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361.
H.-J. Sue E. I. Garcia-Meitin N. A. Orchard 《Journal of Polymer Science.Polymer Physics》1993,31(5):595-608
The fracture behavior of a core-shell rubber (CSR) modified epoxy is investigated using both fracture mechanics and microscopy tools. The CSR-modified epoxy is found to be toughened via numerous line-array cavitations of the CSR particles, followed by plastic flow of the epoxy matrix. The toughening effect via the above craze-like damage process is found to be as effective as that of the well-known widespread rubber cavitation/matrix shear yielding mechanisms. The conditions for triggering the craze-like damage appear to be both stress state and rubber concentration dependent. The type of rubber tougheners utilized also plays a critical role in triggering this rather unusual craze-like damage in epoxy systems. © 1993 John Wiley & Sons, Inc. 相似文献
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We study the expected delay in cyclic polling models with general ‘branching-type’ service disciplines. For this class of
models, which contains models with exhaustive and gated service as special cases, we obtain closed-form expressions for the
expected delay under standard heavy-traffic scalings. We identify a single parameter associated with the service discipline
at each queue, which we call the ‘exhaustiveness’. We show that the scaled expected delay figures depend on the service policies
at the queues only through the exhaustiveness of each of the service disciplines. This implies that the influence of different
service disciplines, but with the same exhaustiveness, on the expected delays at the queues becomes the same when the system
reaches saturation. This observation leads to a new classification of the service disciplines. In addition, we show monotonicity
of the scaled expected delays with respect to the exhaustiveness of the service disciplines. This induces a complete ordering
in terms of efficiency of the service disciplines. The results also lead to new rules for optimization of the system performance
with respect to the service disciplines at the queues. Further, the exact asymptotic results suggest simple expected waiting-time
approximations for polling models in heavy traffic. Numerical experiments show that the accuracy of the approximations is
excellent for practical heavy-traffic scenarios.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
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Fe(II)--Fe(III) hydroxy-chloride, -sulphate and -carbonate were prepared by oxidation of a ferrous hydroxide precipitate in anion-containing aqueous solutions. The compounds are characterized by monitoring the redox potential Eh and the pH of stochiometric suspension vs time with the appropriate concentration ratios. X-ray diffraction allows us to characterize the crystal structure by distinguishing “green rust one” (GR1) from “green rust two” (GR2). Since green rusts (GRs) are of a pyroaurite-sjögrenite-like structure, i.e., consisting of intercalated foreign anions and water molecules in the interlayers between the brucite-like layers of Fe(OH)2, their chemical formulae can be determined from the Mössbauer spectra. Three quadrupole doublets are observed: D1 and D2 correspond to a ferrous state with isomershift IS of about 1.27 mm s-1 and quadrupole splittings QS of about 2.85 and 2.60 mm s-1, respectively, whereas D3 corresponds to a ferric state with IS and QS of about 0.4 mm s-1. The hyperfine parameters of these doublets are similar from one green rust to another but their intensity ratios vary considerably. Finally, Eh and pH equilibrium diagrams of the Fe species in the presence of chloride, sulphate and carbonate anions contained within the water solution are drawn and the thermodynamic conditions of existence and degrees of oxidation of green rusts are discussed. 相似文献
368.
H. Salehi 《International Journal of Theoretical Physics》1998,37(4):1253-1263
We study the quantum constraints of a conformalinvariant action for a scalar field. For this purpose webriefly present a reformulation of the duality principleadvanced earlier in the context of generally covariant quantum field theory, and apply it toexamine the finite structure of the quantum constraints.This structure is shown to admit a dimensional coupling(a coupling mediated by a dimensional coupling parameter) of states to gravity. Invariancebreaking is introduced by defining a preferredconfiguration of dynamical variables in terms of thelargescale characteristics of the universe. In thisconfiguration a close relationship between the quantumconstraints and the Einstein equations isestablished. 相似文献
369.
Fixed-frequency and threshold photoelectron spectra have been recorded for ionization from the S ls shells in SF6, CS2 and COS, the Si 1s shells in SiH4 and SiCl4 and the Cl 1s shell in SiCl4 using synchrotron radiation. Fixed-frequency spectra generally showed a single strong ionization feature with associated weak satellite structure due to excited ionized states. Threshold spectra closely resembled X-ray absorption spectra but with an additional feature due to direct ionization. In cases where resonant process enhanced the NEXAFS spectrum direct ionization was not observed. 相似文献
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