Influence of modified PET waste on synthesis and properties of styrene-acrylic emulsion

Glycolysis product of the waste PET was used to synthesis of 2-hydroxyethyl-4-{[(2-(prop-2-enoyloxy)ethoxy]carbonyl}benzoate (HETA) and further application in the emulsion polymerization of styrene/(meth)acrylic monomers. The resulting polymer dispersion was characterized by FTIR, DLS, TEM, and TGA. The experimental results reveal that HETA plays an important role in thermal, mechanical and other properties of the resulting polymer film.     

Preparation of Silver Nanoparticles Reduced by Formamidinesulfinic Acid and Its Application in Colorimetric Sensor

A rapid one-step preparation approach of silver nanoparticles (AgNPs) was reported by employing formamidinesulfinic acid as reducing agent and soluble starch as stabilizing agent. The formation of AgNPs was further confirmed by using UV–Vis absorption spectroscopy, X-ray diffraction spectroscopy and transmission electron microscopy techniques. The resultant AgNPs could be directly used for the colorimetric reaction with metal ions. The results showed that Al³⁺, Cr³⁺, Fe³⁺ and Hg²⁺ ions could induce the color change of AgNPs from yellow to pink (Al³⁺), orange (Cr³⁺) and colorless (Fe³⁺ and Hg²⁺), respectively, which can be observed by the naked eye. Based on these, a sensitive colorimetric sensor for Al³⁺, Fe³⁺, Cr³⁺ and Hg²⁺ ions detection was developed.     

Development of an <Emphasis Type="Italic">Agrobacterium</Emphasis>-Mediated Transformation Method and Evaluation of Two Exogenous Constitutive Promoters in Oleaginous Yeast <Emphasis Type="Italic">Lipomyces starkeyi</Emphasis>

The biogenic iron oxide/hydroxide materials possess useful combination of physicochemical properties and are considered for application in various areas. Their production does not require special investments because these compounds are formed during cultivation of neurophilic iron bacteria. Bacteria from genus Leptothrix develop intensively in the Sphaerotilus-Leptothrix group of bacteria isolation medium and feeding media of Fedorov and Lieske. These media are different in their composition which determined the present study as an attempt to clear up the reasons that define the differences in the composition of the laboratory-obtained biomasses and the natural biomass finds. FTIRS, Mössbauer spectroscopy, and XRD were used in the research. Comparative analysis showed that the biomass and control samples contain iron compounds (α-FeOOH, γ-FeOOH, β-FeOOH, γ-Fe₂O₃) in different ratios. The biomass samples were enriched in oxyhydroxides of higher dispersion. Organic residuals of bacterial origin, SO₄, CO₃, and PO₄ groups were registered in the biogenic materials.     

[O2Pb3]2(BO3)Br: An Oxidoborate Oxide Bromide with the ∞1[O2Pb3] Double Chains Based on Edge‐sharing OPb4 Tetrahedra

Through extensive research on the PbO / PbBr₂ / B₂O₃ system, a new single crystal of yellow lead‐containing oxyborate bromine, [O₂Pb₃]₂(BO₃)Br, was grown from the melt. It crystallizes in the centrosymmetric space group Cmcm (no. 63) of the orthorhombic system with the following unit cell dimensions: a = 9.5748(8) Å, b = 20.841(2) Å, c = 5.7696(5) Å, and Z = 4. The whole structure is characterized by an infinite one‐dimensional (1D) _∞¹[O₂Pb₃] double chain, which is based on the OPb₄ oxocentered tetrahedra and considered as the derivative of the continuous sheet of OPb₄ tetrahedra from the tetragonal modification of α‐PbO. The 1D _∞¹[O₂Pb₃] double chains are further bridged by the BO₃ units through common oxygen atoms to form two‐dimensional (2D) _∞¹[[(O₂Pb₃)(BO₃)] layers, with Br atoms situated between the layers. IR spectroscopy, UV/Vis/NIR diffuse reflectance spectroscopy, and thermal analysis were also performed on the reported material.     

Adaptive complete synchronization of the noise-perturbed two bi-directionally coupled chaotic systems with time-delay and unknown parametric mismatch

In this paper, we design an adaptive-feedback controller to synchronize a class of noise-perturbed two bi-directionally coupled chaotic systems with time-delay and unknown parametric mismatch. Based on invariance principle of stochastic time-delay differential equations, some sufficient conditions of adaptive complete synchronization are given. Comparing with other papers, here we consider the effect of internal noise, time-delay and parametric mismatch in the synchronized process. As the illustrative examples, the famous Lorenz system and Rössler system are considered here. In order to validate the proposed scheme, numerical simulations are performed, and the numerical results show that our scheme is very effective.     

改进的QuEChERS方法结合液相色谱-串联质谱法测定腐竹和豆干中的二甲基黄和二乙基黄

建立了基于改进的QuEChERS方法结合液相色谱-串联质谱测定腐竹和豆干中二甲基黄和二乙基黄的方法。在2.0 g腐竹和豆干样品中加入5 mL水浸泡,然后加入10 mL乙腈提取,加入1.0 g NaCl、2.0 g无水硫酸镁进行液液分离;取1 mL提取液经50 mg N-丙基二乙胺分散固相萃取净化,经液相色谱分离、质谱测定,外标法定量。二甲基黄在添加水平为0.3、1和10 μg/kg时,方法的回收率为73.5%~84.5%;二乙基黄在添加水平为0.1、1和10 μg/kg时,方法的回收率为70.5%~81.2%;方法的相对标准偏差小于11%。二甲基黄的检出限和定量限分别为0.1 μg/kg和0.3 μg/kg,二乙基黄的检出限和定量限分别为0.05 μg/kg和0.1 μg/kg。该方法可以用于腐竹、豆干中二甲基黄和二乙基黄的快速筛查和定量分析。     

平行机上带有前瞻区间的不相容工件组在线排序问题

研究当不相容工件组的个数与机器数相等时,具有前瞻区间的单位工件平行机无界平行分批在线排序问题.工件按时在线到达, 目标是最小化 最大完工时间. 具有前瞻区间是指在时刻t, 在线算法能预见到时间区间(t,t+\beta) 内到达的所有工件的信息.不可相容的工件组是指属于不同组的工件不能被安排在同一批中加工. \beta\geq 1 时, 提供了一个最优的在线算法; 当0\leq \beta < 1时, 提供了一个竞争比为1+\alpha 的最好可能的在线算法, 其中\alpha是方程\alpha^{2}+(1+\beta) \alpha+\beta-1=0的一个正根.最后, 给出了当\beta =0 时稠密算法竞争比的下界,并提供了达到该下界的最好可能的稠密算法.     

Further Example of Diphosphates: Synthesis and Characterization of K2Li2P2O7

By the application of cation substitution, a new mixed‐alkali metal diphosphate, K₂Li₂P₂O₇, was successfully synthesized through high temperature solution method for the first time. The single‐crystal X‐ray structural analysis shows that it crystallizes in the monoclinic space group C2/c (no. 15), with lattice constants a = 9.814(3) Å, b = 5.5163(15) Å, c = 13.538(4) Å, Z = 4, and β = 110.47(2)°. Its open cage‐like _∞³[Li₂(P₂O₇)]^2– framework is built up from alternating arrangement of Li₂O₆ and P₂O₇ dimers that form eight and twelve‐membered‐ring channels along the [010] direction, and the K atoms are entrapped in the larger twelve‐membered‐ring channels. Detailed structure comparisons in the N₄P₂O₇ (N = mixed alkali metals) family are discussed. In addition, the structural validity was verified through the IR spectrum. Thermal analyses and UV/Vis/NIR diffuse reflectance spectrum are also performed on the reported compound.     

一种新的海面空气动力学粗糙度方案

综合利用6个国际海洋观测试验资料,共同验证Charnock参数与无因次粗糙度长度(z0/Hs)对波龄的依赖性,建立粗糙度回归模型,并对其进行显著性和适用性检验,从而导出粗糙度无因子形式与有效波高有关.利用研制的粗糙度方案(SP07)研究充分发展风浪与风区、风时和水深的关系,及粗糙度长度对摩擦速度和波龄的敏感度.把SP07方案引人国际上最先进的计算海气通量的COARE(V3.0)算法中,选择1985年12月在北海的FPN平台上的试验资料,进一步检验SP07方案的适用性.得出目前国际上最先进的002和TY01方案较高估计了摩擦速度,YT96方案略偏低估计了摩擦速度,文中研制的方案计算结果与实测结果最接近.     

Ce:KNSBN晶体光扇效应的入射光强度阈值特性研究

采用非同时读出条件下的两波耦合实验装置,以单束光入射Ce:KNSBN光折变晶体,系统研究了Ce:KNSBN晶体中光扇效应随入射光偏振态、入射光强度、光入射角的变化情况.结果表明异常偏振光入射晶体时光扇效应明显,且存在明显的入射光强度阈值特性,入射光强度阈值为38.2 mW/cm2;相同光入射角下,稳态光扇强度随入射光强度的增强而明显变大;对应相同的入射光强度,稳态光扇强度随光入射角θ的增大而增大,当θ为15°时到达峰值,而后随θ的增大而逐渐减小.同时对光扇效应的入射光强度阈值特性以及稳态光扇强度随入射光偏振态、入射光强度、光入射角的变化作出了相应的物理解释.