Wastes Treatment: Hydrothermal electrolytic oxidation of wastewater

Abstract

Electrochemical evolution of hydrogen gas, oxygen gas and chlorine at the electrodes is the usual reaction in conventional electrolysis of aqueous salt solution. However, here we demonstrate that the electrolysis governing reaction in hydrothermal solutions is different from the electrolysis performed at atmospheric pressure and temperatures up to 100°C. Experimental electrolytic reaction of aqueous salt solution carried out inside a sealed 300-mL batch autoclave showed that; accumulation of hydrogen gas, oxygen gas and chlorine is highly suppressed under hydrothermal (250°C and 7 MPa) conditions. We have also observed that, when organics are present in the aqueous salt solution being hydrothermally electrolyzed, an effective oxidation of organics is accomplished. Furthermore, for hydrothermal electrolytic oxidation (HEO) with oxygen gas added, experimentally observed TOC removal profile demonstrates apparent anodic oxidation electrical current efficiency of almost 200% for highconcentrated acetic acid solutions.     

Chaos anticontrol and synchronization of three time scales brushless DC motor system

Chaos anticontrol of three time scale brushless dc motors and chaos synchronization of different order systems are studied. Nondimensional dynamic equations of three time scale brushless DC motor system are presented. Using numerical results, such as phase diagram, bifurcation diagram, and Lyapunov exponent, periodic and chaotic motions can be observed. By adding constant term, periodic square wave, the periodic triangle wave, the periodic sawtooth wave, and kx|x| term, to achieve anticontrol of chaotic or periodic systems, it is found that more chaotic phenomena of the system can be observed. Then, by coupled terms and linearization of error dynamics, we obtain the partial synchronization of two different order systems, i.e. brushless DC motor system and rate gyroscope system.     

New method for energy compensation of free electron laser

In this paper the theory of FEL operation in a longitudinal uniform magnetic field integrated with a synchronous precessing electro-magnetic field is expounded in view of the main problems in FEL development. A new energy compensation method is suggested as a new way and basis for the development of FEL research.     

Metamaterial absorber and extending absorbance bandwidth based on multi-cross resonators

In this paper, we report the design, simulation, and measurements of a broadband metamaterial absorber (MA) based on a periodic array of multi-layer cross-structure resonators. A perfect narrowband MA consists of cross-structure resonator, dielectric substrate, and continuous metal films, and the absorption frequency can be tunable by changing the geometrical parameters based on L-C resonance circuit theory. Furthermore, the absorption band of our design is effectively extended by simply stacking several such structural layers with different geometrical dimensions. Finally, the 4-layer cross-structure MA is only 2 mm, which can achieve a full width at half maximum (FWHM) bandwidth of 2 GHz by numerical simulations, and 90 % bandwidth of 1.9 GHz by experiments.     

Simulation of InGaN/GaN light-emitting diodes with a non-local quantum well transport model

Blue InGaN/GaN multiple quantum well (MQW) light-emitting diodes (LEDs) are simulated by the APSYS software with a non-local quantum well transport model which is used to describe the phenomenon that carriers can fly over the quantum wells directly. The simulation results based on this model are in good agreement with the experiment and show its significant influence on the output power, carrier transport, peak wavelength and current crowding effect of the InGaN/GaN MQW LEDs, indicating that the non-local quantum well transport plays an important role in these devices.     

Effects and Corrections for Mobile NMR Measurement

Nuclear magnetic resonance (NMR) under motion has drawn significant attention in recent years. Motion of the NMR probe has serious effects on NMR measurement. For example, NMR logging normally runs at downhole condition with tool motion at a speed of 30 ft/min. We propose here methods for motion corrections of NMR data based on the quantitative analysis of motion effects on polarization and echo acquisition. We also produced a multi-functional NMR scanning system to verify the theoretical analysis. Presented experiments demonstrate that the theoretical and experimental results match very well.     

一类扩张了的软弹簧型Duffing方程的紊动性态

本文用Melnikov函数方法讨论了一类扩张了的软弹簧型Duffing方程(k=1,2,3,…)在周期激励下的紊动现象.给出了出现二阶同宿切的条件.文中所采用的方法对于不能给出并宿轨道的显式的系统的研究是非常有用的.     

对流扩散方程一类改进的特征线修正有限元方法

１引言在地下水污染,地下渗流驱动,核污染,半导体等问题的数值模拟中,均涉及抛物型对流扩散方程（或方程组）的数值求解问题．这些对流扩散型偏微分方程（或方程组）具有共同的特点：对流的影响远大于扩散的影响,即对流占优性,对流占优性给问题的数值求解带来许多困难,因此对流占优问题的有效数值解法一直是计算数学中重要的研究内容．用通常的差分法或有限元法进行数值求解将出现数值振荡．为了克服数值振荡,提出各种迎风方法和修正的特征方法并在这些问题上得到成功的实际应用、８０年代,Ｄｏｕｇｌａｓ和Ｒｕｓｓｅｌｌ［２］等…     

An Active Set Modified Polak–Ribiére–Polyak Method for Large-Scale Nonlinear Bound Constrained Optimization

In this paper, we propose an active set modified Polak?CRibiére?CPolyak method for solving large-scale optimization with simple bounds on the variables. The active set is guessed by an identification technique at each iteration and the recently developed modified Polak?CRibiére?CPolyak method is used to update the variables with indices outside of the active set. Under appropriate conditions, we show that the proposed method is globally convergent. Numerical experiments are presented using box constrained problems in the CUTEr test problem libraries.     

Enhanced high-rate performance of sub-micro Li4Ti4.95Zn0.05O12 as anode material for lithium-ion batteries

Zn-doped Li₄Ti₅O₁₂ was prepared by a ball milling-assisted solid-state method, and the characters were determined by X-ray diffraction, Raman spectroscopy, scanning electron microscopy, cyclic voltammetry, and galvanostatic charge–discharge testing. The results show that Li₄Ti_5?x Zn _x O₁₂ (x?=?0, 0.05) exhibits the pure phase structure, and Zn doping does not change the electrochemical reaction process and basic spinel structure of Li₄Ti₅O₁₂. The particle size of both samples is about 300–500 nm. The prepared Li₄Ti_4.95Zn_0.05O₁₂ presents an excellent rate capability and capacity retention. At the charge–discharge rate of 1C, the initial discharge capacity of Li₄Ti_4.95Zn_0.05O₁₂ is 268 mAh g^?1. After 90 cycles at 5C, the discharge capacity of Li₄Ti_4.95Zn_0.05O₁₂ is obviously higher than that of Li₄Ti₅O₁₂. The excellent electrochemical performance of the Li₄Ti_4.95Zn_0.05O₁₂ electrode could be attributed to the improvement of reversibility by doping zinc and the sub-micro particle size.