A procedure for obtaining lower bounds for ground state energies of atoms and molecules

Using Löwdin's partition method we have re-derived the D. Weinstein lower bound, E > H ₁₁ - . By the same method, plus the assumption that the calculated first excited state energy is lower than a certain weighted average of approximate energies of all the excited states, we have derived a moderately better lower bound.     

A Mössbauer effect study of Y(57Fe:Mn)12

The intermetallic compound, YMn₁₂, doped with 0.5at.%⁵⁷Fe has been investigated using the⁵⁷Fe Mössbauer resonance. The data show that the Fe impurities occupy preferentially the f-site at the expense of the i- and j-sites. Whereas the i- and j-sites are expected to carry identical local magnetic moments in the ordered state, low temperature hyperfine fields of 50.08(±0.05)T and 2.90(±0.03)T are measured for the i- and j-sites respectively. It is proposed that large transferred hyperfine fields are responsible for this disparity.     

Flow-injection analysis: A review of its early history

A review is given of the development of flow-injection analysis, which seeks to establish the various lines of research which led to the present form of the technique.     

Differential cross sections for np and nd elastic scattering near 130 MeV

We have measured the np (nd) elastic scattering cross sections at 25(17) angles in the interval 30°–168° (c.m.), using a neutron beam with a broad spectrum peaked near 130 MeV. At backward angles the outgoing charged particles from a liquid hydrogen (deuterium) target were detected; at forward angles we detected neutrons scattered from a hydrogenated (deuterated) scintillating target. Cross sections have been normalized to the energy dependent solution of the Livermore nucleon-nucleon partial wave analysis, evaluated at 130 MeV. The np measurements represent a marginal improvement on previous work; the nd cross sections show some differences from pd measurements, in agreement with earlier indications at an energy of 152 MeV.     

Specific heat of A-15 Nb3Al0.83Ge0.21

The specific heat of A-15 Nb₃Al_.83Ge_.21 with a transition temperature, T_c, of 20.0 K has been measured from 6 to 25 K. Values of the parameters derived from the data are γ=35.0±2 mJ/mole-K²; the Debye temperature, θ_D=278±5 K; the energy gap, △, normalized as 2△/kT_c, is 4.9±.3, and the thermodynamic critical field, H_c(0), is 4700±300 Gauss.     

Spin correlations in the paramagnetic phase and ring exchange in La2CuO4

Spin correlations in the paramagnetic phase of La(2)CuO(4) have been studied using polarized neutron scattering, with two important results. First, the temperature dependence of the characteristic energy scale of the fluctuations and the amplitude of the neutron structure factor are shown to be in quantitative agreement with the predictions of the quantum nonlinear sigma model. Second, a comparison of a high-temperature series expansion of the equal-time spin correlations with the diffuse neutron intensity provides definitive experimental evidence for ring exchange.     

Grüneisen ratio divergence at the quantum critical point in CeCu(6-x)Agx

The heavy-fermion system CeCu6-xAgx is studied at its antiferromagnetic quantum critical point, xc=0.2, by low-temperature (T> or =50 mK) specific heat, C(T), and volume thermal expansion, beta(T), measurements. Whereas C/T proportional to log((T0/T) would be compatible with the predictions of the itinerant spin-density-wave (SDW) theory for two-dimensional critical spin fluctuations, beta(T)/T and the Grüneisen ratio, Gamma(T) proportional to beta/C, diverge much weaker than expected, in strong contrast to this model. Both C and beta, plotted as a function of the reduced temperature t=T/T0 with T0=4.6 K, are similar to what was observed for YbRh2(Si(0.95)Ge(0.05))2 (T0=23.3 K), indicating a striking discrepancy to the SDW prediction in both systems.