Effect of genesis on the properties and hydrogen reducibility of NiO-ZnO mixed oxides

The physico-chemical properties and reactivity tested by hydrogen reduction have been studied for two series of NiO-ZnO mixed oxides of various composition. The solid nickel oxide or zinc oxide in interaction with the solution of nitrate of the second component were used as the precursors in each series. The differences in some physico-chemical parameters of the samples in both series were correlated with their reduction behaviour, followed both in iso- and non-isothermal regime. Moreower, the influence of various factors modifying the reactivity of mixed oxides was also investigated and the results were compared with those obtained from earlier studied analogous systems of quite different origin.This revised version was published online in November 2005 with corrections to the Cover Date.     

Lanthanum nitrate decomposition by both temperature programmed heating and citrate gel combustion

Thermal decomposition of lanthanum nitrate to lanthanum oxide was carried out by both temperature programmed heating (TPH) and citrate-gel combustion. The temperature programmed heating was carried out under flow of oxidizing (air), neutral (nitrogen) and reducing (25 vol.% hydrogen+argone mixture) gases, and the processes were controlled by simultaneous thermogravimetry and differential thermal analysis. It was shown that hydrogen atmosphere helps to reduce temperatures of all decomposition steps. The results of TPH were utilized to check the nature of residues in the products of lanthanum nitrate-to-oxide conversion performed via citrate-gel combustion technique.     

On the vector field problem for O(n)/O(1)xO(1)xO(n-2)

We prove new results about the vector field problem on the real flag manifolds O(n)/O(1) x O(1) x O(n - 2). For some infinite families of these manifolds, we completely solve the vector field problem.     

Division and <Emphasis Type="Italic">k</Emphasis>-th root theorems for <Emphasis Type="Italic">Q</Emphasis>-manifolds

We prove that a locally compact ANR-space X is a Q-manifold if and only if it has the Disjoint Disk Property (DDP), all points of X are homological Z _∞-points and X has the countable-dimensional approximation property (cd-AP), which means that each map f: K → X of a compact polyhedron can be approximated by a map with the countable-dimensional image. As an application we prove that a space X with DDP and cd-AP is a Q-manifold if some finite power of X is a Q-manifold. If some finite power of a space X with cd-AP is a Q-manifold, then X ² and X × [0, 1] are Q-manifolds as well. We construct a countable family χ of spaces with DDP and cd-AP such that no space X ∈ χ is homeomorphic to the Hilbert cube Q whereas the product X × Y of any different spaces X, Y ∈ χ is homeomorphic to Q. We also show that no uncountable family χ with such properties exists. This work was supported by the Slovenian-Ukrainian (Grant No. SLO-UKR 04-06/07)     

Colour intransparency and the cross sections for colour-singlet and colour-octet hadrons in the Low-Nussinov model

The dependence of cross sections on the colour state of the colliding hadrons is investigated within the Low-Nussinov model of two-gluon exchange. The total cross sections for colour-octet hadrons are practically constant as functions of the hadronic radii, while they tend to zero when the radii of the colour-singlet hadrons approach zero. The slope parameter of the differential clastic cross sections for small momentum transfers is rather insensitive to the colour structure of the colliding hadrons. The integrated colour exchange cross section is calculated.     

Precipitation and characterization of uniform submicrometer lead titanate particles. Part II: Reaction mechanism

The chemical mechanism of the precipitation of lead titanium peroxohydroxide particles in a solution of nitrilotriacetate (NTA) complexes of lead and titanium peroxo-hydroxide is envisioned as the interaction between cations of lead hydroxide and anions of polymeric titanium peroxo-hydroxide.     

Algorithms for ham-sandwich cuts

Given disjoint setsP ₁,P ₂, ...,P _d inR ^d withn points in total, ahamsandwich cut is a hyperplane that simultaneously bisects theP _i . We present algorithms for finding ham-sandwich cuts in every dimensiond>1. Whend=2, the algorithm is optimal, having complexityO(n). For dimensiond>2, the bound on the running time is proportional to the worst-case time needed for constructing a level in an arrangement ofn hyperplanes in dimensiond−1. This, in turn, is related to the number ofk-sets inR ^d−1 . With the current estimates, we get complexity close toO(n ^3/2 ) ford=3, roughlyO(n ^8/3 ) ford=4, andO(n ^d−1−a(d) ) for somea(d)>0 (going to zero asd increases) for largerd. We also give a linear-time algorithm for ham-sandwich cuts inR ³ when the three sets are suitably separated. A preliminary version of the results of this paper appeared in [16] and [17]. Part of this research by J. Matoušek was done while he was visiting the School of Mathematics, Georgia Institute of Technology, Atlanta, and part of his work on this paper was supported by a Humboldt Research Fellowship. W. Steiger expresses gratitude to the NSF DIMACS Center at Rutgers, and his research was supported in part by NSF Grants CCR-8902522 and CCR-9111491.     

Electrocatalytic activity of sol-gel-prepared RuO2/Ti anode in chlorine and oxygen evolution reactions

Electrocatalytic properties of RuO₂/Ti anode with different coating masses, which are prepared by the alkoxide sol-gel procedure, are investigated in chlorine and oxygen evolution reactions by polarization measurements and electrochemical impedance spectroscopy in H₂SO₄ and NaCl electrolytes. According to polarization measurements, the activity of anodes at overpotentials below 100 mV is independent of coating mass. However, impedance measurements above 100 mV reveal changes in the activity of anodes in chlorine evolution reaction for different coating masses. The diffusion limitations related to the evolved chlorine are registered in low-frequency domain at 1.10 V (SCE), diminishing with the increase in potential to the 1.15 V (SCE). The observed impedance behavior is discussed with respect to the activity model for activated titanium anodes in chlorine evolution reaction involving formation of gas channels within porous coating structure. Gas channels enhance the mass transfer rate similarly to the forced convection, which also increases the activity of anode. This is more pronounced for the anode of greater coating mass due to its more compact surface structure. The more compact structure appears to be beneficial for gas channels formation. Published in Russian in Elektrokhimiya, 2006, Vol. 42, No. 10, pp. 1173–1179. The text was submitted by the authors in English.