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991.
992.
在合成含有8-羟基喹啉(8HOQ)配位基单体的基础上,将其与甲基丙烯酸甲酯(MMA)共聚得到含有8-羟基喹啉侧基的聚甲基丙烯酸甲酯(PMMA8q),实现了8-羟基喹啉的高分子化;通过PMMA8q和小分子协同配体与稀土离子Eu(Ⅲ)的配位反应,制备了两个稀土高分子发光配合物:Eu(PMMA8q)(8HOQ)2(H2O)3和Eu(PMMA8q)2(TTA)(H2O)3(TTA:噻吩甲酰三氟丙酮)。利用元素分析、红外光谱方法对各阶段产物进行了表征,用荧光光谱研究了两个稀土高分子配合物的荧光特性及发光机理。 相似文献
993.
Monodisperse spherical periodic mesoporous organosilicas (PMOs) with ethane integrated in the framework were synthesized and their application as stationary phase for chromatographic separation is demonstrated. The ethane-PMOs were prepared by condensation of 1,2-bis(triethoxysilyl)ethane (BTSE) in basic condition using octadecyltrimethylammonium chloride (C(18)TMACl) as template and ethanol as co-solvent. The morphology and mesoporous structure of ethane-PMOs were controlled under different concentrations of sodium hydroxide (NaOH) and EtOH. The results of scanning electron microscopy (SEM), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), nitrogen sorption measurement, Fourier transform infrared spectroscopy (FT-IR) and elemental analysis showed that ethane-PMOs have spherical morphology, uniform particle distribution, highly ordered pore structure, high surface area and narrow pore-size distribution. The column packed with these materials exhibits good permeability, high chemical stability and good selectivity of mixtures of aromatic hydrocarbons in normal phase high-performance liquid chromatography (HPLC). 相似文献
994.
This paper proposes a flexible fast profilometry based on modulation measurement. Two orthogonal gratings through a beam splitter are vertically projected on an object surface, and the measured object is placed between the imaging planes of the two gratings. Then the image of the object surface modulated by the orthogonal gratings can be obtained by a CCD camera in the same direction as the grating projection. This image is processed by the operations consisting of performing the Fourier transform, spatial frequency filtering and inverse Fourier transform. Using the modulation distributions of two grating patterns, we can reconstruct the 3D shape of the object. In the measurement process, we only need to capture one fringe pattern, so it is faster than the MMP and remains the advantages of it. In the article, the principle of this method, the setup of the measurement system, some simulations and primary experiment results are given. The simulative and experimental result proves it can restore the 3D shape of the complex object fast and comparatively accurate. Because only one fringe pattern is needed in the testing, our method has a promising extensive application prospect in real-time acquiring and dynamic measurement of 3D data of complex objects. 相似文献
995.
996.
997.
用手性配体改性铝锂试剂对芳香酮的还原 总被引:1,自引:0,他引:1
用手性一元酮作辅助配体,与1,2,5,6-二丙酮甘iAlh5对芳香酮进行对映选择 的,得到光学活性产物8个。通过与α-乙酰氧基-L-丙酰氯生成非对映异构体酯,经气相色谱分析,芳酮挑学产率为23.3 ̄71.2%。初步探讨了配体之间对称性匹配的情况。 相似文献
998.
Hung CC Su YN Tsao PN Chen PC Lin SJ Lin CH Mu SC Liu CA Chang YC Lin WL Hsieh WS Hsu SM 《Electrophoresis》2007,28(6):894-899
Congenital central hypoventilation syndrome (CCHS) is a rare neurological disorder characterized by abnormal autonomic central nervous system control of breathing during sleep. Mutations in the paired-like homeobox 2B (PHOX2B) gene, including point mutation, frameshift, and polyalanine expansion, are associated with the pathogenesis of CCHS. In this study, PHOX2B mutations were analyzed in seven CCHS patients, their family members, and 1520 healthy individuals from the general population using CE to provide high sensitivity and resolution screening for the PHOX2B polyalanine polymorphism. Seven mutations in the PHOX2B gene, including two frameshift mutations and five polyalanine expansions in the 20-residue polyalanine tract, were identified. The various phenotypes observed in CCHS patients with PHOX2B mutations suggest that the size of the expansion allele is associated with the CCHS risk. In addition, significant differences were found in allele and genotype distributions between the healthy individuals. Alleles (GCN)(20) and (GCN)(15) had the highest population incidence rates of 94.84 and 4.51%, respectively, with the remaining alleles, (GCN)(13) and (GCN)(7), accounting for 0.59 and 0.06%, respectively. Therefore, it has been demonstrated that CE can be used to improve the detection of polyalanine expansions in the PHOX2B gene. The attractive alternative method is a promising tool for the detection of disorders involving trinucleotide repeat tracts. 相似文献
999.
Shuzhen Fan Qingpu Wang Shutao Li Shuanghong Ding Fufang Su 《Optics Communications》2006,266(2):620-626
A method of more precise determination of the focal length of equivalent thermal lens (TL) is presented in this paper. The method is based on the diffraction theory of aberrations. By numerically calculating the optical path difference (OPD) distribution and the Strehl ratio, the focal lengths for “top-hat” pumping and Gaussian pumping are obtained and the equations for the focal lengths are presented by curve fitting. Also the equations for average pump radii are presented. The experiment on a fiber-coupled LD pumped Nd:YAG laser is carried out. The experimental results verify the validity of the method. 相似文献
1000.
利用频闪结构光测量旋转叶片的三维面形 总被引:3,自引:0,他引:3
在对快速甚至高速运动物体进行研究时,需要对运动物体各个时刻的三维面形和形变量进行数字化描述。提出了一种利用频闪光作为结构照明光源,基于傅里叶变换轮廓术对旋转叶片每个时刻的三维面形和变形量进行动态测量的光学方法。使用自行设计的同步控制单元对风扇叶片旋转位置进行检测,用该检测信号同步驱动频闪结构光源的发光和图像采集系统“冻结”记录下旋转叶片表面变形条纹的瞬时图像,再运用傅里叶变换轮廓术计算出每一瞬间时刻旋转叶片的三维面形,分析这些三维面形数字化结果可以进一步得到旋转叶片的变形量。通过对家用电风扇的实验,验证了该方法的合理性和可行性。该方法可望在高速运动物体的面形和变形研究上有广泛运用。 相似文献