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71.
Semi-empirical model potential calculations have been performed for bound and continuum properties of Li? and Na?. The calculated electron affinities of the 2s21S state of Li? and the 3s21S and 3p23Pe states of Na? are in agreement with the calculations of Norcross and with experimental data. Positions of possible autoionizing states are calculated using projection and root stabilization methods. The Stieltjes imaging method of Langhoff is employed to compute the photodetachment cross sections of Li? and Na? and the results are in excellent agreement with the close-coupling calculations of Moores and Norcross. A comparison of variational and numerical results for the coupled time-dependent Hartree-Fock photoionization of helium shows that good Stieltjes imaging results can be obtained with a very small basis set for the variational calculation. The continuous photoemission profile for the 3p23Pe state of Na? is also obtained. 相似文献
72.
An HPLC post column chemical derivatization procedure based on the interaction between an acridinium triflate and amines to form highly colored derivatives on-line is described for the determination of aromatic amines. Benzocaine and butesin, local anesthetic agents that contain the aromatic amine group, were used as model compounds. Reversed-phase HPLC conditions were developed for both the separation of analytes and the reaction between analytes and the acridinium triflate in the system. Three-dimensional knitted teflon shape coils and the internal diameter and length of the coils were important parameters in reducing band broadening and background noise.N-Methyl-9-chloroacridinium triflate was shown to be applicable to the determination of primary aromatic amines, selected secondary aromatic amines, hydrazides, and hydrazines. Application of the on-line chemical derivatization procedure to the analysis of pharmaceutical dosage forms containing procainamide (primary aromatic amine), isoniazid (hydrazide), and hydralazine (hydrazine) is also described. 相似文献
73.
[reaction: see text]. Commercially available cyanoethyl phosphoramidites derived from T, d(C), d(A), and d(G) were hydrolyzed (1H-tetrazole, MeCN/H2O) to give the corresponding H-phosphonates in excellent yields. Palladium(0)-catalyzed cross-coupling of each of these with the thymidine-derived vinylbromide 2 afforded the corresponding vinylphosphonate-linked dimers TT, d(C)T, d(A)T, and d(G)T in modest to good yields. The TT dimer was further elaborated to give a 5'-DMT-TT-3'-CEP building block, and this was used in the automated synthesis of the TpTTpT tetramer. 相似文献
74.
On heating, ammonium metavanadate (AMV) decomposes in several atmospheredependent stages. An important decomposition intermediate, ammonium hexavanadate (AHV), may also be prepared by wet-chemical methods and the kinetic parameters for the thermal decomposition of AMV and of the AHV preparation have been obtained. The kinetic study has been supplemented by surface-area measurements and by electron microscopic examination of the surfaces of reactant, intermediate and product crystallites. On the basis of the type of decomposition curve, the measured activation energies, and the effects of oxygen and water vapour on the decomposition rate, it has been concluded that in vacuum and in inert atmospheres the evolution of ammonia is the rate-determining step, while in oxidizing atmospheres evolution of water is rate determining. Comparison of the kinetic parameters with thermodynamic data for the decomposi. tion has led to suggestions as to the nature of the activated complexes involved. 相似文献
75.
Development and application of a simple routine method for the determination of selenium in serum by octopole reaction system ICPMS 总被引:1,自引:0,他引:1
The aim of the study was to develop an inductively coupled plasma mass spectrometry (ICPMS) method for robust and simple routine determination of selenium in serum. Polyatomic interferences on 76Se, 77Se, and 78Se were removed by applying an octopole reaction system ICPMS with the reaction cell pressurized with H2 gas. We developed a novel simple optimization routine for the H2 gas flow based on a signal-to-noise ratio (SNR) calculation of the selenium signal measured in a single selenium standard. The optimum H2 flow was 2.9 mL min–1. The selenium content in serum was determined after a 50-fold dilution with 0.16 M HNO3 and quantified by using addition calibration and gallium as an internal standard. The method detection limit was 0.10 g L–1 for 76Se and 78Se and 0.13 g L–1 for 77Se. Human serum samples from a case-control study investigating if selenium was associated with risk of colorectal adenoma were analyzed. The average selenium concentration for the control group (n=768) was 137.1 g L–1 and the range was 73.4–305.5 g L–1. The within-batch repeatability (a batch is ten samples) estimated from 182 replicate analyses was 6.3% coefficient of variation (CV), whereas the between-batch repeatability was 7.4% CV estimated from 361 replicates between batches. The method accuracy was evaluated by analysis of a human serum certified reference material (Seronorm Serum level II, Sero A/S, Norway). There was a fairly good agreement between the measured average of 145±3 g L–1 (n=36) and the certified value of 136±9 g L–1. In addition the method was successfully applied for analysis of zinc serum concentrations without further optimization. For the Seronorm certified reference material a value of 911±75 g L–1 (n=31) for zinc was obtained, which corresponds well to the certified zinc value of 920±60 g L–1. 相似文献
76.
Charles W. Stewart C. A. Von Frankenberg 《Journal of Polymer Science.Polymer Physics》1967,5(3):623-631
The thermodynamic properties of amorphous polyethylene are calculated from a model based on the method of significant structures. The motion of a molecule as a whole is described by the motion of segments, each segment moving independently of all others. It is assumed that on melting, holes appear in the solid lattice and the segments can move into these vacancies, obtaining some gaslike degrees of freedom. The complete frequency distribution for polyethylene is used for the solidlike degrees of freedom, while a corrected classical partition function is used for the gaslike degrees of freedom. The calculated thermodynamic properties are in reasonable agreement with experimentally determined values, assuming each gaslike segment to consist of 20 CH2 groups. 相似文献
77.
Miklos Kertesz Yong S. Lee James J. P. Stewart 《International journal of quantum chemistry》1989,35(2):305-313
It is shown that infinite long polyacene chains may have three energetically close but structurally distinct isomers (a symmetrical, sym, form and two lower symmetry forms: one with double bonds in a trans and another isomer with double bonds in a cis pattern). The energetics is based on solid state MNDO theory. We discuss that the symmetrical form has a substantial energy gap Eg in the Hartree–Fock approach owing to exact exchange terms, which are nonlocal. Broken symmetry Hartree–Fock (HF ) solutions for polyacene are also described. An angularly distorted structure suggested earlier on Jahn–Teller grounds is found to be energetically not favorable. 相似文献
78.
James J. P. Stewart 《Journal of computational chemistry》1991,12(3):320-341
Using a recently developed procedure for optimizing parameters for semiempirical methods,1 PM3 has been extended to a total of 28 elements. Average ΔHf errors for the newly parameterized elements are Be: 8.6, Mg: 8.4, Zn: 5.8, Ga: 14.9, Ge: 11.4, As: 8.5, Se: 11.1, Cd: 2.6, In: 11.3, Sn: 9.0, Sb: 13.7, Te: 11.3, Hg: 6.8, Tl: 6.5, Pb: 7.4, and Bi: 10.9 kcal/mol. For some elements the paucity of data has resulted in a method, which, while highly accurate, is likely to be only poorly predictive. 相似文献
79.
Russell J. Waugh John H. Bowie Roger N. Hayes 《Journal of mass spectrometry : JMS》1991,26(4):250-256
Deprotonated dipeptides, on collisional activation, fragment by the characteristic process NH2CH(R1) CONHCH(R2)CO2? → NH2?C(R1)CONHCH(R2)CO2H → ?NHCH(R2)CO2H + NH2C(R1)?C?O, when R1 and R2 = H or alkyl. However, when one of the constituent amino acids is either aspartic acid or glutamic acid, the standard cleavage becomes minor in comparison with fragmentation through the α-side-chain of Asp or Glu. For example, [Asp-Leu - H]? and [Leu-Asp - H]? both fragment principally by loss of water, a fragmentation not normally noted for peptides. In addition, [Leu-Asp - H]? loses CO2 and also forms HO2CCH?CHCO2?˙. These fragmentations establish that Asp is the C-terminal amino acid. In contrast, isomeric Glu dipeptides, e.g. [Glu-Ala - H]? and [Ala-Glu - H]? undergo similar fragmentation, both competitively losing H2O and CO2. Both spectra also contain a product ion at m/z 128, identified as the pyroglutamate anion. Product ion and deuterium-labelling studies have been used in an attempt to elucidate the complex fragmentation mechanisms in these systems. 相似文献
80.
4-(4-Hydroxyphenyl)-2-phenylamino-1,8-naphthyridine was prepared via cyclisation of N-phenyl-N′-3-(4-hydroxyphenethen-1-yl)pyridin-2-ylthiourea in the presence of mercuric oxide. Derivatives of 4-methyl-2-aminoquinolines were prepared in a similar manner from 2-vinylphenylthioureas. 相似文献