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151.
Summary The formation of ternary complexes of the MAL3– type [where M = CuII, NiII and ZnII ; A = nitrilotriacetic acid (NTA); L = 1-hydroxy-2-naphthoic acid (1,2 HNA) and 2-hydroxy-1-naphthoic acid (2,1 HNA)] have been studied potentiometrically in 50% v/v aqueous — ethanol (25° and µ = 0.1). Under identical conditions the binary complexes of the 1,2- and 2,1-HNA ligands have also been examined. The values of mixed ligand formation constants KMAL have been found to be lower than KML (first step formation constant of binary complexes) and even less than
(second step formation constant of binary complexes). 相似文献
152.
Kalyan Kali Sen Gupta Saroj Chandra Kumar Pratik Kumar Sen Amalendu Banerjee 《Reaction Kinetics and Catalysis Letters》1988,36(2):423-428
The kinetics of oxidation of methanol by bromate ion in hydrochloric acid medium has been investigated. A mechanism consistent with the experimental observations is suggested.
. , .相似文献
153.
Suresh Chandra Rastogi 《Journal of separation science》1995,18(10):653-658
A gas chromatographic (GC)-mass spectrometric (GC-MS) method has been developed for the routine analysis of 11 fragrance substances in cosmetics: cinnamic alcohol, cinnamic aldehyde, eugenol, hydroxy citronellal, α-amyl cinnamic aldehyde, geraniol, isoeugenol, coumarin, dihydrocoumarin, citronellal and citral. Methods for sample preparation of various types of cosmetic products, prior to GC analysis, have also been developed and proved to be rugged. Detection limits of all of target fragrance substances were approximately 1 ppm. Calibration curves of the target fragrance substances analyzed by GC were found to be linear in the investigated concentration range, 0.005% – 0.50%. The recoveries of the target fragrances from various types of cosmetic products were 80% – 116% and the relative standard deviations of the quantitative analysis of the target fragrance substances were within 5%. 相似文献
154.
A vesicle-forming chiral cationic surfactant (1R,2S)-(-)-N-dodecyl-N-methyl-ephedrinium bromide was evaluated as a pseudo-stationary phase in micellar electrokinetic chromatography (MEKC) for enantioseparation of eight non-steroidal anti-inflammatory drugs e.g., carprofen, flurbiprofen, fenoprofen, ibuprofen, indoprofen, ketoprofen, naproxen and suprofen by capillary electrophoresis. The effects of varying experimental conditions such as pH and concentration of surfactant in the running buffer on the enantiomer separation of the drugs are reported. A mixture of five of the above drugs was separated and each enantiomeric pair was also separated simultaneously in a single run by use of the surfactant. The strong electrostatic interactions between the analytes and the vesicles seemed to have a major role in the enantiomeric separation of the profens. 相似文献
155.
[reaction: see text] N-Aromatic secondary amides can be transformed into O-aromatic esters in high yield via N-nitrosamide intermediates. The amides can be generated in situ from the corresponding aromatic amines or nitro compounds, and phenols can easily be made from the esters. The reaction can be modified by addition of methyl methacrylate or toluene at 0 degrees C to give polymerization or deamination, respectively. The rearrangement mechanism may involve radical formation and recombination. 相似文献
156.
J.Michael Birchall Roy Fields Robert N. Haszeldine Reginald J. McLean 《Journal of fluorine chemistry》1980,15(6):487-495
Thermolysis of hexafluorocyclopropane in the presence of ethylene, propene, vinyl chloride, and vinyl bromide gives good yields of the corresponding 1,1-difluorocyclopropanes, formed by addition of difluorocarbene to the olefin. The tetrafluoroethylene formed dimerises to octafluorocyclobutane, co-dimerises with the olefin, or survives, depending on the reaction conditions. With allene, hexafluorocyclopropane gives 1-(difluoromethylene)cyclopropane, 2,2,3,3-tetrafluorospiropentane, and products derived from tetrafluoroethylene and allene. 相似文献
157.
This article describes an integrated process for simultaneous purification of lysozyme, ovalbumin, and ovomucoid from hen egg white. The crude egg white extract was passed through a cation exchanger Streamline trade mark SP and the bound lysozyme was eluted with 5% ammonium carbonate, pH 9.0, containing 1 M NaCl after elution of avidin. This partially purified lysozyme was further purified 639-fold on dye-linked cellulose beads. Ovalbumin and ovomucoid did not bind to Streamline SP. Ovalbumin could be precipitated from this unbound fraction by 5% trichloroacetic acid, and ovomucoid was removed from the supernatant by precipitation with ethanol. The yields of lysozyme, ovomucoid, and ovalbumin were 77, 94, and 98%, respectively. All the purified proteins showed single bands on sodium dodecyl sulfate polyacrylamide gel electrophoresis. All the steps are easily scalable, and the process described here can be used for large-scale simultaneous purification of these proteins in the pure form. 相似文献
158.
A density-functional theory is presented to study the structure of polymers, having attractive interactions, confined between attractive surfaces. The theory treats the ideal-gas free-energy functional exactly and uses weighted density approximation for the hard-chain contribution to the excess free-energy functional. The bulk interactions of freely jointed hard spheres are obtained from generalized Flory equation of state and the attractive interactions are calculated using the direct correlation function obtained from the polymer reference interaction site model theory along with the mean spherical approximation closure. The theoretical predictions are found to be in quite good agreement with the Monte Carlo simulation results for varying densities, chain lengths, and different interaction potentials. The results confirm important implications of using different approximations for the hard-sphere and attractive interactions. 相似文献
159.
A new chelating resin was synthesised by the modification of styrene-divinylbenzene (2%) copolymer and incorporation of dithiocarbamate groups. The polydithiocarbamate resin was characterised by elemental analysis, thermal studies and IR studies. The analytical characteristics of the sorbent were established and optimum sorption conditions for Cu, Ni, Pb, Fe, As and Mn determined. The total sorption capacity of the resin was 37 mg g−1 for Ni(II), 35 mg g−1 for Cu(II), 29 mg g−1 for Fe(III) and 23 mg g−1 for Pb(II). The optimum pH for the removal of metal ions was 3-5 for Ni(II), 5 for Cu(II), 4 for Fe(III) and 4-5 for Pb(II). High sorption capacity was observed when compared with other conventional chelating polymers. The sorption kinetics was fairly rapid, as apparent from the loading half time t1/2 values, indicating a better accessibility of the chelating sites. 相似文献
160.
Ellen Herlihy Peter H. Gies Colin R. Roy Michael Jones 《Photochemistry and photobiology》1994,60(3):288-294
Abstract Quantifying individual exposure to ultraviolet radiation (UVR) is critical to understanding the etiology of a number of diseases including nonmelanotic and melanotic skin cancers. Measurements of personal exposure to solar UVR were made in Hobart, Tasmania in February (summer) 1991 for six different outdoor activities using UVR-sensitive polysulfone (PS) film attached at seven anatomical sites. Concurrent behavioral and environmental observations were also made. To date many studies have relied on subject recall to quantify past solar UVR exposures. To gain insight into the accuracy of subject recall the measured UVR exposures received by different subjects using the PS film were compared to those calculated from personal diaries and ambient solar UVB levels from a monitoring station. In general, when UVR exposure activities took place under close supervision, good correlations were obtained between the PS badges and the ambient measurements/diaries approach. Ultraviolet radiation exposures for the field study involving 94 subjects engaged in a number of outdoor activities are presented. 相似文献