Low-lying levels in103Rh from Coulomb excitation

Five low-lying negative parity states of¹⁰³Rh up to 1277 keV excitation energy were observed to be Coulomb excited with 2·5–4·5 MeV protons. The de-excitation gamma rays from these levels were identified in the singles spectra recorded with a 57 cc Ge(Li) detector. The level energies, branching ratios, reduced transition probabilitiesB(E2) and the multipole mixing ratios () were obtained. The 880, 1106 and 1277 keV levels have been Coulomb excited with protons for the first time. The ambiguity in theJ values for 803 and 1106 keV levels have been resolved using ²-fits, the assigned spin values are 1/2^– and 5/2^–, respectively. The-values for 474·1 and 811·2 keV transitions were obtained for the first time. The results have been discussed in the light of previously reported results.The authors wish to thank Professor I. M. Govil for his active interest at various stages of this work. One of us (DCT) acknowledges the financial support from U.G.C., New Delhi, under Faculty Improvement Programme.     

Background levels of uranium in human urine

The literature on the normal content of uranium in urine is reviewed. The reported normal concentration has declined several orders of magnitude over the years, probably due to improvements in analytical technique rather than a real change. The lowest mean values were reported with spectrometry (mean of 23 ng/l in 12 subjects) and thermal ion mass spectrometry (3.4 ng/l in 1 subject). Even spectrometry is not sufficiently sensitive at normal levels, so that techniques such as fission track analysis or mass spectrometry must be used to obtain results above the detection limit of the technique for individual samples.     

Thiosalicylic acid-immobilized Amberlite XAD-2: metal sorption behaviour and applications in estimation of metal ions by flame atomic absorption spectrometry

Thiosalicylic acid (TSA)-modified Amberlite XAD-2 (AXAD-2) was synthesized by coupling TSA with the support matrix AXAD-2 through an azo spacer. The resulting chelating resin was characterized by elemental analyses, thermogravimetric analysis (TGA) and infrared spectra. The newly designed resin quantitatively sorbs CdII, CoII, CuII, FeIII, NiII and ZnII at pH 3.5-7.0 when the flow rate is maintained between 2 and 4 ml min-1. The HCl or HNO3 (2 mol l-1) instantaneously elutes all the metal ions. The sorption capacity is 197.5, 106.9, 214.0, 66.2, 309.9 and 47.4 mumol g-1 of the resin for cadmium, cobalt, copper, iron, nickel and zinc, respectively, whereas their preconcentration factor is between 180-400. The breakthrough volume of HCl or HNO3 for elution of these metal ions was found to be 4-8 ml. The limit of detection (LOD) for CdII, CoII, CuII, FeIII, NiII and ZnII was 0.48, 0.20, 4.05, 0.98, 1.28 and 3.94 micrograms l-1, respectively, and the limit of quantification (LOQ) was found to be 0.51, 0.29, 4.49, 1.43, 1.58 and 4.46 micrograms l-1, respectively. The loading half time, t1/2, for the cations was found to be less than 2.0 min, except for nickel for which the value was 13.1 min. The determination of each of these six cations is possible in the presence of other five, if their concentration is up to 4 times. All six metals were determined in river water (RSD approximately 0.7-7.7%) and tap water samples (RSD approximately 0.3-5.7%). The estimation of Co was made in the samples of multivitamin tablets (RSD < 2.3%). The results agree with those quoted by manufacturers.     

Studies on chromium(III) complexes of some new dithiocarbamato ligands

Summary Tris-chelates of chromium(III) have been synthesised with five new dithiocarbamates, [RR'NCS₂]^–, where R=PhCH₂ and R/t'=H, PhCH₂, Me, Et and i-Pr. Magnetic moments together with electronic, i.r. and e.s.r spectra of the complexes have been described. Various ligand-field parameters have been evaluated and discussed.     

Investigating the interface of superhydrophobic surfaces in contact with water

Neutron reflectivity (NR) is used to probe the solid, liquid, vapor interface of a porous superhydrophobic (SH) surface submerged in water. A low-temperature, low-pressure technique was used to prepare a rough, highly porous organosilica aerogel-like film. UV/ozone treatments were used to control the surface coverage of hydrophobic organic ligands on the silica framework, allowing the contact angle with water to be continuously varied over the range of 160 degrees (superhydrophobic) to <10 degrees (hydrophilic). NR shows that the superhydrophobic nature of the surface prevents infiltration of water into the porous film. Atomic force microscopy and density functional theory simulations are used in combination to interpret the NR results and help establish the location, width, and nature of the SH film-water interface.     

Structural changes by sulfoxidation of phenothiazine drugs

Summary The side-chain conformations of psychoactive phenothiazine drugs in crystals are different from those of biologically inactive ring sulfoxide metabolites. This study examines the potential energies, molecular conformations and electrostatic potentials in chlorpromazine, levomepromazine (methotrimeprazine), their sulfoxide metabolites and methoxypromazine. The purpose of the study was to examine the significance of the different crystal conformations of active and inactive phenothiazine derivatives, and to determine why phenothiazine drugs lose most of their biological activity by sulfoxidation. Quantum mechanics and molecular mechanics calculations demonstrated that conformations with the side chain folded over the ring structure had lowest potential energy in vacuo, both in the drugs and in the sulfoxide metabolites. In the sulfoxides, side chain conformations corresponding to the crystal structure of chlorpromazine sulfoxide were characterized by stronger negative electrostatic potentials around the ring system than in the parent drugs. This may weaken the electrostatic interaction of sulfoxide metabolites with negatively charged domains in dopamine receptors, and cause the sulfoxides to be virtually inactive in dopamine receptor binding and related pharmacological tests.     

Tributyltin hydride-mediated straightforward synthesis of a new isoxazolo-benzazulene ring system

Tributyltin hydride-mediated straightforward synthesis of a new isoxazolo-benzazulene system from the derivatives afforded by the Baylis-Hillman reaction of 3-(2-bromophenyl)-4-isoxazolecarbaldehydes is described.