多缺陷结构的一维磁光多层膜隔离器

由磁光介质（M）和电介质（G）周期性排列构成的磁光光子晶体会出现很强的光 局域性，最近用它来实现磁光隔离器引起人们广泛的兴趣.给出了一种可用于计算 偏振光在各向异性介质传播问题的传输矩阵方法.并用该方法计算了对称多缺陷结构磁光多 层膜隔离器的光学性质，发现随着缺陷数目的增多，旋转角及透过率的频谱响应得到改善. 当缺陷增加到一定数目时，不需要额外的反射层即可实现反射型磁光隔离器的要求. 关键词： 光隔离器 磁光效应 多层膜 光子晶体     

A hybrid immersed‐boundary and multi‐block lattice Boltzmann method for simulating fluid and moving‐boundaries interactions

A numerical method is developed for modelling the interactions between incompressible viscous fluid and moving boundaries. The principle of this method is introducing the immersed‐boundary concept in the framework of the lattice Boltzmann method, and improving the accuracy and efficiency of the simulation by refining the mesh near moving boundaries. Besides elastic boundary with a constitutive law, the method can also efficiently simulate solid moving‐boundary interacting with fluid by employing the direct forcing technique. The method is validated by the simulations of flow past a circular cylinder, two cylinders moving with respect to each other and flow around a hovering wing. The versatility of the method is demonstrated by the numerical studies including elastic filament flapping in the wake of a cylinder and fish‐like bodies swimming in quiescent fluid. Copyright © 2006 John Wiley & Sons, Ltd.     

An efficient one-pot reaction of indoles, nitroacetate, and paraformaldehyde for the synthesis of tryptophan derivatives

An efficient method for the synthesis of tryptophan analogues has been developed via one-pot reaction of commercial available indoles, ethyl nitroacetate, and paraformaldehyde in the presence of molecular sieves. The reaction provided tryptophan nitro-precursors in moderate to good yields, which were further converted to α-hydroxymethylated tryptophan derivatives catalyzed by DABCO in high yields.     

反射型LCOS器件纯相位调制特性的研究

研究了反射型的LCOS显示器件的相位调制特性.采用2×2的Jones矩阵计算仿真，从理论上分析了它的相位调制特性，建立了一套测量振幅和相位特性的测试系统.它采用He-Ne激光为光源，用干涉仪观察波前相位，将LCOS显示器件作为液晶空间光调制器，用计算机和相关的电路系统驱动控制，并用CCD采样数据，测试了1024×768 LCOS显示器件的相位调制特性.理论和实验的一致性说明了在特定的入射、出射偏振光配制下，LCOS显示器件可以做纯相位调制器. 关键词： 空间光调制器 液晶显示器 反射型LCOS     

Positive periodic solutions for a nonlinear difference system via a continution theorem

Based on a continuation theorem of Mawhin, the existence of a positive periodic solution for a nonlinear difference system is studied.     

Effects of Ag Atomic Segregation from Different Planes on the Size-Dependent Melting of Ag–Pd Clusters

This paper studies the effects of Ag atomic segregation from the inner (100) or (111) planes on the melting of Ag–Pd clusters with different sizes by a molecular dynamics simulation. The results show that Ag segregation leads to the atomic energy decreases with increasing the temperature. Furthermore, the effect of the (100) segregation is larger than that of the (111) segregation. Meanwhile, the influence of segregation on the energy decreases with increasing the cluster size. The melting points of the clusters without segregation are the largest, followed by the clusters with a (111) and (100) segregation.     

Simultaneous determination of seven bioactive components in Guizhi Fuling capsule by microwave-assisted extraction combined with ultra performance liquid chromatography tandem mass spectrometry

A simple, rapid and reliable microwave-assisted extraction (MAE) combined with ultra performance liquid chromatography tandem mass spectrometry method was developed for simultaneous determination of the seven bioactive constituents in Guizhi Fuling capsule (GFC), namely gallic acid, amygdalin, albiflorin, paeoniflorin, paeonol, cinnamic acid and pachymic acid, respectively. The operation of MAE optimised through orthogonal array design experiment was performed at 80°C for 10 min with methanol–water (70:30, v/v) as the extracting solvent. The method was validated including intra- and inter-day precision, repeatability and stability, with relative standard deviation less than 3.9%, 3.3%, 4.4% and 3.1%, respectively. All analytes showed the good linearity (r >0.999), and their average recoveries varied between 98.2% and 101.2%. The results indicated that this method was simple, effective and suitable for the quality control of GFC.     

Sesquiterpene-neolignans from Manglietia hookeri

The comet assay-guided fractionation of the twigs of Manglietia hookeri resulted in the isolation of three sesquiterpene-neolignans, including a new one 5-allyl-2-(4-allyl-phenoxy)-3-[7-(1-hydroxy-1-methyl-ethyl)-1, 4a-dimethyl-decahydro-naphthalen-1-yloxy]-phenol (1), and eudesobovatol A (2) and eudesobovatol B (3), together with three lignans, obovatol (4), honokiol (5) and magnolol (6). Their structures were elucidated on the basis of spectral analysis and by comparison with related literature data. Compounds 1, 4–6 showed a protective effect on UV inductive DNA damage in mice lymphocyte cells, while compound 1 indicated the smallest Olive Tail Moment 7.34 ± 2.09 at 6 × 10^?6 μM.     

Nitrogen Analogues of Thiele’s Hydrocarbon

A series of bis[N,N‐di‐(4‐methoxylphenyl)amino]arene dications 1 ²⁺– 3 ²⁺ have been synthesized and characterized. Their electronic structures were investigated by various experiments assisted by theoretical calculations. It was found that they are singlets in the ground state and that their diradical character is dependent on the bridging moiety. 3 ²⁺ has a smaller singlet–triplet energy gap and its excited triplet state is thermally readily accessible. The work provides a nitrogen analogue of Thiele’s hydrocarbon with considerable diradical character.     

井筒保护煤柱合理留设的相似材料模拟

本文首先给出了冠山矿井筒保护煤柱的留设方案，然后介绍了用相似材料模型检验其合理性的原理，过程和结果。