Jae Il Lee Hye Suk Lee 《Biomedical chromatography : BMC》2019,33(9)
A liquid chromatography–tandem mass spectrometric method for the simultaneous determination of 75 abuse drugs and metabolites, including 19 benzodiazepines, 19 amphetamines, two opiates, eight opioids, cocaine, lysergic acid diethylamide, zolpidem, three piperazines and 21 metabolites in human hair samples, was developed and validated. Ten‐milligram hair samples were decontaminated, pulverized using a ball mill, extracted with 1 mL of methanol spiked with 28 deuterated internal standards in an ultrasonic bath for 60 min at 50°C, and purified with Q‐sep dispersive solid‐phase extraction tubes. The purified extracts were evaporated to dryness and the residue was dissolved in 0.1 mL of 10% methanol. The 75 analytes were analyzed on an Acquity HSS T3 column using gradient elution of methanol and 0.1% formic acid and quantified in multiple reaction monitoring mode with positive electrospray ionization. Calibration curves were linear (r ≥ 0.9951) from the lower limit of quantitation (2–200 pg/mg depending on the drug) to 2000 pg/mg. The coefficients of variation and accuracy for intra‐ and inter‐assay analysis at three QC levels were 4.3–12.9% and 89.2–109.1%, respectively. The overall mean recovery ranged from 87.1 to 105.3%. This method was successfully applied to the analysis of 11 forensic hair samples obtained from drug abusers. 相似文献
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