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101.
Makarycheva-Mikhailova AV Bokach NA Kukushkin VY Kelly PF Gilby LM Kuznetsov ML Holmes KE Haukka M Parr J Stonehouse JM Elsegood MR Pombeiro AJ 《Inorganic chemistry》2003,42(2):301-311
Pt(IV)-mediated addition of the sulfimide Ph2S = NH and the mixed sulfide/sulfimides o- and p-[PhS(=NH)](PhS)-C6H4 by the S=NH group to the metal-bound nitriles in the platinum(IV) complexes [PtCl4(RCN)2] proceeds smoothly at room temperature in CH2Cl2 and results in the formation of the heterodiazadiene compounds [PtCl4[NH=C(R)N=SR'Ph]2] (R' = Ph, R = Me, Et, CH2Ph, Ph; R' = o- and p-(PhS)C6H4; R = Et). While trans-[PtCl4(RCN)2] (R = Et, CH2Ph, Ph) reacting with Ph2S=NH leads exclusively to trans-[PtCl4[NH=C(R)N=SPh2]2], cis/trans-[PtCl4(MeCN)2] leads to cis/trans mixtures of [PtCl4[NH=C(Me)N=SPh2]2] and the latter have been separated by column chromatography. Theoretical calculations at both HF/HF and MP2//HF levels for the cis and trans isomers of [PtCl4[NH=C(Me)N=SMe2]2] indicate a higher stability for the latter. Compounds trans-[PtCl4[E-NH=C(R)N=SPh2]2] (R = Me, Et) and cis-[PtCl4[E-NH=C(Me)N=SPh2][Z-NH=C(Me)N=SPh2]] have been characterized by X-ray crystallography. The complexes [PtCl4[NH=C(R)N=SPh2]2] undergo hydrolysis when treated with HCl in nondried CH2Cl2 to achieve the amidines [PtCl4[NH=C(NH2)R]2] the compound with R = Et has been structurally characterized) and Ph2SO. The heterodiazadiene ligands, formed upon Pt(IV)-mediated RCN/sulfimide coupling, can be liberated from their platinum(IV) complexes [PtCl4[NH=C(R)N=SR'Ph]2] by reaction with Ph2PCH2CH2PPh2 (dppe) giving free NH=C(R)=SR'Ph and the dppe oxides, which constitutes a novel route for such rare types of heterodiazadienes whose number has also been extended. The hybrid sulfide/sulfimide species o- and p-[PhS(=NH)](PhS)C6H4 also react with the Pt(II) nitrile complex [PtCl2(MeCN)2] but the coupling--in contrast to the Pt(IV) species--gives the chelates [PtCl2[M-I=C(Me)N=S(Ph)C6H4SPh]]. The X-ray crystal structure of [PtCl2[M-I=C(Me)N=S(Ph)C6H4SPh-o]] reveals the bond parameters within the metallacycle and shows an unusual close interaction of the sulfide sulfur atom with the platinum. 相似文献
102.
The mass spectra of neopentyl alcohol, bromide and chloride and some 13C and 2H labelled analogues have been studied. Most fragmentations of the molecular ions of these compounds occur by simple bond cleavages and do not involve rearrangement before fragmentation. We propose that in the [M ? CH3]+ fragment ions, seven of the eight hydrogen atoms and all four carbon atoms are involved in randomisation when an ethylene molecule is ejected. The eighth hydrogen atom (which comes from a methyl group) is probably associated with the heteroatom. The neopentylcation, observed only in the mass spectrum of the bromide, fragments mainly by loss of an ethylene molecule, also containing randomly selected hydrogen and carbon atoms. The [C4H7]+ ion also was observed to undergo complete atom scrambling. 相似文献
103.
Treatment of several divalent transition-metal trifluoromethanesulfonates [M(II)(OTf)2; M(II) = Mn, Co, Ni] with [NEt4][Tp*Fe(III)(CN)3] [Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate] in DMF affords three isostructural rectangular clusters of {[Tp*Fe(III)(CN)3M(II)(DMF)4]2[OTf]2} x 2DMF (M(II) = Mn, 3; Co, 4; Ni, 5) stoichiometry. Magnetic studies of 3-5 indicate that the Tp*Fe(CN)3(-) centers are highly anisotropic and exhibit antiferromagnetic (3 and 4) and ferromagnetic (5) exchange to afford S = 4, 2, and 3 spin ground states, respectively. ac susceptibility measurements suggest that 4 and 5 exhibit incipient single-molecule magnetic behavior below 2 K. 相似文献
104.
We present an accurate and fast wave tracking method that uses parametric representations of tracked fronts, combined with modifications of level set methods that use narrow bands. Our strategy generates accurate computations of the front curvature and other geometric properties of the front. We introduce data structures that can store discrete representations of the location of the moving fronts and boundaries, as well as the corresponding level set fields, that are designed to reduce computational overhead and memory storage. We present an algorithm we call stack sweeping to efficiently sort and store data that is used to represent orientable fronts. Our implementation features two reciprocal procedures, a forward ‘front parameterization’ that constructs a parameterization of a front given a level set field and a backward ‘field construction’ that constructs an approximation of the signed normal distance to the front, given a parameterized representation of the front. These reciprocal procedures are used to achieve and maintain high spatial accuracy. Close to the front, precise computation of the normal distance is carried out by requiring that displacement vectors from grid points to the front be along a normal direction. For front curves in two dimensions, a cubic interpolation scheme is used, and G 1 surface parameterization based on triangular patches is used for the three-dimensional implementation to compute the distances from grid points near the front. To demonstrate this new, high accuracy method we present validations and show examples of combustion-like applications that include detonation shock dynamics, material interface motions in a compressible multi-material simulation and the Stephan problem associated with dendrite solidification. 相似文献
105.
Ronald F. Stewart 《Molecular physics》2013,111(4):879-883
An analytical expression of dipolar absorption, obtained by truncating the memory function hierarchy to the first order is compared to experimental results on Furan and Chloroform at different temperatures. The proposed method permits the prediction of the form of the correlation functions if the high frequencies absorption spectrum only, is known. 相似文献
106.
107.
Mohammed I. Jeraal Nicholas Holmes Geoffrey R. Akien Richard A. Bourne 《Tetrahedron》2018,74(25):3158-3164
Reaction optimisation and understanding is fundamental for process development and is achieved using a variety of techniques. This paper explores the use of self-optimisation and experimental design as a tandem approach to reaction optimisation. A Claisen-Schmidt condensation was optimised using a branch and fit minimising algorithm, with the resulting data being used to fit a response surface model. The model was then applied to find new responses for different metrics, highlighting the most important for process development purposes. 相似文献
108.
Aminomercuration and aminoselenation of electron rich alkenes provides a useful route to adenosine nucleoside analogs. 相似文献
109.
Xuan Thinh Duong Irina Holmes Ji Li Brett D. Wick Dongyong Yang 《Journal of Functional Analysis》2019,276(4):1007-1060
In this paper we establish the characterization of the weighted BMO via two weight commutators in the settings of the Neumann Laplacian on the upper half space and the reflection Neumann Laplacian on with respect to the weights associated to and respectively. This in turn yields a weak factorization for the corresponding weighted Hardy spaces, where in particular, the weighted class associated to is strictly larger than the Muckenhoupt weighted class and contains non-doubling weights. In our study, we also make contributions to the classical Muckenhoupt–Wheeden weighted Hardy space (BMO space respectively) by showing that it can be characterized via the area function (Carleson measure respectively) involving the semigroup generated by the Laplacian on and that the duality of these weighted Hardy and BMO spaces holds for Muckenhoupt weights with while the previously known related results cover only . We also point out that this two weight commutator theorem might not be true in the setting of general operators L, and in particular we show that it is not true when L is the Dirichlet Laplacian on . 相似文献
110.
ABSTRACT In this paper, we present a systematic roadmap for developing a robust and parallel multi-material reactive hydrodynamic solver that integrates historically stable algorithms with new and current modern methods to solve explosive system design problems. The Ghost Fluid Method and Riemann solvers were used to enforce appropriate interface boundary conditions. Improved performance in terms of computational work and convergence properties was achieved by modifying a local node sorting strategy that decouples ghost nodes, allowing us to set material boundary conditions via an explicit procedure, removing the need to solve a coupled system of equations numerically. The locality and explicit nature of the node sorting concept allows for greater levels of parallelism and lower computational cost when populating ghost nodes. Non-linear numerical issues endemic to the use of real Equations of State in hydro-codes were resolved by using more thermodynamically consistent forms allowing us to accurately resolve large density gradients associated with high energy detonation problems at material interfaces. Pre-computed volume tables were implemented adding to the robustness of the solver base. 相似文献