全文获取类型
收费全文 | 196篇 |
免费 | 1篇 |
专业分类
化学 | 128篇 |
晶体学 | 3篇 |
力学 | 3篇 |
数学 | 12篇 |
物理学 | 51篇 |
出版年
2023年 | 1篇 |
2022年 | 3篇 |
2021年 | 5篇 |
2020年 | 4篇 |
2019年 | 2篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 3篇 |
2015年 | 2篇 |
2014年 | 9篇 |
2013年 | 18篇 |
2012年 | 13篇 |
2011年 | 33篇 |
2010年 | 6篇 |
2009年 | 5篇 |
2008年 | 5篇 |
2007年 | 13篇 |
2006年 | 15篇 |
2005年 | 6篇 |
2004年 | 5篇 |
2003年 | 1篇 |
2002年 | 8篇 |
2001年 | 2篇 |
2000年 | 4篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1984年 | 1篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 1篇 |
排序方式: 共有197条查询结果,搜索用时 15 毫秒
61.
Extraction and high-performance liquid chromatographic (HPLC) procedures are described that permit the complete analysis of free and conjugated zeranol metabolites in plasma from pigs implanted with [3H]zeranol. Free metabolites (9.0%) are extracted and then analysed by radio-HPLC on a reversed phase C18 column. They are distributed between three compounds that have been identified by gas chromatography-mass spectrometry as taleranol, zeranol and zeralanone. Direct radio-HPLC of the pre-extracted, deproteinated and Sep-Pak C18-purified plasma on a reversed-phase C18 column using tetrabutylammonium as an ion-pairing agent showed four main peaks: one corresponds to a weakly retained unidentified compound(s) (20%) and the other three were identified as the taleranol, zeranol and zeralanone glucuro conjugates. However, the total recovery is only about 25% owing to strong affinity of this polar material for the plasma proteins. Enzymatic deconjugation of the pre-extracted plasma followed by radio-HPLC analysis of the freed metabolites led to a good recovery of the radioactivity (81.8%) and allowed the quantitation of the different metabolites. These preliminary results indicate that zeranol is metabolized in the pig following pathways similar to those in other tested species. 相似文献
62.
Recent studies have shown that semiempirical methods (e.g., PM3 and AM1) for zinc-containing compounds are unreliable for modeling structures containing zinc ions with ligand environments similar to those observed in zinc metalloenzymes. To correct these deficiencies a reparameterization of zinc at the PM3 level was undertaken. In this effort we included frequency corrected B3LYP/6-311G* zinc metalloenzyme ligand environments along with previously utilized experimental data. Average errors for the heats of formation have been reduced from 46.9 kcal/mol (PM3) to 14.2 kcal/mol for this new parameter set, termed ZnB for "Zinc, Biological." In addition, the new parameter sets predict geometries for the Bacillus fragilis active site model and other zinc metalloenzyme mimics that are qualitatively in agreement with high-level ab initio results, something existing parameter sets failed to do. 相似文献
63.
Challenges encountered in extending the sensitivity of US Environmental Protection Agency Method 314.0 for perchlorate in drinking water 总被引:1,自引:0,他引:1
Wagner HP Suarez FX Pepich BV Hautman DP Munch DJ 《Journal of chromatography. A》2004,1039(1-2):97-104
Concerns about the potential adverse health effects of perchlorate at concentrations below the minimum reporting level (MRL) of US Environmental Protection Agency (EPA) Method 314.0 (generally recognized as 4.0 microg/l) have led to an interest in increasing the sensitivity of the method. This work describes the use of 2 mm columns with a large-loop direct injection method, a column concentration technique and this concentration technique with a background reduction step, to increase the sensitivity for the analysis of trace levels of perchlorate in high ionic strength matrices. The concentrator columns studied were the Dionex TAC LP-1 and a new Dionex high capacity Cryptand concentrator column. The use of a surrogate to monitor trapping efficiency for the concentration technique and the use of confirmational columns to minimize the potential for false positives are also discussed. The large-loop direct injection method and the column concentration methods provided acceptable data when the samples were pre-treated with solid phase pretreatment cartridges. The background reduction technique did not provide acceptable data with either of the concentrator columns evaluated. 相似文献
64.
65.
66.
Francisco P.J. Valero Carlos B. Suarez 《Journal of Quantitative Spectroscopy & Radiative Transfer》1978,19(6):579-590
Absolute intensities, self-broadening coefficients, and foreign-gas broadening by Ar and N2 were measured at temperatures of 197, 233 and 294 K for the 3001II←0000 band of CO2 at 6348 cm-1. Also, the intensity parameters and total band intensity were calculated. We obtained for the vibration-rotation interaction factor the value F(m) = 1 + (0.26 ± 0.06) × 10-2m + (0.92 ±0.32 × 10-4 m2; for the purely vibrational transition moment, we found ¦R00003001II¦к(0.4351 ± 0.0014)()10b3 debye; and, for the total band intensity at STP conditions, Sband(3001II←0000)STP = 1255 ± 9 cm-1 km-1 atm-1.Self-broadening coefficients at 197 and 294 K were also measured, as well as broadening by Ar and N2. Foreign-gas-broadening efficiencies (Ar and N2) were determined. Finally, a comparison is made with measurements by other authors and with theoretically calculated values. 相似文献
67.
Ma. Joaquina Caballero Inmaculada Suarez Baudilio Coto Rafael Van Grieken Benjamín Monrabal 《Macromolecular Symposia》2007,257(1):122-130
Summary: The incorporation of comonomer molecules in the backbone of a homopolymer can influence the final properties of the material, decreasing its crystallinity and the melting and glass transition temperatures, and increasing its impact resistance and transparency. In the present work, ten ethylene/propylene copolymers have been synthesized using a supported metallocene catalytic system covering the whole composition range. Any desired composition was obtained by controlling the feed composition during the reaction. These synthesized copolymers have been characterized by different techniques in order to study the effect of the comonomer incorporation onto their final properties. When the comonomer content is low, the behaviour of the copolymer is similar to that of the corresponding homopolymer. Nevertheless, if the comonomer content increases, the copolymer becomes more amorphous (low crystallization temperature and soft XRD signals) and easily deformable, reaching a behaviour close to that corresponding to an elastomeric material. In order to corroborate these results the samples have been characterized by TREF and GPC-MALS. TREF analysis showed that copolymers containing less than 10% and more than 80% of ethylene are semicrystalline, with elution temperatures typical of this kind of polymers. Molecular weights are higher for homopolymers and they decrease as the comonomer concentration increases, whereas the polydispersity index keeps almost constant at the expected value for this kind of samples. 相似文献
68.
Coy Barrera CA Coy Barrera ED Granados Falla DS Delgado Murcia G Cuca Suarez LE 《Chemical & pharmaceutical bulletin》2011,59(7):855-859
A novel seco-limonoid, rel-(1S,5R,9S,7R,8S,9R,10S,11R,13S,14R,15R,17R)-11,19-dihydroxy-7-acetoxy-7-deoxoichangin (raputiolide) (1), and two novel quinolone alkaloids N-methyl-2-phenoxyquinolin-4(1H)-one (heptaphyllone A) (2) and 6-methylbenzofuro[2,3-b]quinolin-4(1H)-one (heptaphyllone B) (3), along with the known seco-limonoid ichangin (4), were isolated from Raputia heptaphylla PITTIER (Rutaceae) stem bark. Five known alkaloids, N-methyl-8-methoxyflindersine (5), skimmianine (6), kokusaginine (7), dictamnine (8) and flindersiamine (9), were also isolated from R. heptaphylla leaves. Their structures were established on the basis of full spectroscopic data interpretation supported by data from the pertinent literature. seco-Limonoid 1 configuration was determined by enhanced nuclear Overhauser effect spectroscopy (NOESY) experiments and density functional theory (DFT) molecular modeling. The antileishmanial effect of the isolated compounds was evaluated on Leishmania Viannia panamensis (promastigotes and amastigotes). Whereas alkaloids 2-3, 6-8 and limonoid 4 exhibited no significant parasitocide activity against internalized L. (V.) panamensis amastigotes, limonoid 1 and alkaloid 5 had leishmanicidal activity on intracellular amastigotes (EC??: 8.7 μg/ml) and promastigotes (EC(50): 14.3 μg/ml), respectively. 相似文献
69.
Carmen M. Romero Luis C. Garzon Luis H. Blanco Andres F. Suarez 《Journal of solution chemistry》2014,43(6):1147-1155
The solubility of nitrogen and argon in aqueous solutions of dodecyltrimethylammonium bromide (DTAB) were measured, using the drop pressure method, at temperatures between (283.15 and 298.15) K and partial pressure of 101325 Pa of gas in an instrument specially developed for this purpose. The gas solubility was calculated as Henry’s constant. The solubilities of argon and of nitrogen increase linearly with DTAB concentration and decrease as the temperature increases. Experimental results show that the increase in the solubility of argon and nitrogen in the DTAB micelles is between 59.0 and 83.5 higher than the solubility in pure water, reflecting the ability of DTAB micelles to increase the solubility of non-polar gases in water. 相似文献
70.
Khachatryan V Sirunyan AM Tumasyan A Adam W Bergauer T Dragicevic M Erö J Fabjan C Friedl M Frühwirth R Ghete VM Hammer J Hänsel S Hartl C Hoch M Hörmann N Hrubec J Jeitler M Kasieczka G Kiesenhofer W Krammer M Liko D Mikulec I Pernicka M Rohringer H Schöfbeck R Strauss J Taurok A Teischinger F Waltenberger W Walzel G Widl E Wulz CE Mossolov V Shumeiko N Suarez Gonzalez J Benucci L Ceard L Cerny K De Wolf EA Janssen X Maes T Mucibello L Ochesanu S Roland B Rougny R Selvaggi M Van Haevermaet H 《Physical review letters》2011,106(8):082001
The differential cross section for the inclusive production of isolated prompt photons has been measured as a function of the photon transverse energy E(T)(γ) in pp collisions at √s=7 TeV using data recorded by the CMS detector at the LHC. The data sample corresponds to an integrated luminosity of 2.9 pb(-1). Photons are required to have a pseudorapidity |η(γ)|<1.45 and E(T)(γ)>21 GeV, covering the kinematic region 0.006相似文献