全文获取类型
收费全文 | 813篇 |
免费 | 21篇 |
国内免费 | 3篇 |
专业分类
化学 | 592篇 |
晶体学 | 21篇 |
力学 | 26篇 |
数学 | 72篇 |
物理学 | 126篇 |
出版年
2023年 | 3篇 |
2022年 | 7篇 |
2021年 | 15篇 |
2020年 | 10篇 |
2019年 | 4篇 |
2018年 | 6篇 |
2017年 | 9篇 |
2016年 | 20篇 |
2015年 | 12篇 |
2014年 | 31篇 |
2013年 | 47篇 |
2012年 | 49篇 |
2011年 | 59篇 |
2010年 | 34篇 |
2009年 | 29篇 |
2008年 | 50篇 |
2007年 | 38篇 |
2006年 | 37篇 |
2005年 | 45篇 |
2004年 | 44篇 |
2003年 | 30篇 |
2002年 | 40篇 |
2001年 | 32篇 |
2000年 | 37篇 |
1999年 | 36篇 |
1998年 | 12篇 |
1997年 | 12篇 |
1996年 | 14篇 |
1995年 | 8篇 |
1994年 | 11篇 |
1993年 | 9篇 |
1992年 | 5篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1986年 | 5篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1978年 | 4篇 |
1976年 | 1篇 |
1975年 | 3篇 |
1974年 | 1篇 |
1973年 | 2篇 |
1972年 | 1篇 |
1970年 | 2篇 |
1968年 | 1篇 |
1967年 | 2篇 |
排序方式: 共有837条查询结果,搜索用时 31 毫秒
121.
122.
123.
T. S. Kim T. V. Cuong C. S. Park J. Y. Park H. J. Lee E. -K. Suh C. -H. Hong 《Journal of Crystal Growth》2004,260(3-4):336-342
GaAs1−xNx epilayers were grown on a GaAs(0 0 1) substrate by metalorganic chemical vapor deposition. Composition was determined by high resolution X-ray diffraction. Band gap was measured from 77 to 400 K by using photocurrent measurements. The photocurrent spectra show clear near-band-edge peak and their peak energies drastically decrease with increasing nitrogen composition due to band gap bowing in the GaAs1−xNx epilayers. Those red shifts were particularly notable for low nitrogen compositions. However, the shifts tended to saturate when the nitrogen composition become higher than 0.98%. When the nitrogen composition is in the range 1.68–3.11%, the measured temperature dependence of the energy band gap was nicely fitted. However, the properties for the nitrogen composition range 0.31–0.98% could not be fitted with a single fitting model. This result indicates that the bowing parameter reaches 25.39 eV for low nitrogen incorporation (x=0.31%), and decreases with increasing nitrogen composition. 相似文献
124.
T.S. Kim J.Y. Park T.V. Cuong H.J. Lee E.-K. Suh C.-H. Hong 《Journal of Crystal Growth》2004,270(3-4):340-345
The tri-methyl-Sb flow and the surfactant time dependence of photocurrent (PC) spectra was studied on InGaAsN/GaAs-strained multiple quantum wells (MQWs) structures grown by using metalorganic chemical vapor deposition (MOCVD). The structural properties of InGaAsN/GaAs-strained MQWs were investigated by using high-resolution X-ray diffraction (HRXRD). In the case of InGaAsN/GaAs-strained MQWs, an increase in compressive strain from an analysis of the satellite peaks in HRXRD was observed on increasing the tri-methyl-Sb flow and the surfactant time. For InGaAsN/GaAs-strained MQWs, the peaks observed in the photocurrent spectra were preliminarily assigned to electron–heavy hole (e1–hh) and electron–light hole (e1–lh) fundamental excitonic transitions. Their peaks are red-shifted with increasing tri-methyl-Sb flow and surfactant time. But the photocurrent peak is blue-shifted at the surfactant time of . It seems to be due to the improvement of structure properties at interface owing to a surfactant-suppressing surface diffusion phenomenon during growth. We compared this with the result of the experimental energies for InGaAsN/GaAs-strained MQWs. 相似文献
125.
The complex, [Zn(L)(NCO)]Cl · 3H2O (1) (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,01.18,07.12]docosane), has been synthesized and structurally characterized. 1 crystallizes in the monoclinic system, space group P21/n with a = 10.530(3), b = 9.315(2), c = 27.188(3) Å, = 92.58(1)°, V = 2664.1(9)Å3, and Z = 4. The zinc atom is in a distorted squarepyramidal environment with the four nitrogen atoms of the macrocycle and one nitrogen atom of the isocyanate ligand. 相似文献
126.
A novel compound catena-(-CrO4-O,O)[Ni(L1)Ni(L2)] 3H2O (1) (L1 = 3,5,10,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane and L2 = 2,5,9,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane) has been synthesized for the first time and structurally characterized. 1 crystallizes in the triclinic space group P with a = 9.623(1), b = 10.084(1), c = 12.723 (3) Å, = 66.74(2), = 75.20(1), = 72.02(1)°, V = 1066.2(3) Å3, and Z = 2. The coordination environment around the Ni(II) ions is an axially elongated octahedron with the secondary amines of the isomeric ligands and two oxygen atoms of [CrO4]2–. 相似文献
127.
We present a facile and straightforward method to synthesize uniform poly(vinyl amine) hydrogel shells with excellent loading capability for active materials and controllable responsiveness to applied stimuli, providing tunable releasing properties. 相似文献
128.
We present the effects of oxygen on the irreversible bonding of a microchannel using an ultraviolet (UV) curable material of polyurethane acrylate (PUA). Microchannels were fabricated by bonding a top layer with impressions of a microfluidic channel and a bottom layer consisting of a PUA coating on a glass or a polyethylene terephthalate (PET) film substrate. The resulting channel is a homogeneous conduit of the PUA material. To find optimal bonding conditions, the bottom layer was cured under different oxygen concentration and UV exposure time at a constant UV intensity (10 mW cm(-2)). Our experimental and theoretical studies revealed that the channel bonding is severely affected by the concentration of oxygen either in the form of trapped air or permeated air out of the channel. In addition, an optimal UV exposure time is needed to prevent clogging or non-bonding of the channel. 相似文献
129.
130.
Novel blue emitters, oligo-MCPPs (tri-MCPP, tetra-MCPP, and penta-MCPP), have been synthesized and characterized. The introduction of cyclopenta[def]phenanthrene (CPP) units into the structure of oligo-MCPPs gave LEDs with high efficiency and pure blue emission. UV-visible absorption spectra of the thin films of these compounds appear at 333-354 nm, and their maximum PL emission at 416-447 nm. Multilayer organic EL devices with oligo-MCPPs as an emitting layer showed the turn-on voltage of about 4.8 V, the maximum brightness of 1076 cd/m2 (at 8.2 V), the maximum luminescence efficiency of 0.81 cd/A, and the CIE coordinates of (0.17, 0.14) with blue color. 相似文献