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31.
The current research focuses on the creation of a general technique that solves the key issue of any operational chemical plant, namely, how to strike a delicate balance between profit and environmental impact. As a case study, a commercial vinyl chloride monomer (VCM) production unit was used. This research produced a new modelling and optimization tool that commercial chemical plants can use to measure their environmental impact and strike a careful balance between profit and environmental damage. This paper demonstrates how to model commercial complex reactors using Aspen and ANN in an easy-to-use manner. The current study used a multi-objective hybrid ANN and genetic algorithm to find a delicate balance between profit and environmental damage. A case study of a commercial VCM manufacturing process demonstrates the efficacy of the proposed methodology. The suggested methodology creates optimal VCM reactor operating parameters, which can be used in commercial plants to increase profit. Furthermore, the suggested methodology creates a set of Pareto optimal solutions platform to acquire insight into the profit-environmental impact balance. These insights could be extremely beneficial to plant management in making educated decisions about plant operations. 相似文献
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Fei Yu Sucharita Roy Enrique Arevalo John Schaeck Jason Wang Kimberly Holte Jay Duffner Nur Sibel Gunay Ishan Capila Ganesh V. Kaundinya 《Analytical and bioanalytical chemistry》2014,406(13):3079-3089
The binding affinity and specificity of heparin to proteins is widely recognized to be sulfation-pattern dependent. However, for the majority of heparin-binding proteins (HBPs), it still remains unclear what moieties are involved in the specific binding interaction. Here, we report our study using saturation transfer difference (STD) nuclear magnetic resonance (NMR) to map out the interactions of synthetic heparin oligosaccharides with HBPs, such as basic fibroblast growth factor (FGF2) and fibroblast growth factor 10 (FGF10), to provide insight into the critical epitopes of heparin ligands involved. The irradiation frequency of STD NMR was carefully chosen to excite the methylene protons so that enhanced sensitivity was obtained for the heparin–protein complex. We believe this approach opens up additional application avenues to further investigate heparin–protein interactions. 相似文献
33.
Dattatray J. Late Vindhyesh R. Singh Sucharita Sinha Mahendra A. More K. Dasgupta Dilip S. Joag 《Applied Physics A: Materials Science & Processing》2009,97(4):905-909
Micro/nano structures have been obtained by laser surface treatment on sintered LaB6 pellets employing a picosecond pulsed Nd:YAG laser at a pressure of ∼1×10−3 mbar. The X-ray diffraction pattern of the laser treated pellet shows a set of well defined diffraction peaks, indexed to
the cubic phase of LaB6 only. The scanning electron microscope studies reveal formation of micro and nano structures upon laser treatment and the
resultant surface morphology is found to be strongly influenced by the laser fluence. Field electron emission studies made
on the LaB6 pellet, treated with optimized laser fluence, have been performed in a planar diode configuration under ultra high vacuum
conditions. The threshold field required to draw an emission current density of ∼10 μA/cm2 has been found to be ∼2.3 V/μm and a current density of ∼530 μA/cm2 has been drawn at an applied field of 5.2 V/μm. The Fowler-Nordheim plot is found to be linear in accordance with the quantum
mechanical tunneling phenomenon, confirming the metallic nature of the emitter. The emission current at the pre-set value
∼10 μA shows very good stability over a period of more than 3 hours. The present results emphasize the effectiveness of a
picosecond laser treatment towards fabrication of a nano metric LaB6 emitter for high current density applications. 相似文献
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35.
Sucharita Sinha E. Ramadasan K. Dasgupta L.M. Gantayet 《Applied Surface Science》2007,253(9):4404-4408
Metallographic investigation of the microstructure of sintered Thoria pellets necessitates appropriate surface preparation of these pellets. Conventional etching methods involving either chemical or thermal etching techniques being unsuitable for surface etching of irradiated Thoria fuel, laser-based surface treatment was envisaged as a potential alternative technique. Thoria pellets were subjected to laser surface treatment using a pulsed Nd:YAG laser.Our preliminary studies have successfully demonstrated laser etching of sintered Thoria pellets with good reproducibility, clearly revealing grain structures and well-defined grain boundaries. Detailed parametric investigations determining optimum laser parameters for the process, are presented. Our results on ultra-short laser-based etching of sintered Thoria pellets are also discussed. 相似文献