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101.
Rainer Strommer Wolfgang Strauss Helmut Emmert Reinhard Sailer Rudolf Steiner Eva Reisinger Ernst Haslinger Hans W. Schramm 《Monatshefte für Chemie / Chemical Monthly》2001,132(3):387-392
Summary. Selenium dioxide oxidation allows the selective introduction of a hydroxyl group at position 6 of the steroid skeleton of
the antihormone (11β, 17β)-11-(4-dimethylamino-phenyl)-17-hydroxyl-17-(1-propynyl)-estra-4,9-dien-3-one (mifepristone, RU
486) and leads in a one-step procedure to two diastereomeric oxidation products. Their structure (6α- and 6β-hydroxy-mifepristone)
was determined by NMR spectroscopy. The antiprogestinic activity of the oxidation products is comparable to that of mifepristone.
Received August 25, 2000. Accepted (revised) October 24, 2000 相似文献
102.
Mateja Pogorevc Ulrike T. Strauss Marianne Hayn Kurt Faber 《Monatshefte für Chemie / Chemical Monthly》2000,220(2):639-644
Biocatalytic resolution of the tertiary terpene alcohol (±)-linalool was accomplished via hydrolysis of its corresponding acetate ester using two highly enantiospecific enzymes (E > 100). The latter were identified in a crude cell-free extract of Rhodococcus ruber DSM 43338 and could be separated by (partial) protein purification. Since they showed opposite enantiopreference, they were
termed (R)- and (S)-linalyl acetate hydrolase (LAH). The activity and selectivity of the enzyme preparations was markedly dependent on the fermentation
conditions. 相似文献
103.
Kuno Strauss 《Nachrichten aus der Chemie》2005,53(12):1266-1266
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We consider the linear stability problem for a symmetric equilibrium of the relativistic Vlasov‐Maxwell (RVM) system. For an equilibrium whose distribution function depends monotonically on the particle energy, we obtain a sharp linear stability criterion. The growing mode is proved to be purely growing, and we get a sharp estimate of the maximal growth rate. In this paper we specifically treat the periodic 1½D case and the 3D whole‐space case with cylindrical symmetry. We explicitly illustrate, using the linear stability criterion in the 1½D case, several stable and unstable examples. © 2006 Wiley Periodicals, Inc. 相似文献
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We consider the classical water wave problem described by the Euler equations with a free surface under the influence of gravity over a flat bottom. We construct two‐dimensional inviscid periodic traveling waves with vorticity. They are symmetric waves whose profiles are monotone between each crest and trough. We use bifurcation and degree theory to construct a global connected set of such solutions. © 2003 Wiley Periodicals, Inc. 相似文献
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