全文获取类型
收费全文 | 164篇 |
免费 | 3篇 |
国内免费 | 2篇 |
专业分类
化学 | 57篇 |
晶体学 | 2篇 |
力学 | 3篇 |
数学 | 14篇 |
物理学 | 93篇 |
出版年
2022年 | 2篇 |
2019年 | 2篇 |
2018年 | 1篇 |
2017年 | 2篇 |
2016年 | 3篇 |
2015年 | 2篇 |
2014年 | 7篇 |
2013年 | 24篇 |
2012年 | 8篇 |
2011年 | 12篇 |
2010年 | 8篇 |
2009年 | 2篇 |
2008年 | 6篇 |
2007年 | 4篇 |
2006年 | 4篇 |
2005年 | 5篇 |
2004年 | 3篇 |
2003年 | 9篇 |
2002年 | 5篇 |
2001年 | 7篇 |
2000年 | 1篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1997年 | 5篇 |
1996年 | 4篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1968年 | 2篇 |
1957年 | 1篇 |
1939年 | 1篇 |
1934年 | 2篇 |
1933年 | 2篇 |
1867年 | 1篇 |
排序方式: 共有169条查询结果,搜索用时 0 毫秒
91.
92.
93.
94.
Storch KV Kowski P Strauch G Trettin R Wieser T 《Isotopes in environmental and health studies》1996,32(4):387-403
Abstract The groundwaters studied and labelled as mineral water were "natural mineral waters" for bottled waters and "natural curative waters" for heal therapeutical applications. They were characterized either by a specific mineralization or their suitability for balneology. To reveal the actual hydrological situation isotope investigations using (2)H, (18)O, (3)H, (12)C and (14)C (DIC) and (34)S (sulphate) were included in a study describing samples of 24 mineral water deposits in Saxonia. The water was classified into 4 hydrochemical types of genesis. Due to different hydrogeological and hydrochemical situations widely scattered isotope ratios were measured. Most of the investigated mineral waters are containing at least parts of younger waters (with residence times less than about 40 years). Correlations between chemical composition and the tritium content could be observed within different springs from the areas Bad Brambach, Bad Elster and Burkhardswalde. Strong variations in δ(34)S were found in samples with low sulphate content, showing different sulphur sources, as well as microbiological reactions. On the other hand mineral waters from Bad Brambach and Bad Elster show nearly the same δ(34)S value of about 6‰ CDT despite beeing of a different chemical type. The δ(13)C values between -22 and -2.2y PDB are related to different sources of CO(2). 相似文献
95.
Gerhard Strauch 《Isotopes in environmental and health studies》2013,49(4):407-408
Beaver Lake and Radok Lake, the largest known epishelf lake and the deepest freshwater lake on the Antarctic continent, respectively, were isotopically (δ2H, δ18O) and hydrogeochemically studied. Radok Lake is an isothermal and non-stratified, i.e. homogeneous water body, while Beaver Lake is stratified with respect to temperature, salinity, and isotopic composition. The results for the latter attest to freshwater (derived from snow and glacier melt) overlying seawater. 相似文献
96.
Claudia Strauch 《Probability Theory and Related Fields》2016,164(1-2):361-400
The problem of pointwise adaptive estimation of the drift coefficient of a multivariate diffusion process is investigated. We propose an estimator which is sharp adaptive on scales of Sobolev smoothness classes. The analysis of the exact risk asymptotics allows to identify the impact of the dimension and other influencing values—such as the geometry of the diffusion coefficient—of the prototypical drift estimation problem for a large class of multidimensional diffusion processes. We further sketch generalizations of our results to arbitrary diffusions satisfying suitable Bernstein-type inequalities. 相似文献
97.
Applying the theory of uniform distribution, especially the Erdös-Turán-Koksma inequality and the Koksma-Hlawka inequality, to the two-dimensional Kloosterman sequence , j=1,2,…,?(n) (where , and ?(n) is the Euler function) we find an estimation for the discrepancy of this sequence and an error term for the Kth moment, K=1,2,…, of the sequence of distances as
98.
We analyse the evolution of a two-stage chemical reaction betweentwo neighbouring plumes of reactants. Under the assumption thatthe plumes are approximately Gaussian we derive a system ofordinary differential equations for the total amount, the centroidand the variance of each reactant. We compare the solution ofthese equations with full numerical simulation of the reaction.Excellent agreement is obtained, with solution of the near-Gaussianmodel requiring considerably less computational effort thanthe full simulations. Of key importance is the yield of thereaction, and we discuss this feature in particular. 相似文献
99.
AM Cardoso SM Alexandre CM Barros AJ Correia NM Nibbering 《Rapid communications in mass spectrometry : RCM》1999,13(19):1885-1888
The collision-induced dissociation (CID) of deprotonated arylalkylamines of general formula R(1)C(6)H(4)CHR(2)CH(2)NR(3)(2) (where R(1) = H, OH, F or NO(2); R(2) = H or OH; R(3) = H or CH(3)) generated by negative chemical ionization with H(2)O and D(2)O as ionizing reagents, is discussed. The negative chemical ionization mass spectra show that, in the absence of a hydroxy group in the aromatic ring, deprotonation takes place at the benzylic position whereas the proton is lost from the OH group when present. The nitro compound forms only M(-.) ions. The CID spectra of the deprotonated molecules show that fragmentations are strongly dependent on the structural features of the molecules, namely the presence or absence of substituents in the aromatic ring or aliphatic chain. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
100.
An ab initio-based model of the temperature-induced ferroelectric phase transition in Sn2P2S6 (SPS) as a prototype of an unconventional ferroelectric is developed. The order parameter in SPS is found as the valley line on a total-energy surface of the zone-center fully symmetrical Ag and polar Bu distortions. Significant nonlinear coupling between order parameter and strain is observed. Monte Carlo simulations describe the additional low-temperature rearrangement in polar structure, which appears in domain boundaries, and describe the relaxation phenomena near the ferroelectric phase transition. 相似文献