Determination of manganese in grain by potential titration with catalytic end-point indication

A method of catalytic potential titration for the determination of trace manganese by using crystal violet ion selective electrode is reported in this paper. It is based on the catalytic effect of manganese (II) on the oxidation of crystal violet by potassium periodate in the presence of nitrilotriacetic acid (NTA). The experiments indicated that this technique showed high sensitivity and high accuracy. The results of determination of trace manganese in grain could be compared with the results obtained by means of atomic absorption spectrometry.     

Tandem conjugate addition-α-alkylation of unsaturated amides. Synthetic methodology.

1,4-Addition of RLi, RMgX, and (RS) ₂CHLi reagents to unsaturated amides 2a-c followed by α-alkylation is shown to constitute a general and efficient synthetic procedure for the formation of two CC bonds in a single step.     

Pushing the detectability of voltammetry: how low can we go?

The coupling of adsorptive accumulation with catalytic reactions results in remarkably low (sub-picomolar) detection limits. This review assesses various strategies for attaining such dual-amplification effects, that lead to the most sensitive voltammetric technique, adsorptive-catalytic stripping voltammetry (AdCtSV).     

Effect of water-soluble cross-linker on the growth and properties of ethyl acrylate–methacrylic acid emulsion opolymer particles

Model ethyl acrylate–methacrylic acid copolymer latices and latices of particles cross-linked by copolymerizing small amounts of water-soluble N,N′-methylenebisacrylamide were prepared by nonseeded semicontinuous emulsion copolymerization. Dynamic and static light scattering measurements indicated a slightly higher degree of polydispersity in the case of cross-linked particles, especially in the initial stages of polymerization. The hydrodynamic volume of the alkalinized particles controlling the viscosity properties of the dispersions decreased with the time of polymerization and in the case of cross-linked copolymer almost reached a constant value at about 1 h. The different character of the particle structure was confirmed by differences in particle disintegration after alkali addition or in the presence of methanol. Received: 2 February 1999/Accepted: 28 June 2000     

The triplet channel in the photodissociation of ozone in the Hartley band: classical trajectory surface hopping analysis

The triplet channel in the photodissociation of ozone in the Hartley band, O3 + hv-->O(3P) + O2(3sigma), is investigated by means of a classical trajectory surface hopping method using ab initio diabatic potential energy surfaces for the B and the R states. Because of the strong recoil in the R state along the breaking O-O bond, O2(3sigma) is produced with a high rotational energy. The nonadiabatic transition probability depends markedly on the coordinate along the crossing seam. As a consequence a unique correlation is found between the internuclear geometry at the crossing and the final vibrational state of O2(3sigma). The calculated distribution of the translational energy is in good accord with the measured distribution.     

Lipophilicity determination of some potential photosystem II inhibitors on reversed-phase high-performance thin-layer chromatography

The retention characteristics of 25 2-cyano-3-methylthio-3-substituted amine-acrylates are determined using reversed-phase thin-layer chromatography (RP-TLC) with methanol-water mixtures as eluents. The relationship between Rm values and partition coefficients (C log P) are established. The Rm values decrease linearly with increasing methanol concentration in the eluent. The Rm values extrapolated to zero organic modifier concentration (Rm0) in the eluent are highly related to C log P. The Rm0 value can be used to evaluate the lipophilicity of this kind of compound.     

Determination of iodide in drinking water by isotope dilution analysis

The most suitable way of determination iodine-deficiency is to measure iodine concentrations in water and urine. For this reason, a method that can determine iodide concentrations in drinking water and suitable for routine analysis, is developed. Water samples have been collected from four Aegean localities: Izmir, Salihli, Ödemis and Tire situated in the western Turkey. The method is based on substochiometric isotope dilution analysis. Iodile concentrations vary within 9.86–85.14 μg/l ranges in the analyzed samples. Mean value is 44.92±22.07 μg/l.     

Flow-injection catalytic spectrophotometric determination of nitrite using the redox reaction between naphthol green B and potassium bromate

A flow injection catalytic spectrophotometric method is proposed for the determination of nitrite based on its catalytic effect on the redox reaction between naphthol green B and potassium bromate in phosphoric acid medium. The reaction is monitored spectrophotometrically by measuring the decrease in absorbance of naphthol green B at the maximum absorption wavelength of 722 nm. The detection limit is 0.5 ng cm(-3) in a sample volume of 90 mm(3). Up to 50 samples can be analyzed per hour with a relative precision of ca. 2%. The method is free from most interferences, especially from large amounts of nitrate. The procedure was successfully applied to the determination of trace nitrite in natural waters.