全文获取类型
收费全文 | 14217篇 |
免费 | 2056篇 |
国内免费 | 1481篇 |
专业分类
化学 | 10761篇 |
晶体学 | 193篇 |
力学 | 668篇 |
综合类 | 123篇 |
数学 | 1375篇 |
物理学 | 4634篇 |
出版年
2024年 | 28篇 |
2023年 | 236篇 |
2022年 | 333篇 |
2021年 | 429篇 |
2020年 | 534篇 |
2019年 | 517篇 |
2018年 | 393篇 |
2017年 | 363篇 |
2016年 | 685篇 |
2015年 | 638篇 |
2014年 | 746篇 |
2013年 | 1084篇 |
2012年 | 1263篇 |
2011年 | 1247篇 |
2010年 | 881篇 |
2009年 | 818篇 |
2008年 | 1022篇 |
2007年 | 924篇 |
2006年 | 809篇 |
2005年 | 767篇 |
2004年 | 555篇 |
2003年 | 420篇 |
2002年 | 403篇 |
2001年 | 358篇 |
2000年 | 306篇 |
1999年 | 251篇 |
1998年 | 214篇 |
1997年 | 168篇 |
1996年 | 153篇 |
1995年 | 175篇 |
1994年 | 150篇 |
1993年 | 130篇 |
1992年 | 119篇 |
1991年 | 105篇 |
1990年 | 86篇 |
1989年 | 48篇 |
1988年 | 59篇 |
1987年 | 48篇 |
1986年 | 49篇 |
1985年 | 44篇 |
1984年 | 31篇 |
1983年 | 13篇 |
1982年 | 25篇 |
1981年 | 16篇 |
1980年 | 9篇 |
1979年 | 11篇 |
1978年 | 11篇 |
1977年 | 10篇 |
1975年 | 9篇 |
1974年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
11.
12.
Mei Xueqing Li Zhixiong Bagherzadeh Seyed Amin Karimipour Aliakbar Bahrami Mehrdad Karimipour Arash 《Journal of Thermal Analysis and Calorimetry》2021,145(4):2123-2128
Journal of Thermal Analysis and Calorimetry - Artificial neural network/kriging interpolation method optimization method which is evaluated concerned the hybrid nanofluid composed of iron oxide... 相似文献
13.
Polypyrrole Shell@3D‐Ni Metal Core Structured Electrodes for High‐Performance Supercapacitors
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Gao‐Feng Chen Yu‐Zhi Su Pan‐Yong Kuang Zhao‐Qing Liu Dao‐Yi Chen Xu Wu Nan Li Prof. Shi‐Zhang Qiao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(12):4614-4621
Three‐dimensional (3D) nanometal films serving as current collectors have attracted much interest recently owing to their promising application in high‐performance supercapacitors. In the process of the electrochemical reaction, the 3D structure can provide a short diffusion path for fast ion transport, and the highly conductive nanometal may serve as a backbone for facile electron transfer. In this work, a novel polypyrrole (PPy) shell@3D‐Ni‐core composite is developed to enhance the electrochemical performance of conventional PPy. With the introduction of a Ni metal core, the as‐prepared material exhibits a high specific capacitance (726 F g?1 at a charge/discharge rate of 1 A g?1), good rate capability (a decay of 33 % in Csp with charge/discharge rates increasing from 1 to 20 A g?1), and high cycle stability (only a small decrease of 4.2 % in Csp after 1000 cycles at a scan rate of 100 mV s?1). Furthermore, an aqueous symmetric supercapacitor device is fabricated by using the as‐prepared composite as electrodes; the device demonstrates a high energy density (≈21.2 Wh kg?1) and superior long‐term cycle ability (only 4.4 % and 18.6 % loss in Csp after 2000 and 5000 cycles, respectively). 相似文献
14.
Yongjie Zhou Yuqi Mei Tian Luo Wenxue Chen Qiuping Zhong Haiming Chen Weijun Chen 《Molecules (Basel, Switzerland)》2021,26(9)
The contribution of rheological properties and viscoelasticity of the interfacial adsorbed layer to the emulsification mechanism of enzymatic modified sugar beet pectin (SBP) was studied. The component content of each enzymatic modified pectin was lower than that of untreated SBP. Protein and ferulic acid decreased from 5.52% and 1.08% to 0.54% and 0.13%, respectively, resulting in a decrease in thermal stability, apparent viscosity, and molecular weight (Mw). The dynamic interfacial rheological properties showed that the interfacial pressure and modulus (E) decreased significantly with the decrease of functional groups (especially proteins), which also led to the bimodal distribution of particle size. These results indicated that the superior emulsification property of SBP is mainly determined by proteins, followed by ferulic acid, and the existence of other functional groups also promotes the emulsification property of SBP. 相似文献
15.
16.
Luo Dajuan Liu Bingqian Gao Rong Su Lixia Su Yonghuan 《Journal of Solid State Electrochemistry》2022,26(3):749-759
Journal of Solid State Electrochemistry - Cortisol, a steroid hormone, has been confirmed as a kind of biomarker that reflects the stress response of psychobiology and related adverse health... 相似文献
17.
A protocol to correct for intra‐ and interspecific variation in tail hair growth to align isotope signatures of segmentally cut tail hair to a common time line
下载免费PDF全文
![点击此处可从《Rapid communications in mass spectrometry : RCM》网站下载免费的PDF全文](/ch/ext_images/free.gif)
18.
19.
Solid‐state 31P NMR investigation on the status of guanine nucleotides in paclitaxel‐stabilized microtubules
下载免费PDF全文
![点击此处可从《Magnetic resonance in chemistry : MRC》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Ga Hyang Lee Su Young Oh Kwon Joo Yeo Taslima Ferdous Meeyeon Cho Younkee Paik 《Magnetic resonance in chemistry : MRC》2015,53(5):330-336
Microtubule dynamics is a target for many chemotherapeutic drugs. In order to understand the biochemical effects of paclitaxel on the GTPase activity of tubulin, the status of guanine nucleotides in microtubules was investigated by 31P cross‐polarization magic angle spinning (CPMAS) NMR. Microtubules were freshly prepared in vitro in the presence of paclitaxel and then lyophilized in sucrose buffer for solid‐state NMR experiments. A 31P CPMAS NMR spectrum with the SNR of 25 was successfully acquired from the lyophilized microtubule sample. The broadness of the 31P spectral lines in the spectrum indicates that the molecular environments around the guanine nucleotides inside tubulin may not be as crystalline as reported by many diffraction studies. Deconvolution of the spectrum into four spectral components was carried out in comparison with the 31P NMR spectra obtained from five control samples. The spectral analysis suggested that about 13% of the nucleotides were present as GTP and 37% as GDP in the β‐tubulin (E‐site) of the microtubules. It was found that most of the GDPs were present as GDP‐Pi complex in the microtubules, which seems to be one of the effects of paclitaxel binding. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
20.
Ling-Yang Hsu Qiumin Liang Zhiheng Wang Hsin-Hung Kuo Wun-Shan Tai Shi-Jian Su Xiuwen Zhou Yi Yuan Yun Chi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(67):15375-15386
Iridium complexes bearing chelating cyclometalates are popular choices as dopant emitters in the fabrication of organic light-emitting diodes (OLEDs). In this contribution, we report a series of blue-emitting, bis-tridentate IrIII complexes bearing chelates with two fused five-six-membered metallacycles, which are in sharp contrast to the traditional designs of tridentate chelates that form the alternative, fused five-five metallacycles. Five IrIII complexes, Px-21 – 23 , Cz-4 , and Cz-5 , have been synthesized that contain a coordinated dicarbene pincer chelate incorporating a methylene spacer and a dianionic chromophoric chelate possessing either a phenoxy or carbazolyl appendage to tune the coordination arrangement. All these tridentate chelates afford peripheral ligand–metal–ligand bite angles of 166–170°, which are larger than the typical bite angle of 153–155° observed for their five-five-coordinated tridentate counterparts, thereby leading to reduced geometrical distortion in the octahedral frameworks. Photophysical measurements and TD-DFT studies verified the inherent transition characteristics that give rise to high emission efficiency, and photodegradation experiments confirmed the improved stability in comparison with the benchmark fac-[Ir(ppy)3] in degassed toluene at room temperature. Phosphorescent OLED devices were also fabricated, among which the carbazolyl-functionalized emitter Cz-5 exhibited the best performance among all the studied bis-tridentate phosphors, showing a maximum external quantum efficiency (EQEmax) of 18.7 % and CIEx,y coordinates of (0.145, 0.218), with a slightly reduced EQE of 13.7 % at 100 cd m−2 due to efficiency roll-off. 相似文献