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61.
Margarita A. Deneva Pepa I. Uzunova Marin N. Nenchev 《Optical and Quantum Electronics》2007,39(3):193-212
We report (theory, experimental check) an improved approach for generation of a tunable, subnanosecond pulse (0.1–0.4 ns),
based on a single pulsation (“spike”) separation from the transient oscillations in a dye laser with active mirror (AMIR).
A pumping by 20–50 ns pulses from Q-switched Nd:YAG laser is considered. The separation is in original, two-spectral selective
channels cavity, where the forced by AMIR quenched generation at one of the wavelength stops initially started spiking generation
at the other wavelength after the first spike development. The AMIR quickly starts the quenching generation at a precisely
controlled moment and with necessary intensity thus assuring the desired separation. An advantage is a high reproducibility
of the separation for high (~250%) pump power fluctuations combined with tuning in large range (~20 nm). To obtain such an
operation we form ~1 ns leading front pump pulse by electrooptical temporal cutting of the input pump pulse and use an optical
delay line. This increases also a few times the power in the separated spike (to be ~100 kW). Our approach widens the combinations
of lasers for effective applications of spike separation technique (dye lasers excited by Q-switched solid-state or Cu-vapor
lasers). 相似文献
62.
John C. Graham Xinmin Xu Lonnie Jones Margarita Orticochea 《Journal of polymer science. Part A, Polymer chemistry》1990,28(5):1179-1183
The reaction of bis(ethyl-3-oxo-butanolato-O1,O3)-bis(2-propanolato)titanium(Tyzor DCR and 2-isocyanatoethyl methacrylate (IEM) in refluxing hexane produced a mixture of trimer and polymers of 2-isocyanatoethyl methacrylate which varied considerably from 23 to 92% polymer as the molar ratio of bis(ethyl-3-oxo-butanolato-O1,O3)-bis(2-propanolato)titanium(Tyzor DCR) to 2-isocyanatoethyl methacrylate (IEM) varied from 1:4 to 1:32. The IEM 1-nylon polymer which was soluble in cresol and phenol was characterized by FTIR, 1H-NMR, and 13C-NMR. This analysis also showed that the methacrylate carbon–carbon double bond survived our reaction conditions intact. Based on atomic absorption determination of titanium, the molecular weight of the polymer ranged between 3000 and 4000 g/mol. Thermal gravimetric analysis (TGA) showed the polymer to be stable in air to approximately 250°C. 相似文献
63.
64.
Vapor–liquid equilibria (VLE) data at 100 kPa have been determinated for the ternary system cyclohexane + cyclohexene + morpholine and two constituent binary systems cyclohexane + morpholine and cyclohexene + morpholine. The thermodynamic consistency of experimental data has been verified. Both binary systems deviate moderately from ideality without the presence of an azeotrope. The VLE data have been well correlated using local composition models (Wilson, NRTL and UNIQUAC) and have been also predicted with the original UNIFAC. 相似文献
65.
Dimethylgermylene and its Ge=Ge doubly bonded dimer, tetramethyldigermene, have been characterized directly in solution by
308-nm laser flash photolysis in n-hexane solution, as well as 254-nm photolysis in hydrocarbon glasses at t = 77 K. An absorption band maximum of λ
max ≈ 430 nm and molar absorption coefficient of ε ≈ 2,700 M−1 cm−1 have been shown to be attributable to low-temperature glasses, while the absorption band maximum of λ
max ≈ 480 nm and molar absorption coefficient of ε ≈ 2,400 M−1 cm−1 have been shown to be related to dimethylgermylene in n-hexane solution. The molar absorption coefficient of tetramethyldigermene (λ
max ≈ 380 nm) was determined to be ε ≈ 84,000 M−1 cm−1. The germylene is formed via (formal) cheletropic photocycloreversion of 7,7′-dimethylgerma-1,4,5,6-tetraphenyl-2,3-benzo-norbornadiene.
Tetramethyldigermene and 1,2,3,4-tetraphenylnaphthalene in the triplet state were formed, together with dimethylgermylene.
We attempted to explain the various contradictory interpretations of experimental data existing in the literature on this
reaction. 相似文献
66.
Differential Alternative Pulses Voltammetry (DAPV), introduced by the authors earlier, was applied with HMDE for direct As(III) determination in the presence of Pb(II) in natural water without sample pretreatment. Distinguishable peaks of As(III) and Pb(II) were registered in 1 M HCl supporting electrolyte at a concentration ratio as high as 1 : 6, while complete peak overlapping occurs applying DPP at any concentration ratio at the same experimental conditions. In‐situ As(III) determinations in the presence of Pb(II) in contaminated ground waters in Mexico were performed, using especially designed disposable safe mercury drop electrodes. 相似文献
67.
Carlos Rodríguez-Abreu Margarita Sanchez-Domínguez Bojan Šarac Marija Bešter Rogač Rekha Goswami Shrestha Lok Kumar Shrestha Dharmesh Varade Goutam Ghosh Vinod K. Aswal 《Colloid and polymer science》2010,288(8):923-935
Mixtures of a hydrophobic triblock copolymer (L121, PEO5PPO68PEO5) and a hydrophobic anionic surfactant (AOT, Sodium bis(2-ethylhexyl)sulfosuccinate), each alone forming turbid vesicular
solutions in water, aggregate to produce a thermodynamically stable, transparent and isotropic solution. Mixed AOT/L121 aggregates
could be confirmed by fluorescence, surface tension, differential scanning calorimetry (DSC) and isothermal titration calorimetry
(ITC). In an isotropic region, where mixed aggregates are formed, there is a synergistic interaction between monomers of AOT
and L121 in the mixture. In addition, Small Angle Neutron Scattering (SANS) experiments provided evidence that mixed aggregates
have the shape of either spheres (with a certain polydispersity) or very short ellipsoids (axial ratio below 2), confirming
a transition from giant multilamellar vesicles to small aggregates upon mixing the two hydrophobic amphiphiles. Upon dilution,
the morphology changes to disk-like. From an examination of the results of all the methods the peculiar behavior of the mixed
AOT/L121 system is explained. 相似文献
68.
Khachatryan V Sirunyan AM Tumasyan A Adam W Bergauer T Dragicevic M Erö J Fabjan C Friedl M Frühwirth R Ghete VM Hammer J Hänsel S Hartl C Hoch M Hörmann N Hrubec J Jeitler M Kasieczka G Kiesenhofer W Krammer M Liko D Mikulec I Pernicka M Rohringer H Schöfbeck R Strauss J Taurok A Teischinger F Wagner P Waltenberger W Walzel G Widl E Wulz CE Mossolov V Shumeiko N Suarez Gonzalez J Benucci L Cerny K De Wolf EA Janssen X Maes T Mucibello L Ochesanu S Roland B Rougny R Selvaggi M Van Haevermaet H 《Physical review letters》2011,106(11):112001
Measurements of the total and differential cross sections dσ/dp(T)(B) and dσ/dy(B) for B(+) mesons produced in pp collisions at sqrt[s]=7 TeV are presented. The data correspond to an integrated luminosity of 5.8 pb(-1) collected by the CMS experiment operating at the LHC. The exclusive decay B(+)→J/ψK(+), with J/ψ→μ(+)μ(-), is used to detect B(+) mesons and to measure the production cross section as a function of p(T)(B) and y(B). The total cross section for p(T)(B)>5 GeV and |y(B)|<2.4 is measured to be 28.1±2.4±2.0±3.1 μb, where the first uncertainty is statistical, the second is systematic, and the last is from the luminosity measurement. 相似文献
69.
Chatrchyan S Khachatryan V Sirunyan AM Tumasyan A Adam W Bergauer T Dragicevic M Erö J Fabjan C Friedl M Frühwirth R Ghete VM Hammer J Hänsel S Hoch M Hörmann N Hrubec J Jeitler M Kiesenhofer W Krammer M Liko D Mikulec I Pernicka M Rohringer H Schöfbeck R Strauss J Taurok A Teischinger F Wagner P Waltenberger W Walzel G Widl E Wulz CE Mossolov V Shumeiko N Suarez Gonzalez J Bansal S Benucci L De Wolf EA Janssen X Maes J Maes T Mucibello L Ochesanu S Roland B Rougny R Selvaggi M Van Haevermaet H 《Physical review letters》2011,107(9):091802
Electroweak production of the top quark is measured for the first time in pp collisions at √=7 TeV, using a data set collected with the CMS detector at the LHC and corresponding to an integrated luminosity of 36 pb?1. With an event selection optimized for t-channel production, two complementary analyses are performed. The first one exploits the special angular properties of the signal, together with background estimates from the data. The second approach uses a multivariate analysis technique to probe the compatibility with signal topology expected from electroweak top-quark production. The combined measurement of the cross section is 83.6±29.8(stat+syst)±3.3(lumi) pb, consistent with the standard model expectation. 相似文献
70.
Khachatryan V Sirunyan AM Tumasyan A Adam W Bergauer T Dragicevic M Erö J Fabjan C Friedl M Frühwirth R Ghete VM Hammer J Hänsel S Hartl C Hoch M Hörmann N Hrubec J Jeitler M Kasieczka G Kiesenhofer W Krammer M Liko D Mikulec I Pernicka M Rohringer H Schöfbeck R Strauss J Taurok A Teischinger F Waltenberger W Walzel G Widl E Wulz CE Mossolov V Shumeiko N Suarez Gonzalez J Benucci L Ceard L Cerny K De Wolf EA Janssen X Maes T Mucibello L Ochesanu S Roland B Rougny R Selvaggi M Van Haevermaet H 《Physical review letters》2011,106(1):011801
The results of the first search for long-lived gluinos produced in 7 TeV pp collisions at the CERN Large Hadron Collider are presented. The search looks for evidence of long-lived particles that stop in the CMS detector and decay in the quiescent periods between beam crossings. In a dataset with a peak instantaneous luminosity of 1×10(32) cm-2 s-1, an integrated luminosity of 10 pb-1, and a search interval corresponding to 62 hours of LHC operation, no significant excess above background was observed. Limits at the 95% confidence level on gluino pair production over 13 orders of magnitude of gluino lifetime are set. For a mass difference mg - mχ1(0) >100 GeV/c2, and assuming BR(g→gχ1(0))=100%, mg < 370 GeV/c2 are excluded for lifetimes from 10 μs to 1000 s. 相似文献