Isospin Effect on the Emission Mechanism of Hot Nuclei in 35MeV/u 40Ar +112Sn/124Sn Reactions

As an extension of radioactive ion beam physics, the research on isospin dependent properties of hot nuclei has increasingly attracted considerable interest. The isospin effect on the decay of hot nuclei in reactions 35MeV/u ⁴⁰Ar+¹¹²Sn/¹²⁴Sn has been investigared. It is concluded that due to Coulomb repulsion and instability, proton-rich hot nuclei probably emit prides such as a with high energy to increase their neutron-proton ratio. Moreover, the decay chain for those particles is seemingly long and the emission Probability is high. Thus, the conventional observations, for instance, the ‘slope temperature’ extracted from energy spectrum, may very appreciably with the measured particles.     

碳纳米管的功能化研究进展

综述了碳纳米管功能化的一些最新研究进展,重点介绍了一些功能化方法、功能化碳纳米管的性能表征及应用前景。文献49篇。     

Ce∶KNSBN晶体光扇效应的入射光强度阈值特性研究

采用非同时读出条件下的两波耦合实验装置,以单束光入射Ce∶KNSBN光折变晶体,系统研究了Ce∶KNSBN晶体中光扇效应随入射光偏振态、入射光强度、光入射角的变化情况。结果表明异常偏振光入射晶体时光扇效应明显,且存在明显的入射光强度阈值特性,入射光强度阈值为38.2mW/cm2;相同光入射角下,稳态光扇强度随入射光强度的增强而明显变大;对应相同的入射光强度,稳态光扇强度随光入射角θ的增大而增大,当θ为15°时到达峰值,而后随θ的增大而逐渐减小。同时对光扇效应的入射光强度阈值特性以及稳态光扇强度随入射光偏振态、入射光强度、光入射角的变化作出了相应的物理解释。     

Synthesis and Optical Properties of Novel Carbazole Derivatives Containing Pyridine Ring

A series of novel monodisperse, well‐defined molecules with a pyridine core and carbazole arms were synthesized by simple procedures with Iodo‐reaction and Ullmann reaction. Their structures were confirmed by IR, ¹H NMR, ¹³C NMR, and elementary analysis. Moreover, the fluorescence spectra showed that these compounds exhibited strong fluorescence with the maximum wavelengths ranging from 373 to 385 nm.     

GC-MS Assisted with Chemometric Methods Applied for Investigation of Migration Behavior of Phthalate Plasticizers in Fatty Foods Simulant

PVC films with different thickness and different contents of 9 phthalate plasticizers (PAEs) were manufactured according to a uniform design method. The migration contents of PAEs in isooctane, which was set as a fatty foods simulant, were first determined using GC-MS analysis. It was found that the chromatographic peaks of diisononyl ortho-phthalate (DINP) and diisodecyl ortho-phthalate (DIDP) very considerably overlapped, with a lower signal to noise ratio (SNR). For resolution of the noisy overlapped peaks, twice continuous wavelet transform (CWT) was adopted. Then, the migration models of PAEs were obtained by the non-negative least squares method (NNLS). The results show that the noisy overlapped peaks were successfully resolved with increasing the SNR 10 times; the migration ratio of the 9 PAEs at 70 °C are located with the range 0.0556–0.3383 %; the migration amount of a specific plasticizer is proportional to its content and some coexisting plasticizers; temperature is a significant impact factor for the migration process. The proposed chemometric-assisted GC-MS analysis provides a new approach for investigation of this complex process.     

新一代照明光源白光LED的发展概况

1概述 目前，常见照明光源存在一定的不足：真空器件体积大，易碎，发光效率低；日光灯短波紫外线激发波长更长的红绿蓝荧光粉发光，发光效率低，寿命短．体积小，效率高，能耗低，寿命长成为对未来新一代照明光源的基本要求，并且要使光源光谱的分布尽量接近太阳光谱，才能与眼睛的特性相匹配．满足这一条件最好方法就是用两种或多种色光合成白光．     

Influence of modified PET waste on synthesis and properties of styrene-acrylic emulsion

Glycolysis product of the waste PET was used to synthesis of 2-hydroxyethyl-4-{[(2-(prop-2-enoyloxy)ethoxy]carbonyl}benzoate (HETA) and further application in the emulsion polymerization of styrene/(meth)acrylic monomers. The resulting polymer dispersion was characterized by FTIR, DLS, TEM, and TGA. The experimental results reveal that HETA plays an important role in thermal, mechanical and other properties of the resulting polymer film.     

Preparation of Silver Nanoparticles Reduced by Formamidinesulfinic Acid and Its Application in Colorimetric Sensor

A rapid one-step preparation approach of silver nanoparticles (AgNPs) was reported by employing formamidinesulfinic acid as reducing agent and soluble starch as stabilizing agent. The formation of AgNPs was further confirmed by using UV–Vis absorption spectroscopy, X-ray diffraction spectroscopy and transmission electron microscopy techniques. The resultant AgNPs could be directly used for the colorimetric reaction with metal ions. The results showed that Al³⁺, Cr³⁺, Fe³⁺ and Hg²⁺ ions could induce the color change of AgNPs from yellow to pink (Al³⁺), orange (Cr³⁺) and colorless (Fe³⁺ and Hg²⁺), respectively, which can be observed by the naked eye. Based on these, a sensitive colorimetric sensor for Al³⁺, Fe³⁺, Cr³⁺ and Hg²⁺ ions detection was developed.     

Development of an <Emphasis Type="Italic">Agrobacterium</Emphasis>-Mediated Transformation Method and Evaluation of Two Exogenous Constitutive Promoters in Oleaginous Yeast <Emphasis Type="Italic">Lipomyces starkeyi</Emphasis>

The biogenic iron oxide/hydroxide materials possess useful combination of physicochemical properties and are considered for application in various areas. Their production does not require special investments because these compounds are formed during cultivation of neurophilic iron bacteria. Bacteria from genus Leptothrix develop intensively in the Sphaerotilus-Leptothrix group of bacteria isolation medium and feeding media of Fedorov and Lieske. These media are different in their composition which determined the present study as an attempt to clear up the reasons that define the differences in the composition of the laboratory-obtained biomasses and the natural biomass finds. FTIRS, Mössbauer spectroscopy, and XRD were used in the research. Comparative analysis showed that the biomass and control samples contain iron compounds (α-FeOOH, γ-FeOOH, β-FeOOH, γ-Fe₂O₃) in different ratios. The biomass samples were enriched in oxyhydroxides of higher dispersion. Organic residuals of bacterial origin, SO₄, CO₃, and PO₄ groups were registered in the biogenic materials.     

[O2Pb3]2(BO3)Br: An Oxidoborate Oxide Bromide with the ∞1[O2Pb3] Double Chains Based on Edge‐sharing OPb4 Tetrahedra

Through extensive research on the PbO / PbBr₂ / B₂O₃ system, a new single crystal of yellow lead‐containing oxyborate bromine, [O₂Pb₃]₂(BO₃)Br, was grown from the melt. It crystallizes in the centrosymmetric space group Cmcm (no. 63) of the orthorhombic system with the following unit cell dimensions: a = 9.5748(8) Å, b = 20.841(2) Å, c = 5.7696(5) Å, and Z = 4. The whole structure is characterized by an infinite one‐dimensional (1D) _∞¹[O₂Pb₃] double chain, which is based on the OPb₄ oxocentered tetrahedra and considered as the derivative of the continuous sheet of OPb₄ tetrahedra from the tetragonal modification of α‐PbO. The 1D _∞¹[O₂Pb₃] double chains are further bridged by the BO₃ units through common oxygen atoms to form two‐dimensional (2D) _∞¹[[(O₂Pb₃)(BO₃)] layers, with Br atoms situated between the layers. IR spectroscopy, UV/Vis/NIR diffuse reflectance spectroscopy, and thermal analysis were also performed on the reported material.