全文获取类型
收费全文 | 286篇 |
免费 | 7篇 |
专业分类
化学 | 239篇 |
晶体学 | 4篇 |
力学 | 2篇 |
数学 | 3篇 |
物理学 | 45篇 |
出版年
2021年 | 2篇 |
2020年 | 5篇 |
2019年 | 4篇 |
2018年 | 2篇 |
2017年 | 2篇 |
2016年 | 3篇 |
2015年 | 4篇 |
2014年 | 6篇 |
2013年 | 11篇 |
2012年 | 10篇 |
2011年 | 8篇 |
2010年 | 7篇 |
2009年 | 6篇 |
2008年 | 9篇 |
2007年 | 13篇 |
2006年 | 11篇 |
2005年 | 16篇 |
2004年 | 19篇 |
2003年 | 24篇 |
2002年 | 20篇 |
2001年 | 13篇 |
2000年 | 7篇 |
1999年 | 4篇 |
1998年 | 8篇 |
1997年 | 5篇 |
1996年 | 7篇 |
1994年 | 1篇 |
1993年 | 4篇 |
1992年 | 7篇 |
1991年 | 7篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1982年 | 1篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1979年 | 6篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 3篇 |
1974年 | 2篇 |
1972年 | 3篇 |
1971年 | 1篇 |
1968年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有293条查询结果,搜索用时 62 毫秒
61.
A new P-chiral phosphine ligand, (R,R)-2,3-bis(tert-butylmethylphosphino)quinoxaline, has been prepared by the reaction of enantiomerically pure tert-butylmethylphosphine-borane with 2,3-dichloroquinoxaline. This ligand, in contrast to most of the previously reported P-chiral ligands, is an air-stable solid and exhibits excellent enantioselectivities in both Rh-catalyzed asymmetric hydrogenations and Rh- or Pd-catalyzed carbon-carbon bond-forming reactions. 相似文献
62.
Kitajima M Fujii N Yoshino F Sudo H Saito K Aimi N Takayama H 《Chemical & pharmaceutical bulletin》2005,53(10):1355-1358
Two new monoterpene glucosides, demethylsecologanol and 3'-O-glucosylsenburiside II, were isolated from Ophiorrhiza liukiuensis (Rubiaceae) together with 23 known compounds, including camptothecins and beta-carboline-type alkaloids. Their structures were determined by spectroscopic analysis. 相似文献
63.
Grignard reagents react with formic acid in tetrahydrofuran to produce aldehydes in relatively good yields Various aldehydes such as alkyl, aryl, allyl, benzyl and vinyl aldehydes were prepared from the corresponding Grignard reagents. The reaction with vinyl Grignard reagents proceeded with retention of configuration. 相似文献
64.
65.
Akio Kobori Taichiro Arai Yuya Sakata Takayuki Sugita Asako Yamayoshi Akira Murakami 《Tetrahedron letters》2018,59(41):3690-3693
Molecular switches controlled by light stimuli can be applicable to the variety of the biological application. In this study, skeletal structures of a chromophore of fluorescent protein were applied as aglycones of newly designed photochromic nucleosides, “Fluorescent protein-inspired nuceloside: FIN”. Phosphoramidite units of the photochromic nucleosides having imidazolinone derivatives with benzylidene or 3-pyridilidene groups were successfully synthesized for FIN-containing ODNs. Thermodynamic studies of the FIN-containing ODNs revealed that photo-irradiation with specific wavelength induced stability change of the duplexes. 相似文献
66.
Ryohei Sugita Natsuko I. Kobayashi Atsushi Hirose Yoshimi Ohmae Keitaro Tanoi Tomoko M. Nakanishi 《Journal of Radioanalytical and Nuclear Chemistry》2013,298(2):1411-1416
We have developed a real-time radioisotope imaging system (RRIS) that can nondestructively trace 14C-labeled chemicals in plants. In an experiment, after feeding 14CO2 to a plant, the plant was fixed inside a box where lighting was regulated, and beta rays emitted from the 14C in the plant were intermittently imaged using the developed system. As a first step, using a series of standard sources of 14C, the data depth and detection limits of the 14C images captured by the RRIS were evaluated for various integral times. As a result, the linearity between the 14C activity and signal intensity was determined for the range 103. Next, the linearity was validated using plant (Arabidopsis thaliana) organs, resulting that the linearity was shown in the case of young leaf, but was not maintained in the thick organs, such as a flower, mature leaf, siliques, and stem. Considering the good correlation between the intensity by RRIS and the PSL value by an imaging plate (IP) as well as the relative low energy of beta rays emitted from 14C, the thickness of the organs would easily affect the quantitativity of the RRIS as well as an IP. Our findings prove that sequential images of 14C in a living plant sample in a regulated light and air environment can be nondestructively analyzed using the developed system, whose quantitativity is similar to that of an IP. 相似文献
67.
68.
Nurul Sheeda Satoshi OkamiTakashi Komine Ryuji Sugita 《Journal of magnetism and magnetic materials》2008
Edge printing is one of the perpendicular magnetic printing methods for writing servo signals with high speed, high accuracy and low cost. Sub-peaks of waveform from edge printed media are concerned as the sub-peaks can cause errors during the read-back process. In this study, in order to reduce sub-peaks, the influence of printing field, bit length and patterned magnetic layer thickness of master medium on sub-peaks is investigated by using a metal-evaporated (ME) tape as a slave medium. The results show that sub-peak to main peak ratio decreases with stronger printing field, smaller bit length and thicker patterned magnetic layer of master media. 相似文献
69.
Yoshikazu Horino Miki Sugata Tetsu Sugita Ataru Aimono Hitoshi Abe 《Tetrahedron letters》2017,58(22):2131-2134
A palladium-catalyzed reaction of easily accessible 3-(pinacolatoboryl)allyl acetates and aldehydes provides facile access to synthetically useful homoaldol equivalent products with high diastereoselectivity. The reaction presumably proceeds via allylation of aldehydes with α-acetoxy allylboronates that produced in situ by reductive elimination from allylic gem-palladium/boryl intermediates. 相似文献
70.
Takashi Komine Kota Takahashi Hiroshi Murakami Ryuji Sugita 《Journal of magnetism and magnetic materials》2010,322(19):2969-2972
In this study, the effect of exchange stiffness constant on current-driven domain wall motion in nanowires with in-plane magnetic anisotropy (IMA) and perpendicular magnetic anisotropy (PMA) has been investigated using micromagnetic simulation. The critical current density in a nanowire with IMA decreases as the exchange stiffness constant decreases because the domain wall width at the upper edge of the nanowire narrows according to the decrease of the exchange stiffness constant. On the other hand, the critical current density in a nanowire with PMA slightly decreases contrary to that of IMA although the domain wall width reasonably decreases as the exchange stiffness constant decreases. The slight reduction rate of the critical current density is due to the increase of the effective hard-axis anisotropy of PMA nanowire. 相似文献