Kinetics of crystal growth of strontium tungstate from solutions in sodium tungstate melts by continuous cooling

The crystallisation kinetics of strontium tungstate from unstirred saturated solutions in sodium tungstate melts was studied by continuous cooling from initial crystallisation temperatures T₀ = 1000° to 800°C to room temperature at cooling rates R_T = 0.67° to 3.3°C min⁻¹. The main crystal growth was diffusion rate-controlled; the final crystal growth was rate-controlled by the development rate of excess solute concentration. The estimated diffusion rate constant (k_D) values increased with cooling rates and initial crystallisation temperatures. They are higher than the rate constants for diffusion-controlled growth of calcium tungstate from sodium tungstate melts, but very much smaller than those for strontium tungstate from lithium chloride melts.     

Dynamical parameters for dilute Mössbauer impurities

A simple theoretical analysis is presented for Mössbauer parameters and frequency moments of dilute⁵⁷Fe impurities in different metallic hosts. These parameters have been evaluated for a general harmonic solid using Green's function method. Our results suggest that the contribution due to force constant change term is significant for the mean square displacement whereas that due to mass disordering term is predominating in the evaluations of mean square velocity. The variation of frequency moments for the impurity with host Debye-temperatures modified by the host to impurity mass ratios are shown for a number of solids.     

The growth of crystalline vapor deposited carbon-60 thin films

Thin films (25-2500 Å) of C₆₀ molecules have been deposited on both (001) NaCl and mica substrates at varying temperatures by resistive evaporation. Both electron diffraction and high resolution microscopy have been used to assess the degree of crystallinity, the orientational ordering and the nature of the defects present in these face-centered-cubic films. For NaCl, optimum conditions yielded polycrystalline films with a tendency towards a 110 orientation, while for mica, extended single crystal films have been fabricated which exhibit a 111 direction normal to the film surface.     

Separation of Variables for a Lattice Integrable System and the Inverse Problem

We investigate the relation between the local variables of a discrete integrable lattice system and the corresponding separation variables, derived from the associated spectral curve. In particular, we have shown how the inverse transformation from the separation variables to the discrete lattice variables may be factorized as a sequence of canonical transformations.     

Observation of the exchange spring behavior in hard-soft-ferrite nanocomposite

Nanocomposite of hard (BaFe₁₂O₁₉) and soft ferrite (Ni_0.8Zn_0.2Fe₂O₄) are prepared by the mixing of the individual ferrite components at appropriate ratio and subsequent heat treatment. Initially the microstructure of the individual phases is controlled by suitable processing. We have observed the exchange spring behavior in the soft-hard ferrite composite for the first time by tailoring the particle size of the individual phases and by suitable thermal treatment of the composite. It is found that the exchange interaction dominates over the dipolar interaction for smaller particle sizes of the soft ferrite. The magnetization of the composite showed hysteresis loop that is characteristic of the exchange spring system. This gives experimental proof for some theoretical modeling as well as paves way for developing magnet with higher (BH)_max product based on ferrites.     

Bulk reaction modeling of ducts with and without mean flow

A general formulation for analysis of sound field in a uniform flow duct lined with bulk-reacting sound-absorbing material is presented here. Presented theoretical model predicts the rate of attenuation for symmetric as well as asymmetric modes in rectangular duct lined with loosely bound (bulk-reacting) sound-absorbing material, which allows acoustic propagation through the lining. The nature of attenuation in rectangular ducts lined on two and four sides with and without mean flow is discussed. Computed results are compared with published theoretical and experimental results. The presented model can be used as guidelines for the acoustic design of silencers, air-conditioning ducts, industrial fans, and other similar applications.     

Electron transport in sub-micron GaAs channels at 300 K

Transient velocity-field characteristics have been computed for GaAs channels having lengths of 0.1, 0.2, 0.5, 1, and 20 μm for electric fields between 1 and 50 kV/cm at 300 K. The results are compared with earlier calculations and the significant features of the computed results are discussed. It is found that the electron motion for all channel lengths and for all fields is significantly affected by collisions. The threshold field for negative differential mobility increases, and the magnitude of the differential mobility decreases with decrease in the length of the sample. The maximum steady-state velocity increases with decrease in the length and may be as high as 5.4×10⁷ cm/s for 0.1 μm samples.