全文获取类型
收费全文 | 511篇 |
免费 | 5篇 |
专业分类
化学 | 339篇 |
晶体学 | 9篇 |
力学 | 20篇 |
数学 | 61篇 |
物理学 | 87篇 |
出版年
2023年 | 3篇 |
2022年 | 11篇 |
2021年 | 3篇 |
2020年 | 2篇 |
2019年 | 5篇 |
2018年 | 4篇 |
2017年 | 3篇 |
2016年 | 12篇 |
2015年 | 10篇 |
2014年 | 14篇 |
2013年 | 42篇 |
2012年 | 28篇 |
2011年 | 38篇 |
2010年 | 13篇 |
2009年 | 19篇 |
2008年 | 24篇 |
2007年 | 36篇 |
2006年 | 36篇 |
2005年 | 33篇 |
2004年 | 32篇 |
2003年 | 18篇 |
2002年 | 15篇 |
2001年 | 7篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1998年 | 5篇 |
1997年 | 5篇 |
1996年 | 12篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 11篇 |
1991年 | 7篇 |
1990年 | 2篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1985年 | 3篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 5篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1966年 | 1篇 |
1959年 | 1篇 |
1958年 | 1篇 |
排序方式: 共有516条查询结果,搜索用时 0 毫秒
21.
Rishabh Kaundal Manish Kumar Subhash Kumar Dharam Singh Dinesh Kumar 《Molecules (Basel, Switzerland)》2022,27(12)
Background: Himalayan Viola species (Banksha) are traditionally important herbs with versatile therapeutic benefits such as antitussive, analgesic, antipyretic, antimalarial, anti-inflammatory, and anticancerous ones. The current investigation was focused on exploring polyphenolic profiles, antioxidant, and antimicrobial potentials of wild viola species at 15 gradient locations (375–1829 m). Methods: Morphological, physiochemical, and proximate analyses were carried out as per WHO guidelines for plant drug standardization. Total polyphenolic and flavonoid content were carried out using gallic acid and rutin equivalent. UPLC-DAD was used to profile the targeted polyphenols (gallic acid, vanillic acid, syringic acid, p-coumaric acid, ferulic acid, rutin, quercetin, luteolin, caffeic acid, and epicatechin). Similarly, all samples were screened for antioxidant and antimicrobial activity. Statistical analysis was used to correlate polyphenolic and targeted activities to assess Viola species adaptation behavior patterns. Results: Viola canescens (V. canescens) and Viola pilosa (V. pilosa) were found abundantly at their respective sites. Among flowers and leaves, flowers of V. canescens and V. pilosa showed higher total polyphenolic and flavonoid content (51.4 ± 1.13 mg GAE/g and 65.05 ± 0.85 mg RE/g, and 33.26 ± 0.62 mg GAE/g and 36.10 ± 1.41 mg RE/g, respectively). Furthermore, UPLC-DAD showed the uppermost content of p-coumaric acid in flowers and ferulic acid in leaves, while rutin was significant in both the tissues. Conclusions: The adaptive behavior of Viola species showed variability in morphological characters with the altitudes, while targeted polyphenols and activities were significant at mid-altitudes. This research helps in the selection of right chemotype for agrotechnological interventions and the development of nutraceutical products. 相似文献
22.
23.
24.
A simple and efficient method for the iodination of aromatic amines using pyridinium iodochloride (PyICl) in methanol as solvent is reported. Mild reaction conditions, short reaction time, and good to excellent yields of the product are the noteworthy advantages of the method. Pyridinium iodochloride is an efficient solid iodinating reagent and can be handled safely. 相似文献
25.
Allylic amines are synthesized in good to excellent yields by treatment of aziridine-2-alcohols with PPh3/I2/imidazole in THF as solvent under mild conditions. 相似文献
26.
Subhash C. Jain Pankaj Khanna Sunita Bhagat Manish Jain Rajeev Sakhuja 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8):1829-1839
The reaction of indol-2,3-diones ( 1a–i ) with 5-aminoindazole ( 2 ) has resulted in the formation of hitherto unknown 3-(indazol-5-yl)iminoindol-2-ones ( 3a–i ) in quantitative yields which, on 1,3-dipolar cyclocondensation with mercaptoacetic acid ( 4 ), has afforded a series of new spiro heterocycles, 3′-(indazol-5-yl) spiro[3H, indol-3, 2′ -thiazolidine]-2,4′-diones* ( 5a–i ). 相似文献
27.
P. Lizák Subhash Chandra Mojumdar 《Journal of Thermal Analysis and Calorimetry》2013,112(2):1095-1100
Objective evaluation techniques were used in this study of thermal properties of textile fabric. The Alambeta, P tester, and Togmeter measure the passages of air which were used for evaluation of the physiological properties. Fibrous materials were prepared in the form of textile knitting fabric COOLMAX. It is clear from the measurement that there are considerable differences in the results of measurement with described methods. Device Alambeta is convenient for the measurement and evaluation of various thermal properties. Finally, it can be concluded that this field of measurements is developing and will be the subject of further research of other methods, more suitable for measurement of the various characteristics. 相似文献
28.
Vinyl sulphides find a substantial application in organic synthesis.2 The synthetic utility of heter cyclic vinyl sulphides due to the ease in extension of heterocyclic ring3 should be more versatile, Here, we report the synthesis of isoquinolinyl vinyl sulphides from dihydrothiazolo [2, 3-a] isoquinolinium cations, depicting another use of heterocycles in organic synthesis.4 相似文献
29.
Total synthesis of (Z) pulchellalactam, a CD protein tyrosine phosphatase inhibitor, from commercially available methallyl chloride employing ring‐closure metathesis (RCM) as a key step is described. 相似文献
30.
Zahra Afrasiabi Rosana Almudhafar Di Xiao Ekkehard Sinn Amitava Choudhury Aamir Ahmad Alok Vyas Fazlul Sarkar Subhash Padhye 《Transition Metal Chemistry》2013,38(6):665-673
A planar, polycyclic and aromatic hydrocarbon ligand, namely 9,10-phenanthrenequinone semicarbazone, and its transition metal complexes have been synthesized and structurally characterized. The in vitro antiproliferative activity of these compounds against five human cancer cell lines revealed that they were effective against androgen receptor-positive/negative prostate cancer cells as well as COX-positive pancreatic BxPC-3 cancer cell line. The driving force behind such antiproliferative activity seems to be the up-regulated COX expression in these cells, which was amenable for targeting through metal complexation. These structural motifs can, therefore, serve as a starting point for developing novel cytotoxic agents against the growing number of prostate and pancreatic cancers. 相似文献