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31.
On Structured Surfaces with Defects: Geometry,Strain Incompatibility,Stress Field,and Natural Shapes
In this paper we study the stress and deformation fields generated by nonlinear inclusions with finite eigenstrains in anisotropic solids. In particular, we consider finite eigenstrains in transversely isotropic spherical balls and orthotropic cylindrical bars made of both compressible and incompressible solids. We show that the stress field in a spherical inclusion with uniform pure dilatational eigenstrain in a spherical ball made of an incompressible transversely isotropic solid such that the material preferred direction is radial at any point is uniform and hydrostatic. Similarly, the stress in a cylindrical inclusion contained in an incompressible orthotropic cylindrical bar is uniform hydrostatic if the radial and circumferential eigenstrains are equal and the axial stretch is equal to a value determined by the axial eigenstrain. We also prove that for a compressible isotropic spherical ball and a cylindrical bar containing a spherical and a cylindrical inclusion, respectively, with uniform eigenstrains the stress in the inclusion is uniform (and hydrostatic for the spherical inclusion) if the radial and circumferential eigenstrains are equal. For compressible transversely isotropic and orthotropic solids, we show that the stress field in an inclusion with uniform eigenstrain is not uniform, in general. Nevertheless, in some special cases the material can be designed in order to maintain a uniform stress field in the inclusion. As particular examples to investigate such special cases, we consider compressible Mooney-Rivlin and Blatz-Ko reinforced models and find analytical expressions for the stress field in the inclusion. 相似文献
32.
Blends prepared by melt mixing of thermoplastic elastomer have gained considerable attention in recent years from a heat shrinkability point of view. Our present study deals with the measurement of heat shrinkability of the maleic anhydride grafted low‐density polyethylene and ethylene acrylic elastomer. Two samples have been prepared to study the effect of coupling agent's reactivity on the shrinkability of the blends. The coupling agents used are 4,4′‐diamino diphenyl sulphone, and 4,4′‐diamino diphenyl methane. Shrinkability was measured at room temperature, 120 °C, 150 °C, and 180 °C. Shrinkability is found to be greater in high temperature stretched sample rather than that of room temperature stretched sample. It is observed that reactivity as well as heat shrinkability is more when 4,4′‐diamino diphenyl methane is used as a coupling agent. The mechanism of interchain crosslinking reaction has been confirmed by IR spectroscopy. Differential scanning calorimetry was performed to study the thermal stability of the sample. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
33.
Benzo[a]pyrene is a carcinogen often present in diesel. For pervaporative removal of benzo[a]pyrene from n-tetradecane, representing a model diesel composition, both conventional as well as statistically designed experimental methods have been carried out. The effect of membrane composition, thickness, the effect of membrane pretreatment time and operating temperature on pervaporative separation have been investigated by response surface methodology, RSM for efficient permeation of target compound. The suitable membrane has been further used to study the effect of different physico-chemical parameters on permeation conventionally. RSM has also been applied to optimize the operational conditions of pervaporation process to maximize the response, i.e., the pervaporation separation index. With the design of experiments, the quadratic response surface models have been developed to link the response with input variables via mathematical relationships. The maximum value of Pervaporation Separation Index obtained is 1.9654 kg m?2 h?1. The optimized process condition’s run time is 10.79 h, the feed PAH concentration is 166.34 ppm with a permeate side pressure of 0.73 mmHg and an operating temperature of 451.25 K. 相似文献
34.
T. Banerjee S. Chaudhuri M. Moore S. Ray P.S. Chatterjee P. Roychowdhury 《Journal of chemical crystallography》1999,29(12):1281-1286
Both 5-amino-1-(2-hydroxyethyl)imidazole-4-carboxamide (AHIC) and 5-amino-1-(2-chloroethyl)-4-cyanoimidazole (ACCI) have been synthesized and crystallized in the monoclinic space group P21/c, Z = 4, with a = 8.420(2), b = 9.759(2), c = 10.583(2) Å, = 111.80(2)° for AHIC and a = 6.139(1), b = 8.522(2), c = 15.156(3) Å, = 96.71(2)° for ACCI. Differences in the molecular geometries of the two compounds are attributed to the differences in the substituents at the 1- and 4-positions of the imidazole ring. The molecular conformation of AHIC is stabilized by intramolecular hydrogen bonding between the 5-amino and the vicinal carboxamide moiety, resulting in an extended planar structural pattern. The presence of the cyano group in the 4-position of ACCI prevents the formation of such an intramolecular hydrogen bond. Both the crystal structures are stabilized by networks of intermolecular hydrogen bonds. 相似文献
35.
Kishore Kumar Hotha Swapan Roychowdhury Ramesh Mullangi L. K. Ravindranath 《Biomedical chromatography : BMC》2013,27(9):1192-1199
A rapid, simple, specific and sensitive LC‐MS/MS method has been developed and validated for the enantiomeric quantification of amlodipine (AML) isomers [R‐amlodipine (R‐AML) and S‐amlodipine (S‐AML)] with 200 μL of human plasma using R‐AML‐d4 and S‐AML‐d4 as corresponding internal standards as per regulatory guidelines. A simple liquid–liquid extraction process was used to extract these analytes from human plasma. The total run time was 3.5 min and the elution of R‐AML, S‐AML, R‐AML‐d4 and S‐AML‐d4 occurred at 1.62, 2.51, 1.63 and 2.53 min, respectively. This was achieved with a mobile phase consisting of 0.2% ammonia–acetonitrile (20:80, v/v) at a flow rate of 1 mL/min on a Chiralcel OJ RH column. A linear response function was established for the range of concentrations 0.1–10 ng/mL (r >0.998) for each enantiomer. The intra‐ and inter‐day precision values for both enantiomers met the acceptance criteria. Both enantiomers were stable in a set of stability studies, viz. bench‐top, auto‐sampler, freeze–thaw cycles and long‐term. The current assay was successfully applied to a pharmacokinetic study to quantitate AML enantiomers following oral administration of 10 mg AML tablet to humans. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
36.
A new type of outer synchronization between two distinct networks, composed of different classes of oscillators is investigated with the help of open plus closed loop approach, proposed earlier by Jackson and Grosu. It is further assumed that all the members of the network differ in their parameter values. Asymptotic stability of the zero solution of the error equation is proved analytically. Numerical simulation reveals that the same type of members of the two networks gets synchronized. 相似文献
37.
With the help of the general theory of the Heun equation, this paper completes previous work by the authors and other groups
on the explicit representation of the massive gravitino propagator in four-dimensional de Sitter space. As a result of our
original contribution, all weight functions which multiply the geometric invariants in the gravitino propagator are expressed
through Heun functions, and the resulting plots are displayed and discussed after resorting to a suitable truncation in the
series expansion of the Heun function. It turns out that there exist two ranges of values of the independent variable in which
the weight functions can be divided into dominant and sub-dominant families. 相似文献
38.
Pradip K. Gadekar Maryann Hoermann Faith Corbo Rajiv Sharma S. Sarveswari Abhijit Roychowdhury 《Tetrahedron letters》2014
Herein, we have developed a mild and selective reductive deprotection method for the MAc protected alcohols using sodium borohydride. The new deprotection conditions provide a complete orthogonality between O-MAc and other protecting groups such as tert-butyl ester, N-Boc, Fmoc, Cbz, O-TBDMS, N-benzyl, O-benzyl, O-acetyl, N-acetyl, N-MAc, etc. In addition to O-MAc deprotection, this method is also applicable for S-MAc deprotection. 相似文献
39.
Debattam Sarkar Dr. Tanmoy Ghosh Dr. Ananya Banik Dr. Subhajit Roychowdhury Prof. Dirtha Sanyal Prof. Kanishka Biswas 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(27):11208-11215
A two-step optimization strategy is used to improve the thermoelectric performance of SnTe via modulating the electronic structure and phonon transport. The electrical transport of self-compensated SnTe (that is, Sn1.03Te) was first optimized by Ag doping, which resulted in an optimized carrier concentration. Subsequently, Mn doping in Sn1.03−xAgxTe resulted in highly converged valence bands, which improved the Seebeck coefficient. The energy gap between the light and heavy hole bands, i.e. ΔEv decreases to 0.10 eV in Sn0.83Ag0.03Mn0.17Te compared to the value of 0.35 eV in pristine SnTe. As a result, a high power factor of ca. 24.8 μW cm−1 K−2 at 816 K in Sn0.83Ag0.03Mn0.17Te was attained. The lattice thermal conductivity of Sn0.83Ag0.03Mn0.17Te reached to an ultralow value (ca. 0.3 W m−1 K−1) at 865 K, owing to the formation of Ag7Te4 nanoprecipitates in SnTe matrix. A high thermoelectric figure of merit (z T≈1.45 at 865 K) was obtained in Sn0.83Ag0.03Mn0.17Te. 相似文献
40.
Tuhin Roychowdhury Dhruv Shah Varun Jain Dhananjay I. Patel Berg Dodson William Skinner James N. Hilfiker Stacey J. Smith Matthew R. Linford 《Surface and interface analysis : SIA》2020,52(7):433-441
In this work, copper and tungsten were sputtered onto silicon wafers by direct current magnetron sputtering (DCMS) and high-power impulse magnetron sputtering (HiPIMS). The resulting films were characterized by energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), atomic force microscopy (AFM), spectroscopic ellipsometry (SE), and X-ray diffraction (XRD). By EDX and XPS, all the sputtered films showed only the expected metal peaks. By XPS, the surfaces sputtered by DCMS were richer in oxygen than those produced by HiPIMS. By AFM, the surfaces were quite smooth. The root mean square (RMS) roughness values are as follows: 0.83 nm (W, HiPIMS), 1.10 nm (W, DCMS), 0.85 nm (Cu, HiPIMS), and 1.78 nm (Cu, DCMS). By SEM, the HiPIMS films exhibited smaller grain sizes, which was confirmed by XRD. The crystallite sizes estimated by XRD are as follows: 4 nm (W, body-centered cubic, HiPIMS), 13 nm (W, body-centered cubic, DCMS), 7 nm (W, cubic, HiPIMS), 14 nm (W, cubic, DCMS), 25 nm (Cu, HiPIMS), and 35 nm (Cu, DCMS). By SE, the HiPIMS surfaces showed higher refractive indices, which suggested that they were denser and less oxidized than the DCMS surfaces. 相似文献