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131.
In the present work, a comprehensive study of advection–diffusion equation is made using B-spline functions. Advection–diffusion equation has many physical applications such as dispersion of dissolved salts in groundwater, spread of pollutants in rivers and streams, water transfer, dispersion of tracers, and flow fast through porous media. Motivation behind the proposed scheme is to present a solution scheme which is easy to understand. Both linear and quadratic B-spline functions have been used in the present work to understand the basic aspect and advantages of the presented scheme. Along with this, some test examples are studied to observe the correctness of the numerical experiments. Finally, different comparisons are made to cross check the results obtained by the given scheme. 相似文献
132.
Experimental data on masses and lifetimes of unstable particles falls into a pattern, a brief review of some interesting consequences
is presented here. From the experience in semiclassical methods and recent advances in quantum chromodynamics, it is proposed
that an appropriate generalization of the Gutzwiller trace formula for field theories may lead to a systematic semiclassical
chromodynamics theory. The theory can be developed to get appropriate dynamics leading to an explanation of pattern discovered
in the empirical data. 相似文献
133.
Reactions of various halogenated peroxyl radicals with guanine, uric acid, xanthine, hypoxanthine and ascorbic acid in a quaternary microemulsion consisting of sodium lauryl sulfate/water/1-pentanol/cyclohexane have been studied using the technique of pulse radiolysis. For all purine derivatives and ascorbic acid, formation of the respective radical cations have been observed. Variation in biomolecular rate constant values for the reactions of peroxyl radicals with the above-mentioned compounds has been discussed in terms of diffusion of radicals. 相似文献
134.
Kapoor Pratibha Kumar Ajay Nistandra Jyotsna Venugopalan Paloth 《Transition Metal Chemistry》2000,25(4):465-469
The title compound N,N,N′,N′-tetraethylpyridine-2,6-dicarboxamide (DEAP) forms a 1:1 complex with anhydrous CuCl2, [Cu(DEAP)Cl2], (1) which was crystallized from EtOH solution in the monoclinic space group P21/ n with cell constant, a = 10.024(1); b = 13.122(1); c = 14.404(1) Å β = 101.31(1)° V = 1857.8(3) Å3 and Z = 4. The chloro-perchlorato complex, [Cu(DEAP)Cl(ClO4)], (2) obtained in near quantitative yield by reacting (1) with an excess of NaClO4 in EtOH, crystallized in the monoclinic space group P21/ n with cell constants, a = 7.965(1); b = 25.827(2); c = 10.046(1) Å β = 98.81(1)° V = 2042.2(4) Å3 and Z = 4. Both (1) and (2) contain 5-coordinated copper linked to DEAP through O~N~O donor set of atoms with covalently bonded chlorine atoms in (1) and chlorine and perchlorate groups in (2). The coordination geometry is intermediate between square pyramidal and trigonal bipyramidal, and is probably best described as a trigonally distorted rectangular pyramid. 相似文献
135.
The study of dilute Sc impurities in either heavier d-transition metals or in alkali metal hosts is difficult due to their limited solubility; however, the large host-impurity mismatch in these systems makes them particularly interesting in terms of local electronic structure. One way to overcome the solubility problem is implantation into the desired host; in particular, using recoil implantation following heavy-ion nuclear reactions, deep implantation into practically any host can be achieved. Here, we compare the implantation of 43Sc into Cs, studied in situ by the in-beam TDPAD method [1], with the implantation of 44m
Sc into Fe, studied by low-temperature nuclear orientation (LTNO) and related techniques (NMRON, thermal cycling) [2]. 相似文献
136.
We employ the spectral properties of cyclic random matrices to understand the approach to equilibrium of a biased random walk on a disordered lattice. The simplicity of the calculations and the flexibility with which randomness can be modelled makes it a worthwhile alternative. 相似文献
137.
Suresh E. Kurhade Sudhir RavulaV. Siddaiah Debnath BhuniyaD. Srinivasa Reddy 《Tetrahedron letters》2011,52(33):4313-4315
A convenient one-step method for the synthesis of novel dihydrooxazine and oxazoline based sugar hybrids is reported starting from the readily accessible sugar azides and aldehydes. We have used Aubé’s protocol to achieve this transformation. The resulting glycoconjugates could be used to increase the diversity on the sugar backbone and may find applications as potential glycomimetics and in drug discovery. 相似文献
138.
The nucleon exchange process between two nuclei in close proximity and its application to an explanation of fragment mass
and charge distributions in fission and in heavy ion deep inelastic collisions are reviewed. An analysis of the measured correlations
between the energy loss from relative motion and the fragment mass and charge variances in the heavy ion deep inelastic collisions
is presented. The recent data on fragment mass and charge variances as a function of the fragment kinetic energy in thermal
neutron induced fission of235U, lends added support to the hypothesis that the nucleon transport process plays a similar role both in fission and in heavy
ion deep inelastic collisions. 相似文献
139.
Sudhir Malik S. K. Soni R. K. Shivpuri 《Zeitschrift fur Physik C Particles and Fields》1995,67(2):239-244
Experimental results on multiplicity distributions for full phase space and in different pesudorapidity windows of charged secondary particles produced in proton-nucleon collisions at 800 GeV are presented and discussed. It is found that all these multiplicity distributions are well described by negative binomial distributions. We interpret our results on the basis of clan model. The bin size dependence of multiplicity distribution of charged secondary particles in proton-nucleon interactions is analysed in terms of multifractals. The values of generalised dimensions obtained from fitted distributions show a good agreement with those obtained from the data. 相似文献
140.
Formations of triplet state, molecular cation radical, and phenoxyl radical of 3,4‐methylenedioxy phenol (sesamol, SOH) in organic solvents have been investigated by laser photolysis as well as pulse radiolysis techniques. Photolysis of SOH in cyclohexane has been found to produce both triplet state (λmax ~ 480 nm) and phenoxyl radical (425–430 nm) of SOH by mono‐photonic processes. However, radical cation (λmax = 450 nm) and phenoxyl radical of SOH have been observed on radiolysis in cyclohexane. Further, radiolysis of SOH in benzene has been found to produce phenoxyl radical only. Mechanism of phenoxyl radical formation by photo‐excitation of SOH has been studied and triplet energy level of SOH is estimated to lie between 1.85 and 2.64 eV. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献