Electrical characterization of Schottky diodes based on boron doped homoepitaxial diamond films by conducting probe atomic force microscopy

A large planar tungsten carbide (WC) Schottky diode on p-type homoepitaxial diamond was mainly investigated on a microscopic level by atomic force microscopy (AFM) and conducting probe atomic force microscopy (CP-AFM), allowing simultaneous topographic and local electrical resistance imaging measurements. These techniques revealed the existence of a specific microstructure on the WC Schottky contact consisting of electrically insulating islands surrounded by conductive paths. The islands are found to be insulating in the whole range of explored bias [−5 V, +5 V], whereas the current flowing between the islands is 1000 times lower at a reverse bias of −5 V than at a forward bias of +5 V, in agreement with the rectifying ratio found from macroscopic current–voltage (I–V) measurements. CP-AFM provides a prospective imaging tool which is well suited for analyzing the local electrical properties and instabilities of Schottky junctions.     

Six‐wave mixing induced by free‐carrier plasma in silicon nanowire waveguides

Nonlinear wave mixing in mesoscopic silicon structures is a fundamental nonlinear process with broad impact and applications. Silicon nanowire waveguides, in particular, have large third‐order Kerr nonlinearity, enabling salient and abundant four‐wave‐mixing dynamics and functionalities. Besides the Kerr effect, in silicon waveguides two‐photon absorption generates high free‐carrier densities, with corresponding fifth‐order nonlinearity in the forms of free‐carrier dispersion and free‐carrier absorption. However, whether these fifth‐order free‐carrier nonlinear effects can lead to six‐wave‐mixing dynamics still remains an open question until now. Here we report the demonstration of free‐carrier‐induced six‐wave mixing in silicon nanowires. Unique features, including inverse detuning dependence of six‐wave‐mixing efficiency and its higher sensitivity to pump power, are originally observed and verified by analytical prediction and numerical modeling. Additionally, asymmetric sideband generation is observed for different laser detunings, resulting from the phase‐sensitive interactions between free‐carrier six‐wave‐mixing and Kerr four‐wave‐mixing dynamics. These discoveries provide a new path for nonlinear multi‐wave interactions in nanoscale platforms.

     

Transition from strong-field sequential to nonsequential double ionization at near-infrared wavelengths and low intensities

Within a quantum-mechanical model, we investigate strong-field double ionization of a model helium atom by near-infrared, linearly polarized laser pulses at intensities far below the recollision threshold. The quantum simulations show a clear mechanism change from sequential to nonsequential double ionization (NSDI) as the laser intensity increases. For NSDI, the two-electron correlated momentum distribution exhibits a strong final-state Coulomb repulsion effect for high-energy photoelectrons, but absent for low-energy photoelectrons. This repulsion effect is ascribed to field double ionization from doubly-excited states populated by recollision of the first ionized electron when it returns to the parent ion. Such recollision-induced excited states are absent at ultraviolet wavelengths due to the very low returning kinetic energies, resulting to the absence of final-state repulsion effect in NSDI.     

Very high coercivities of top-layer diffusion Au/FePt thin films

The Au/FePt samples were prepared by depositing a gold cap layer at room temperature onto a fully ordered FePt layer, followed by an annealing at 800 °C for the purpose of interlayer diffusion. After the deposition of the gold layer and the high-temperature annealing, the gold atoms do not dissolve into the FePt Ll₀ lattice. Compared with the continuous FePt film, the TEM photos of the bilayer Au(60 nm)/FePt(60 nm) show a granular structure with FePt particles embedded in Au matrix. The coercivity of Au(60 nm)/FePt(60 nm) sample is 23.5 kOe, which is 85% larger than that of the FePt film without Au top layer. The enhancement in coercivity can be attributed to the formation of isolated structure of FePt ordered phase.     

Consensus problems of first-order dynamic multi-agent systems with multiple time delays

Consensus problems of first-order multi-agent systems with multiple time delays are investigated in this paper. We discuss three cases: 1) continuous, 2) discrete, and 3) a continuous system with a proportional plus derivative controller. In each case, the system contains simultaneous communication and input time delays. Supposing a dynamic multi-agent system with directed topology that contains a globally reachable node, the sufficient convergence condition of the system is discussed with respect to each of the three cases based on the generalized Nyquist criterion and the frequency-domain analysis approach, yielding conclusions that are either less conservative than or agree with previously published results. We know that the convergence condition of the system depends mainly on each agent’s input time delay and the adjacent weights but is independent of the communication delay between agents, whether the system is continuous or discrete. Finally, simulation examples are given to verify the theoretical analysis.     

一种全光开关及任意比能量输出光分束器的设计

基于光子晶体非线性Kerr效应设计了一种结构简单的任意比能量输出光分束器, 通过控制抽运光的强度来控制端口能量输出比. 该结构还可以实现控制光传输的动态开关作用, 并且具有插入损耗低、无串扰、信号光的开/关两个状态下的透射率相差非常大的特点, 因此该光开关具有很高的开关比. 关键词： 全光开关 光分束器 非线性Kerr效应 光子晶体     

Seed-mediated synthesis of acanthosphere-like gold microstructures with tunable LSPR in the NIR region using gemini surfactants as directing agents for SERS applications

Acanthosphere-like gold microstructures (AGMs) were synthesized using a facile, two-step, seed-mediated method and butanediyl-1,4-bis(dimethylhexadecylammonium bromide) (16-4-16) as a structure-directing agent. The morphologies and sizes of the products were controlled during the synthesis process by adjusting the concentrations of 16-4-16, the AgNO₃ feed, HAuCl₄, ascorbic acid, the amount of Ag seeds and the types of gemini surfactants used through systematic inquiry; particle sizes ranging from 130 to 800 nm were well prepared. Correspondingly, the morphology of the products changed between regular and irregular AGMs, and the products presented a number of new morphologies, such as open-mouthed submicrostructures and ribbon nanowires. In particular, with the increase in the 16-4-16 concentration, the structural morphology of the thorns clearly changed from a tip to a lamellar structure. A UV-vis spectroscopic analysis indicated that the localized surface plasmon resonance (LSPR) peak of the AGMs could be adjusted by changing the above factors, which extended from 500 to 1350 nm in the near-infrared (NIR) region, enabling a tremendous potential for using the AGMs as platforms for various biomedical applications. Based on the intermediate products, we propose a two-stage growth mechanism for the AGMs in which their solid cores and tips are generated successively. Surface-enhanced Raman scattering (SERS) measurements indicate that the AGMs can serve as sensitive SERS substrates; a SERS detection limit of 5 × 10^?7 M is presented for rhodamine B molecules.

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Graphical abstract

     

Plankton growth dynamic driven by plankton body size in deterministic and stochastic environments

In this paper, we establish a new phytoplankton–zooplankton model by considering the effects of plankton body size and stochastic environmental fluctuations. Mathematical theory work mainly gives the existence of boundary and positive equilibria and shows their local as well as global stability in the deterministic model. Additionally, we explore the dynamics of V-geometric ergodicity, stochastic ultimate boundedness, stochastic permanence, persistence in the mean, stochastic extinction, and the existence of a unique ergodic stationary distribution in the corresponding stochastic version. Numerical simulation work mainly reveals that plankton body size can generate great influences on the interactions between phytoplankton and zooplankton, which in turn proves the effectiveness of mathematical theory analysis. It is worth emphasizing that for the small value of phytoplankton cell size, the increase of zooplankton body size can not change the phytoplankton density or zooplankton density; for the middle value of phytoplankton cell size, the increase of zooplankton body size can decrease zooplankton density or phytoplankton density; for the large value of phytoplankton cell size, the increase of zooplankton body size can increase zooplankton density but decrease phytoplankton density. Besides, it should be noted that the increase of zooplankton body size cannot affect the effect of random environmental disturbance, while the increase of phytoplankton cell size can weaken its effect. There results may enrich the dynamics of phytoplankton-zooplankton models.     

Main Components of Xinjiang Lavender Essential Oil Determined by Partial Least Squares and Near Infrared SpectroscopySCIEI北大核心CSCD

This work was undertaken to establish a quantitative analysis model which can rapid determinate the content of linalool, linalyl acetate of Xinjiang lavender essential oil. Totally 165 lavender essential oil samples were measured by using near infrared absorption spectrum(NIR), after analyzing the near infrared spectral absorption peaks of all samples, lavender essential oil have abundant chemical information and the interference of random noise may be relatively low on the spectral intervals of 7100-4 500 cm(-1). Thus, the PLS models was constructed by using this interval for further analysis. 8 abnormal samples were eliminated. Through the clustering method, 157 lavender essential oil samples were divided into 105 calibration set samples and 52 validation set samples. Gas chromatography mass spectrometry (GC-MS) was used as a tool to determine the content of linalool and linalyl acetate in lavender essential oil. Then the matrix was established with the GC-MS raw data of two compounds in combination with the original NIR data. In order to optimize the model, different pretreatment methods were used to preprocess the raw NIR spectral to contrast the spectral filtering effect, after analysizing the quantitative model results of linalool and linalyl acetate, the root mean square error prediction(RMSEP) of orthogonal signal transformation (OSC) was 0.226, 0.558, spectrally, it was the optimum pretreatment method. In addition, forward interval partial least squares (FiPLS) method was used to exclude the wavelength points which has nothing to do with determination composition or present nonlinear correlation, finally 8 spectral intervals totally 160 wavelength points were obtained as the dataset. Combining the data sets which have optimized by OSC-FiPLS with partial least squares(PLS) to establish a rapid quantitative analysis model for determining the content of linalool and linalyl acetate in Xinjiang lavender essential oil, numbers of hidden variables of two components were 8 in the model. The performance of the model was evaluated according to root mean square error of cross-validation (RMSECV) 9 root mean square error of prediction (RMSEP). In the model, RESECV of linalool and linalyl acetate were 0.170 and 0.416, respectively; RMSEP were 0.188 and 0.364. The results indicated that raw data was pretreated by OSC and FiPLS, the NIR-PLS quantitative analysis model with good robustness, high measurement precision; it could quickly determine the content of linalool and linalyl acetate in lavender essential oil. In addition, the model has a favorable prediction ability. The study also provide a new effective method which could rapid quantitative analysis the major components of Xinjiang lavender essential oil.